Materials Literature
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FTIR, Raman, and surface-enhanced Raman scattering (SERS) of methimazole (MMI) have been investigated. MMI is an important antithyroid drug that inhibits the formation of thyroid hormone. It is widely used clinically in the treatment of hyperthyroidism, and thus it is useful to study its surface adsorption characteris…
White-light emission from ultrasmall CdSe nanocrystals offers an alternative approach to the realization of solid-state lighting as an appealing technology for consumers. Unfortunately, their extremely small size limits the feasibility of traditional methods for nanocrystal characterization. This paper reports the fir…
A recently proposed two-orbital model for the Fe-based superconductors is studied using the Lanczos method on small clusters as well as pairing mean-field approximations. Our main goals are (i) to provide a comprehensive analysis of this model using numerical techniques with focus on the magnetic state at half-filling…
Inspired by the concept of complementary media, we experimentally demonstrate that an engineered metamaterial made of alternating, stripe layers of negatively refracting (photonic crystals) and positively refracting (air) materials strongly collimates a beam of near-infrared light. This quasi-zero-average-index metama…
Nanoclusters of 25 nm sized Mg-THF have been prepared by the solvated metal atom dispersion method. Room-temperature digestive ripening of these nanoclusters in the presence of hexadecylamine (HDA) resulted in highly monodisperse colloidal Mg-HDA nanoparticles of 2.8 +/- 0.2 nm. An insight into the room-temperature di…
Reaction of the azidoborate salt [N(n-Bu)(4)][(C(6)F(5))(3)B(N(3))] ([N(n-Bu)(4)][1]) with the uranium(III) tris(anilide) complex (THF)U(N[t-Bu]Ar)(3) (2; THF = tetrahydrofuran; Ar = 3,5-Me(2)C(6)H(3)) results in formation of the paramagnetic uranium(V) nitridoborate complex [N(n-Bu)(4)][(C(6)F(5))(3)BNU(N[t-Bu]Ar)(3)…
ADVERTISEMENT RETURN TO ISSUEPREVNoteOrigin of Carbon Nanotubes Induced Poly(l-Lactide) Crystallization: Surface Induced Conformational OrderXiao Hu†, Haining An†, Zhong-Ming Li*†, Yong Geng§, Liangbin Li‡, and Chuanlu Yang§View Author Information College of Polymer Science and Engineering and State Key Laboratory of…
The transformation of ethanol to its carbonyl compounds, namely acetaldehyde, ethyl acetate, acetic acid, and ketene, occurs on Au(111) with O-containing Au nanoparticles formed as a result of Au atom release upon ozone exposure. The product distribution strongly depends on the surface oxygen coverage. Ethoxy and acet…
The structural and electronic properties of Si(335)-Au surface decorated with Pb atoms are studied by means of density-functional theory. The resulting structural model features Pb atoms bonded to neighboring Si and Au surface atoms, forming monoatomic chain located 0.2 nm above the surface. The presence of Pb chain l…
The growth and elementary properties of p-type Bi2Se3 single crystals are reported. Based on a hypothesis about the defect chemistry of Bi2Se3, the p-type behavior has been induced through low level substitutions (1 percent or less) of Ca for Bi. Scanning tunneling microscopy is employed to image the defects and estab…
We investigate the feasibility of bare and metal-coated boron buckyball B 80 with M = Li, Na, K, Be, Mg, Ca, Sc, Ti, and V for hydrogen storage using density functional theory approach. We find that M = Ca or Sc are best candidates for hydrogen storage with moderate adsorption energy of H 2 and with clustering of Sc o…
Primary productivity of open ocean environments, such as those inhabited by marine picocyanobacteria, is often limited by low inorganic phosphate (P). To observe how these organisms cope with P starvation, we constructed a full genome microarray for Synechococcus sp. WH8102 and compared differences in gene expression…
Spin-dependent properties of single-layer graphene (SLG) have been studied by nonlocal spin valve measurements at room temperature. Gate voltage dependence shows that the nonlocal magnetoresistance (MR) is proportional to the conductivity of the SLG, which is the predicted behavior for transparent ferromagnetic-nonmag…
The magnetostructural transitions and magnetoelectric effects reported in ${\text{TbMn}}_{2}{\text{O}}_{5}$ are described theoretically and shown to correspond to two essentially different mechanisms for the induced ferroelectricity. The incommensurate and commensurate phases observed between 38 and 24 K exhibit a hyb…
Having driven a large part of the decade's progress in physics, nanoelectronics is now passing from today's realm of the extraordinary to tomorrow's commonplace. This carries the problem of turning proofs of concept into practical artefacts. Better and more sharply focussed predictive modelling will be the ultimate gu…
We present an atomistic first-principles calculation of resistivity induced by atomically rough surfaces of thin Cu films. Our calculations show that the resistivity increases significantly due to surface roughness scattering and it is quite sensitive to both the amount and the nature of roughness. We determine the de…
Using electron diffraction, we show that free electron metals such as sodium and potassium form a highly regular quasiperiodic monolayer on the fivefold surface of icosahedral Al-Pd-Mn and that the quasiperiodicity propagates up to the second layer in sodium. Our photoelectron spectroscopy results show that the quasic…
This thesis presents a systematic study of magnetotransport and magnetic ordering in manganite-high T$_c$ cuprate spin valve structures. YBa$_{2}$Cu$_{3}$O$_{7}$ - La$_{2 / 3}$Sr$_{1 / 3}$MnO$_{3}$ heterostructures of (110) orientation are grown to allow direct injection of spin polarized holes from the La$_{2 / 3}$Sr…
A comprehensive study was performed on hydrogen adsorption and storage in Ca-coated boron fullerenes and nanotubes by means of density functional computations. Ca strongly binds to boron fullerene and nanotube surfaces due to charge transfer between Ca and the B substrate. Accordingly, Ca atoms do not cluster on the s…
The carrier mobility $\ensuremath{\mu}$ of few-layer graphene (FLG) field-effect transistors increases tenfold when the ${\mathrm{SiO}}_{2}$ substrate is replaced by single-crystal epitaxial $\mathrm{Pb}({\mathrm{Zr}}_{0.2}{\mathrm{Ti}}_{0.8}){\mathrm{O}}_{3}$ (PZT). In the electron-only regime of the FLG, $\ensuremat…