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Dynamics of the stratification process in drying colloidal dispersions studied by terahertz time-domain spectroscopy

J. L. M. van Mechelen2014-11-07arXiv

We present an optical study that reveals the bulk dynamics of the stratification process in drying colloidal dispersions. Terahertz time-domain spectroscopy has been used to measure in situ solventborne and waterborne paint layers as a function of drying time. The dynamic behavior of the dry top layer and wet bottom l…

Materials ScienceSoft Condensed MatterChemical Physicsphysics.optics

Three-Dimensional Highly Conductive Graphene–Silver Nanowire Hybrid Foams for Flexible and Stretchable Conductors

Chao Wu、Lijun Fang、Xingyi Huang 等 4 位作者2014-11-07ACS Applied Materials & Interfaces

Graphene foams have showed huge application potentials owing to their unique 3D structure and superior properties. Thus, it is highly desired to develop a simple and effective pathway to fabricate high performance graphene-based foams. Here, we present a polymer template-assisted assembly strategy for fabricating a no…

Graphene research and applicationsSupercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting Materials

Acute exposure to ZnO nanoparticles induces autophagic immune cell death

Brandon M. Johnson、Joseph A. Fraietta、Donald T. Gracias 等 11 位作者2014-11-07Nanotoxicology

The increasing risk of incidental exposure to nanomaterials has led to mounting concerns regarding nanotoxicity. Zinc oxide nanoparticles (ZnO NPs) are produced in large quantities and have come under scrutiny due to their capacity to cause cytotoxicity in vitro and potential to cause harm in vivo. Recent evidence has…

Nanoparticles: synthesis and applicationsAutophagy in Disease and TherapyHeavy Metal Exposure and Toxicity

Mechanical performance of woven kenaf-Kevlar hybrid composites

Ridwan Yahaya、SM Sapuan、Mohammad Jawaid 等 5 位作者2014-11-07Journal of Reinforced Plastics and Composites

Hybrid composites offer a combination of advantages of constituent components to produce a material with determined properties. In the present work, woven hybrid composite was prepared by hand lay-up method in laminate configuration. Kevlar/kenaf hybrid composites were fabricated with total fibre content of 30% and th…

Natural Fiber Reinforced CompositesCellular and Composite StructuresTextile materials and evaluations

An Aqueous Rechargeable Formate‐Based Hydrogen Battery Driven by Heterogeneous Pd Catalysis

Qingyuan Bi、Jiandong Lin、Yongmei Liu 等 7 位作者2014-11-07Angewandte Chemie International Edition

The formate-based rechargeable hydrogen battery (RHB) promises high reversible capacity to meet the need for safe, reliable, and sustainable H2 storage used in fuel cell applications. Described herein is an additive-free RHB which is based on repetitive cycles operated between aqueous formate dehydrogenation (discharg…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAdvanced battery technologies research

Electrolytic Conditioning of a Magnesium Aluminum Chloride Complex for Reversible Magnesium Deposition

Christopher J. Barile、Elizabeth C. Barile、Kevin R. Zavadil 等 5 位作者2014-11-07The Journal of Physical Chemistry C

We describe in this report the electrochemistry of Mg deposition and dissolution from the magnesium aluminum chloride complex (MACC). The results define the requirements for reversible Mg deposition and definitively establish that voltammetric cycling of the electrolyte significantly alters its composition and perform…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationLayered Double Hydroxides Synthesis and Applications

Self-Assembled Peptide Nanofibers Designed as Biological Enzymes for Catalyzing Ester Hydrolysis

Chunqiu Zhang、Xiangdong Xue、Quan Luo 等 11 位作者2014-11-07ACS Nano

The structural arrangement of amino acid residues in a native enzyme provides a blueprint for the design of artificial enzymes. One challenge of mimicking the catalytic center of a native enzyme is how to arrange the essential amino acid residues in an appropriate position. In this study, we designed an artificial hyd…

Advanced biosensing and bioanalysis techniquesChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials

In vitro toxicity assessment of chitosan oligosaccharide coated iron oxide nanoparticles

Sudeep Shukla、Alka Jadaun、Vikas Arora 等 6 位作者2014-11-07Toxicology Reports

Iron oxide nanoparticles (INPs) have potential biological, biomedical and environmental applications. These applications require surface modification of the iron oxide nanoparticles, which makes it non-toxic, biocompatible, stable and non-agglomerative in natural and biological surroundings. In the present study, iron…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsIron oxide chemistry and applications

Synthesis of Phosphorus‐Doped Graphene and its Wide Potential Window in Aqueous Supercapacitors

Yangyang Wen、Bei Wang、Congcong Huang 等 5 位作者2014-11-07Chemistry - A European Journal

Phosphorus-doped (P-doped) graphene with the P doping level of 1.30 at % was synthesized by annealing the mixture of graphene and phosphoric acid. The presence of P was confirmed by elemental mapping and X-ray photoelectron spectroscopy, while the morphology of P-doped graphene was revealed by using scanning electron…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Elemental Analogues of Graphene: Silicene, Germanene, Stanene, and Phosphorene

Sivacarendran Balendhran、Sumeet Walia、Hussein Nili 等 5 位作者2014-11-07OpenAlex

The fascinating electronic and optoelectronic properties of free-standing graphene has led to the exploration of alternative two-dimensional materials that can be easily integrated with current generation of electronic technologies. In contrast to 2D oxide and dichalcogenides, elemental 2D analogues of graphene, which…

Graphene research and applications2D Materials and ApplicationsTopological Materials and Phenomena

Effective Passivation of Exfoliated Black Phosphorus Transistors against Ambient Degradation

Joshua D. Wood、Spencer A. Wells、Deep Jariwala 等 10 位作者2014-11-07arXiv

Unencapsulated, exfoliated black phosphorus (BP) flakes are found to chemically degrade upon exposure to ambient conditions. Atomic force microscopy, electrostatic force microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy are employed to character…

Graphene research and applications2D Materials and ApplicationsSemiconductor materials and devices

Toughening modification of (Acrylonitrile‐styrene‐acrylic copolymer)/(α‐Methylstyrene‐acrylonitrile copolymer) binary blend via using different impact modifiers

Wenqiang Zhu、Bo Xiang、Jun Zhang2014-11-06Journal of Vinyl and Additive Technology

In this work, different impact modifiers such as acrylic resin impact modifier, chlorinated polyethylene (CPE), nitrile rubber, powdered nitrile rubber, and hydrogenated nitrile rubber, were chosen to improve the toughness of (acrylonitrile‐styrene‐acrylic copolymer)/(α‐methylstyrene‐acrylonitrile copolymer) (ASA/α‐MS…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesPolymer Science and PVC

Synthesis of tyrosine-involved corrole Cu(III), Mn(IV), and Mn(III) complexes as biomimetic models of oxygen evolving complex in photosystem II

Ming Xia、Yan Gao2014-11-06Russian Journal of Physical Chemistry A

Boc-protected tyrosine-attached corrole ligand on the “ ortho ” position compound 3 , its corresponding copper (III) 4a , manganese (IV) 4b , and manganese (III) 4c complexes have been designed and synthesized based on the structures of active-centers of related biological systems. 1 H NMR and electronic absorption sp…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Polyurethanes from the crystalline prepolymers resistant to abrasive wear

Agata Domańska、Anna Boczkowska、Marta Izydorzak-Woźniak 等 5 位作者2014-11-06Green Sciences

Abstract The research aimed at the selection of polyurethanes synthesized from poly(tetramethylene ether) glycol (PTMEG), as well as from two different isocyanates 4,4′-methylenebis(cyclohexyl)isocyanate (HMDI) and 4.4′-methylenebis(phenyl isocyanate) (MDI) in order to obtain polyurethane with increased resistance to…

Orthopaedic implants and arthroplastybiodegradable polymer synthesis and propertiesTribology and Wear Analysis

Morphing for faster computations in transformation optics

Ronald Aznavourian、Sébastien Guenneau2014-11-06Optics Express

We propose to use morphing algorithms to deduce some approximate wave pictures of scattering by cylindrical invisibility cloaks of various shapes deduced from the exact computation (e.g. using a finite element method) of scattering by cloaks of two given shapes, say circular and elliptic ones, thereafter called the so…

Magnetic properties of thin filmsMetamaterials and Metasurfaces ApplicationsAdvanced Optical Imaging Technologies

Influence of laser irradiation on the optical properties of nano-sized powder of metal oxide

W.A. Farooq、Syed Mansoor Ali、Walid Tawfik 等 7 位作者2014-11-06Russian Journal of Physical Chemistry A

ZnO Nano powders were prepared by co-precipitation method which includes post-oxidation and annealing in air. Influence of laser irradiation was carried out using 355 nm laser on the physical properties of ZnO nanoparticles. SEM studies reveal agglomeration of grains resulting into enlargement and deformation of the n…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsLaser-Ablation Synthesis of Nanoparticles

Spectrum of edge states in theν=0quantum Hall phases in graphene

P. K. Pyatkovskiy、V. A. Miransky2014-11-06Physical Review B

Edge excitations of the $\ensuremath{\nu}=0$ quantum Hall state in monolayer graphene are studied within the mean-field theory with different symmetry-breaking terms. The analytical expressions for the continuum (Dirac) model wave functions are obtained for the charge density wave, Kekul\'e distortion, ferromagnetic,…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Molecular dynamics simulations of the interfacial characteristics of polypropylene/single-walled carbon nanotubes

S. Rouhi、Y. Alizadeh、R. Ansari2014-11-06Proceedings of the Institution of Mechanical Engineers Part L Journal of Materials Design and Applications

Using molecular dynamics simulations, the interfacial characteristics of polypropylene chains with single-walled carbon nanotubes are studied. The effects of different parameters (including initial orientation of polypropylene chain relative to nanotube, temperature, nanotube chirality and radius, and chain length) on…

Carbon Nanotubes in CompositesConducting polymers and applicationsNanopore and Nanochannel Transport Studies

Novel nanocomposites obtained by dispersion of LDH modified with N ‐tetrabromophthaloyl‐glutamic in poly(amide‐imide) having N ‐trimellitylimido‐ l ‐leucine and 4,4′‐diaminodiphenylether units

Shadpour Mallakpour、Mohammad Dinari、Meysam Talebi2014-11-06Polymer Composites

Layered double hydroxides (LDHs) have attracted much attention as nanofillers in polymer nanocomposites (NCs) due to their particular surface structural, positively charged layer and so on. In this study, a chiral diacid was synthesized by the reaction of tetrabromophthalic anhydride and glutamic acid. LDH was modifie…

biodegradable polymer synthesis and propertiesLayered Double Hydroxides Synthesis and ApplicationsSynthesis and properties of polymers