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Preparation of Fine-Sized SrSi[sub 2]O[sub 2-δ]N[sub 2+2/3δ]:Eu[sup 2+] Phosphor by Spray Pyrolysis and its Luminescent Characteristics

Kyeong Youl Jung、Jeong Hyub Seo2008-01-01Electrochemical and Solid-State Letters

The spray pyrolysis process was applied to prepare oxynitride phosphor , and the luminescence properties were investigated. The prepared particles had a green emission and good excitation characteristics in the region of 400–450 nm. The particles had an oxygen-rich phase . On the basis of the concentration quenching d…

Luminescence Properties of Advanced MaterialsAmmonia Synthesis and Nitrogen ReductionInorganic Chemistry and Materials

Protecting role of cosolvents in protein denaturation by SDS: a structural study

Catherine Michaux、Jenny Pouyez、Johan Wouters 等 4 位作者2008-01-01BMC Structural Biology

BACKGROUND: Recently, we reported a unique approach to preserve the activity of some proteins in the presence of the denaturing agent, Sodium Dodecyl Sulfate (SDS). This was made possible by addition of the amphipathic solvent 2,4-Methyl-2-PentaneDiol (MPD), used as protecting but also as refolding agent for these pro…

Protein Structure and DynamicsEnzyme Structure and FunctionProtein Interaction Studies and Fluorescence Analysis

Hydrophilic monolayer-protected gold nanoparticles and their functionalisation with fluorescent chromophores

Nicolas Nerambourg、Raïssa Praho、Martinus H. V. Werts 等 5 位作者2008-01-01International Journal of Nanotechnology

The efficient implementation of metal nanoparticles in bioanalytical detection schemes, biological imaging and phototherapy requires these particles to be stable against aggregation and chemical desintegration. The functionalisation of these particles with specific (bio)molecular units is a further necessity. These re…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Triple-Phase Boundary and Surface Transport in Mixed Conducting Patterned Electrodes

Matthew E. Lynch、David S. Mebane、Yingjie Liu 等 4 位作者2008-01-01Journal of The Electrochemical Society

The mathematical framework required to account for a triple-phase boundary (TPB) and the accompanying surface transport was added to a two-dimensional numerical model of a mixed conducting thin film by considering appropriate kinetic rate and mass-transport expressions. Approximate parameters were chosen so that the m…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsElectronic and Structural Properties of Oxides

A SYMMETRICAL CIRCUIT MODEL DESCRIBING ALL KINDS OF CIRCUIT METAMATERIALS

Tie Jun Cui、Huifeng Ma、Ruo Peng Liu 等 6 位作者2008-01-01Progress In Electromagnetics Research B

Abstract—We present a generally symmetrical circuit model to describe all kinds of metamaterials with effective permittivity and permeability. The model is composed of periodic structures whose unit cell is a general T-type circuit. Using the effective medium theory, we derive analytical formulations for the effective…

Metamaterials and Metasurfaces ApplicationsPhotonic Crystals and ApplicationsAdvanced Antenna and Metasurface Technologies

Differential Scanning Calorimetry Measurements of Magnesium Borohydride Mg(BH<SUB>4</SUB>)<SUB>2</SUB>

Yigang Yan、Haiwen Li、Yuko Nakamori 等 7 位作者2008-01-01MATERIALS TRANSACTIONS

Multistep dehydriding reactions of magnesium borohydride Mg(BH4)2 were studied by Differential Scanning Calorimetry (DSC) measurements. The values of the enthalpy changes of the reactions from the measurements are in good agreement with those from first-principles calculations. Kinetically restricted dehydriding react…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionSuperconductivity in MgB2 and Alloys

Nanofiber Mats from DNA, SWNTs, and Poly(ethylene oxide) and Their Application in Glucose Biosensors

Yong Liu、Jun Chen、Nguyen Tuan Anh 等 6 位作者2008-01-01Journal of The Electrochemical Society

Ultrafine fibers with diameters ranging from 50 to 300 nm were prepared from DNA/single-walled carbon nanotubes (SWNTs)/poly(ethylene oxide) blended dispersion. Well-defined electrospun fibers were obtained by good control of key dispersion properties related to electrospinning, such as ionic conductivity, surface ten…

Electrochemical sensors and biosensorsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Synthesis and Thermal Cross-Linking Study of Partially-Aminated Epoxidized Linseed Oil

Gustavo Lopez Tellez、Enrique Vigueras‐Santiago、Susana Hernández López 等 4 位作者2008-01-01Designed Monomers & Polymers

The reaction of diamines or triamines with epoxidized oils leads to different reactions of intra/intermolecular cross-linking and the disruption of the ester linkage. However, by controlling the reaction conditions of temperature, stoichiometry and catalyst, production of oxirane rings without cross-linking and/or dis…

Polymer composites and self-healingEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Synthesis and Optical Property Studies of Nanocrystalline ZrO[sub 2]:Ti Long-Lasting Phosphors

Cong Yan、Bin Li、Xiaojun Wang 等 5 位作者2008-01-01Journal of The Electrochemical Society

A facile synthetic route to synthesize the nanocrystalline zirconia particles via preparing polyzirconoxane with zirconium tetraalkoxide is reported, and the luminescent properties of the so-obtained nanophosphors are systematically investigated in this paper. The bluish-white photoluminescence and phosphorescence ori…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsPerovskite Materials and Applications

Growth Behavior of Atomic-Layer-Deposited Pb(Zr,Ti)O[sub x] Thin Films on Planar Substrate and Three-Dimensional Hole Structures

Takayuki Watanabe、Susanne Hoffmann‐Eifert、Cheol Seong Hwang 等 4 位作者2008-01-01Journal of The Electrochemical Society

Quaternary (PZT) films were deposited at by a combination of liquid-injection atomic layer deposition (ALD) of binary PbO, , and thin films. In preliminary work, binary films were deposited at by ALD. Two solutions of and dissolved in ethylcyclohexane (ECH) were prepared, and it was found that the solution provides a…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Effect of microstructure on the hydrogen behavior in 7075 series aluminum alloys

Goroh ITOH、Takahiro Izumi、Takuji Tohyama2008-01-01Journal of Japan Institute of Light Metals

By using hydrogen microprint technique (HMPT) , effect of microstructure on hydrogen permeation behavior in 7075 and 7475 aluminum alloys exposed to gaseous hydrogen has been investigated. The important findings are as follows. The amount of permeated hydrogen is strongly dependent on crystalline structure, temper and…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Design of a high-temperature and high-pressure liquid flow cell for x-ray absorption fine structure measurements under catalytic reaction conditions

Toshihide Kawai、Wang‐Jae Chun、Kiyotaka Asakura 等 8 位作者2008-01-01Review of Scientific Instruments

The design and performance of a new high-pressure and high-temperature cell for measurement of x-ray absorption fine structure (XAFS) spectra of solid catalysts working in a flowing liquid are presented. The cell has flat, high-purity sintered cubic boron nitride (c-BN) windows which can tolerate high temperature (900…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Nanoscale tools to selectively destroy cancer cells

Pierre‐Luc Boudreault、Mathieu Arseneault、François Otis 等 4 位作者2008-01-01Chemical Communications

We present experimental data that demonstrate the potential of synthetic crown ether modified peptide nanostructures to act as selective and efficient chemotherapeutic agents that operate by attacking and destroying cell membranes.

Advanced biosensing and bioanalysis techniquesChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

New fluorinated terphenyl isothiocyanate liquid crystals

Amanda Parish、Sebastian Gauza、Shin‐Tson Wu 等 5 位作者2008-01-01Liquid Crystals

High birefringence (Δn>0.4) nematic liquid crystals are particularly attractive for infrared applications because they enable a thinner cell gap to be used for achieving a fast response time. In this experiment, we evaluate the mesomorphic and physical properties of several fluorinated NCS terphenyl compounds. These c…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochemistry and Electron Transfer Studies

On the origin of paramagnetism in planar nickel(ii) complexes

Adam J. Bridgeman2008-01-01Dalton Transactions

The general rule that in Ni(II) d(8) chemistry, tetrahedral (or nearly tetrahedral) complexes have temperature dependent magnetic moments which are usually larger than the spin-only value whilst square planar complexes are diamagnetic is broken for certain Ni[P((t)Bu)(2)(O)NR](2) complexes. These have planar coordinat…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Synthesis and Charaterization of Magnesium Zinc Ferrites as Electromagnetic Source

Noorhana Yahya、Ami Salwani Mohamad Nor Aripin、Azizuddin A. Aziz 等 7 位作者2008-01-01American Journal of Engineering and Applied Sciences

Fabrication of Mg1-XZnXFe2O4 (where x = 0.2, 0.3, 0.4 and 0.5) samples using a conventional technique is reported. Oxides of magnesium, zinc and iron with purity of about 99.99% were mixed with distilled water in a milling machine for 12 hours. They were then filtered and presintered at 1250°C and sintered at 1350°C f…

Magnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

Influence of variations in liquid-crystalline content upon the self-assembly behavior of siloxane-based block copolymers

Eric Verploegen、Tejia Zhang、Nicholas Murlo 等 4 位作者2008-01-01Soft Matter

A series of well-defined smectic side chain liquid-crystalline (LC) block copolymers with a low glass transition (Tg) siloxane block has been synthesized via anionic polymerization; these systems consist of a glassy polystyrene block and a unique low glass transition temperature LC block based on poly(vinylmethylsilox…

Liquid Crystal Research AdvancementsBlock Copolymer Self-AssemblyAdvanced Materials and Mechanics

Preparation of Cordierite Materials with Tailored Porosity by Gelcasting with Polysaccharides

Isabel Santacruz、Rodrigo Moreno、João Batista Rodrigues Neto2008-01-01International Journal of Applied Ceramic Technology

This paper deals with the rheological characterization of agar and foaming surfactant‐containing suspensions for obtaining stoichiometric cordierite samples with tailored open macroporosity and their characterization through density and microstructural studies. The influence of the processing parameters solid loading…

Polymer Nanocomposites and PropertiesMesoporous Materials and CatalysisPickering emulsions and particle stabilization

Chemistry and supramolecular chemistry of chromium horseshoes

Marzio Rancan、Graham N. Newton、C.A. Muryn 等 7 位作者2008-01-01Chemical Communications

Synthetic and structural studies of Cr horseshoes are reported which show that these compounds demonstrate a rich supramolecular chemistry through H-bonding interactions, and can act as ligands for metal clusters.

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

In vitro characterization of phosphatidylglyceroglycerol‐based thermosensitive liposomes with encapsulated 1H MR T1‐shortening gadodiamide

Tungte Wang、Martin Hossann、Herbert M. Reinl 等 8 位作者2008-01-01Contrast Media & Molecular Imaging

Thermosensitive liposomes (TSL) with encapsulated proton (1H) magnetic resonance (MR) contrast agents have been proposed for noninvasive online temperature monitoring during tumor treatment using chemotherapy combined with hyperthermia (HT). The technique exploits the fact that water exchange between the TSL interior…

Nanoparticle-Based Drug DeliveryAdvanced MRI Techniques and ApplicationsLanthanide and Transition Metal Complexes