Materials Literature
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Epitaxial thin films of LaMnO3 were grown by pulsed laser deposition in identical deposition conditions but in situ annealed in different oxygen environments. All the films showed an insulator to metal transition. It also showed a magnetic order that correlates well with an insulator to metal behavior. The transition…
We propose a novel ferroelectric-gate field-effect transistor (FET) with a polar semiconductor channel, which is called a controlled-polarization-type ferroelectric-gate FET. The essential factor for this device is the stabilization of the spontaneous polarization of the ferroelectric film by the spontaneous polarizat…
Abstract N,N ‐Bis(2‐hydroxyethyl)formamide (BHF) was synthesized efficiently and used as a new plasticizer for corn starch to prepare thermoplastic starch (TPS). The hydrogen bond interaction between BHF and starch was proven by Fourier‐transform infrared (FT‐IR) spectroscopy. As detected by scanning electron microsco…
Using first-principles calculations, we show that nanopatterned graphite films (NPGFs) can exhibit magnetism in analogy to graphene-based nanostructures (GBNs). In particular, graphite films with patterned nanoscale triangular holes and channels with zigzag edges all have ferromagnetic ground states. The magnetic mome…
Abstract Stevensite-like sauconite, with the general composition: <mml:math xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mnf="http://cambridge.org/core/manifest" xmlns:cup="http://contentservices.cambridge.org" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:m="http://cambridge.org/core/metadata" xmlns:core="…
In this work molecular simulations are performed to investigate protein interactions with hydroxylated and methylated mannitol and sorbitol terminated self-assembled monolayer (SAM) surfaces in the presence of explicit water molecules. The role of surface hydrogen bond donor versus acceptor groups is evaluated by comp…
The structural stability of cubic KMF3 (M: Mg, Zn, Co, Ni) perovskites has been studied by powder X-ray diffraction under pressure. Neither superlattice reflections nor peak splitting associated to a phase transition were detected in the 0–10 GPa pressure range. Furthermore, KMgF3 showed no structural changes up to 50…
In the present work, we study the phase composition of ZrO2-TiO2 system by means of XRD and Raman spectroscopy, using also TG-ATD, and N2 adsorption isotherms as complementary characterization techniques. TiO2-ZrO2 samples of selected compositions (0, 10, 90, 50 and 100% in weight of TiO2) were prepared by sol-gel met…
The discovery of carbon nanotubes (CNTs) has stimulated intensive research to characterize their structure and to determine their physical properties, both by direct measurement and through predictive methods. Many of the fundamental and remarkable properties of CNTs are now well-known, and their exploitation in a wid…
Experimental characterization through electron paramagnetic resonance (EPR) and confocal luminescence microscopy (CML) of a Ge-doped glass (preform and fiber) reveals the generation of several point defects by 10 keV X-ray radiation-induced attenuation: GeE', Ge(1), Ge(2), and Ge-ODC. The generation mechanisms of Ge-O…
Understanding the rates at which fluid flows into clay interlayers at the molecular level is fundamental to designing an effective clay barrier system. In this work, molecular interactions at the Na-montmorillonite (MMT)-water interface, emphasizing the flow properties of the clay interlayer, have been studied at the…
The properties of the ion exchange resins, Amberlite IRA 402, a strong anion exchange resin and IRA 67, a weak anion exchange resin were determined to evaluate their comparative suitability for lactic acid recovery from fermented cassava bagasse. Data on binding capacities and recovery proved that weak base resin in c…
Abstract An increased usage of poly‐β‐hydroxyalkanoates (PHA), for instance as bulk biodegradable and biocompatible plastics, will require a cheaper production and downstream processing. If the synthesis of this intracellular biopolyester could be combined with the production of another valuable intracellular product,…
Metamaterial is an artificial material in which the effective phase constant can be controlled by the internal physical periodic structure of the transmission line. Effective phase constant is designed to be of any value, which may be small, large, approximately zero, or negative, attained by changing the dimensions o…
Abstract A suite of experimentally deformed single-crystal pyrite samples has been investigated using electron backscatter diffraction (EBSD). Single crystals were loaded parallel to <100> or <110> and deformed at a strain rate of 10 -5 s -1 , confining pressure of 300 MPa and temperatures of 600°C and 700…
Multiferroic bilayered thin films consisting of Pb(Zr0.52Ti0.48)O3 (PZT) and CoFe2O4 (CFO) layers of different relative thicknesses were prepared on a general Pt/Ti/SiO2/Si substrate via a simple solution processing. The influence of the thickness fraction on their properties including ferroelectric, ferromagnetic, an…
Hydrophilic 2,3-dimercaptosuccinnic acid (HOOC-CH(SH)-CH(SH)-COOH, DMSA) coated monodisperse magnetic nanoparticles (Fe3O4) were dispersed in water, RPMI-1640 with 10% (v/v) fetal calf serum, RPMI-1640, PBS and MES, respectively, to investigate their stability under biologically relevant conditions. The Photon Correla…
The microstructure of partially molten rocks plays a key role in determining their physical properties. The area fraction of intergranular contact, contiguity, governs the establishment of a skeletal framework of solid grains and controls the effective elastic moduli of the aggregate. This work presents a theoretical…
The crossover of single crystalline Sr x Ba 1 − x Nb 2 O 6 (SBN) from ferroelectric to relaxor behavior when increasing the Sr 2+ content from x = 0.4 to x = 0.75 is investigated by dielectric low-frequency susceptometry and scanning piezo-force microscopy. Increasing quenched random electric fields are conjectured to…
We report the synthesis, crystal structure, and thermal and magnetic properties of the two-dimensional achiral soft ferrimagnet [Mn(II)(enH)(H(2)O)][Cr(III)(CN)(6)].H(2)O (1), en = 1,2-diaminoethane, as well as the recyclability of the dehydration and rehydration and their influence on the crystal structure and its ma…