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Experimental and computational studies of Nicotiana tabacum leaves extract as green corrosion inhibitor for mild steel in acidic medium

Jeetendra Bhawsar、Payal Jain、Preeti Jain2015-05-04Alexandria Engineering Journal

In the present work corrosion inhibition of mild steel in 2 M H2SO4 solution by Nicotiana tabacum extract was studied by weight loss method. It has been found that the extract acts as an effective corrosion inhibitor for mild steel in Sulfuric acid medium. The inhibition process is attributed to the formation of an ad…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsConcrete Corrosion and Durability

Carbohydrate‐Based Nanocarriers Exhibiting Specific Cell Targeting with Minimum Influence from the Protein Corona

Biao Kang、Patricia Okwieka、Susanne Schöttler 等 10 位作者2015-05-04Angewandte Chemie International Edition

Whenever nanoparticles encounter biological fluids like blood, proteins adsorb on their surface and form a so-called protein corona. Although its importance is widely accepted, information on the influence of surface functionalization of nanocarriers on the protein corona is still sparse, especially concerning how the…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryAdvanced Drug Delivery Systems

Progress and Prospects in Symmetrical Solid Oxide Fuel Cells with Two Identical Electrodes

Chao Su、Wei Wang、Meilin Liu 等 5 位作者2015-05-04Advanced Energy Materials

Symmetrical solid oxide fuel cells (SOFCs) have attracted increasing attention due to their potential for improved thermomechanical compatibility of the electrolyte and the electrodes, reduced fabrication cost, and enhanced immunity to coking and sulfur poisoning. While the electrode materials of symmetrical SOFCs are…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Efficient Tailoring of Upconversion Selectivity by Engineering Local Structure of Lanthanides in NaxREF3+x Nanocrystals

Hao Dong、Ling‐Dong Sun、Yefu Wang 等 9 位作者2015-05-04Journal of the American Chemical Society

Efficient tailoring of upconversion emissions in lanthanide-doped nanocrystals is of great significance for extended optical applications. Here, we present a facile and highly effective method to tailor the upconversion selectivity by engineering the local structure of lanthanides in Na(x)REF(3+x) nanocrystals. The lo…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesInorganic Fluorides and Related Compounds

Single Benzene Green Fluorophore: Solid‐State Emissive, Water‐Soluble, and Solvent‐ and pH‐Independent Fluorescence with Large Stokes Shifts

Teruo Beppu、Kosuke Tomiguchi、Akito Masuhara 等 5 位作者2015-05-04Angewandte Chemie International Edition

Benzene is the simplest aromatic hydrocarbon with a six-membered ring. It is one of the most basic structural units for the construction of π conjugated systems, which are widely used as fluorescent dyes and other luminescent materials for imaging applications and displays because of their enhanced spectroscopic signa…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

Mesocrystals in Biominerals and Colloidal Arrays

Lennart Bergström、Elena V. Sturm、Germán Salazar‐Alvarez 等 4 位作者2015-05-04Accounts of Chemical Research

High Resolution Image Download MS PowerPoint Slide Conspectus Mesocrystals, which originally was a term to designate superstructures of nanocrystals with a common crystallographic orientation, have now evolved to a materials concept. The discovery that many biominerals are mesocrystals generated a large research inter…

Bone Tissue Engineering MaterialsPaleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and Inhibition

Why Do TD-DFT Excitation Energies of BODIPY/Aza-BODIPY Families Largely Deviate from Experiment? Answers from Electron Correlated and Multireference Methods

Mohammad R. Momeni、Alex Brown2015-05-04Journal of Chemical Theory and Computation

The vertical excitation energies of 17 boron-dipyrromethene (BODIPY) core structures with a variety of substituents and ring sizes are benchmarked using time-dependent density functional theory (TD-DFT) with nine different functionals combined with the cc-pVTZ basis set. When compared to experimental measurements, all…

Advanced biosensing and bioanalysis techniquesLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Life Cycle Assessment of Cellulose Nanofibrils Production by Mechanical Treatment and Two Different Pretreatment Processes

Rickard Arvidsson、Duong Thanh Nguyen、Magdalena Svanström2015-05-04Environmental Science & Technology

Nanocellulose is a bionanomaterial with many promising applications, but high energy use in production has been described as a potential obstacle for future use. In fact, life cycle assessment studies have indicated high life cycle energy use for nanocellulose. In this study, we assess the cradle-to-gate environmental…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Layer-by-Layer Assembly for Graphene-Based Multilayer Nanocomposites: Synthesis and Applications

Taemin Lee、Sa Hoon Min、Minsu Gu 等 8 位作者2015-05-04Chemistry of Materials

Two-dimensional (2D) graphene sheets have become a versatile platform for the fabrication of innovative hybrid materials with various functions due to their unique electrical, optical, thermal, and mechanical properties. The preparation of graphene-based composites with nanoscale precision is highly important for repr…

Graphene research and applicationsSupercapacitor Materials and FabricationGraphene and Nanomaterials Applications

Bio-Inspired Structural Colors ProducedviaSelf-Assembly of Synthetic Melanin Nanoparticles

Ming Xiao、Yiwen Li、Michael C. Allen 等 9 位作者2015-05-04OpenAlex

Structural colors arising from interactions of light with submicron scale periodic structures have been found in many species across all taxa, serving multiple biological functions including sexual signaling, camouflage, and aposematism. Directly inspired by the extensive use of self-assembled melanosomes to produce c…

Gold and Silver Nanoparticles Synthesis and ApplicationsPhotonic Crystals and Applicationsmelanin and skin pigmentation

Reliable Quantitative SERS Analysis Facilitated by Core–Shell Nanoparticles with Embedded Internal Standards

Wei Shen、Xuan Yu Lin、Chaoyang Jiang 等 11 位作者2015-05-04OpenAlex

Quantitative analysis is a great challenge in surface-enhanced Raman scattering (SERS). Core-molecule-shell nanoparticles with two components in the molecular layer, a framework molecule to form the shell, and a probe molecule as a Raman internal standard, were rationally designed for quantitative SERS analysis. The s…

Gold and Silver Nanoparticles Synthesis and ApplicationsProtein Interaction Studies and Fluorescence AnalysisNanocluster Synthesis and Applications

Corrosion of Zirconium Alloys Used for Nuclear Fuel Cladding

Arthur T. Motta、Adrien Couet、Robert J. Comstock2015-05-04OpenAlex

During operation, nuclear fuel rods are immersed in the primary water, causing waterside corrosion and consequent hydrogen ingress. In this review, the mechanisms of corrosion and hydrogen pickup and the role of alloy selection in minimizing both phenomena are considered on the basis of two principal characteristics:…

Nuclear reactor physics and engineeringHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Deciphering a Nanocarbon‐Based Artificial Peroxidase: Chemical Identification of the Catalytically Active and Substrate‐Binding Sites on Graphene Quantum Dots

Hanjun Sun、Andong Zhao、Nan Gao 等 6 位作者2015-05-04OpenAlex

The design and construction of efficient artificial enzymes is highly desirable. Recent studies have demonstrated that a series of carbon nanomaterials possess intrinsic peroxidase activity. Among them, graphene quantum dots (GQDs) have a high enzymatic activity. However, the catalytic mechanism remains unclear. There…

Carbon and Quantum Dots ApplicationsAdvanced Nanomaterials in CatalysisGraphene and Nanomaterials Applications

All-Solid-State Symmetric Supercapacitor Based on Co3O4 Nanoparticles on Vertically Aligned Graphene

Qingyu Liao、Na Li、Shuaixing Jin 等 5 位作者2015-05-04OpenAlex

We have synthesized the hybrid supercapacitor electrode of Co3O4 nanoparticles on vertically aligned graphene nanosheets (VAGNs) supported by carbon fabric. The VAGN served as an excellent backbone together with the carbon fabric, enhancing composites to a high specific capacitance of 3480 F/g, approaching the theoret…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Control of Laser Speckle Noise by Using Polymer-Dispersed LC

Hirokazu Furue、Yuka Sugimoto、Kazuhiro Iwami 等 5 位作者2015-05-03Molecular Crystals and Liquid Crystals

Laser speckle noise occurs owing to the strong interference that originates in the high coherency of laser light and the surface topography of screen. The suppression of the speckle noise is necessary for laser displays such as an image projection system. To reduce the speckle noise, we have tried to control the speck…

Liquid Crystal Research AdvancementsAdvanced Optical Imaging TechnologiesOptical Polarization and Ellipsometry

Synthesis and Liquid Crystal Properties of New Fluorinated Isoxazoles

Luana D. Lopes、Aloir A. Merlo2015-05-03Molecular Crystals and Liquid Crystals

New fluorinated LC 3,5-diarylisoxazolines and 3,5-diarylisoxazoles have been synthesized and their thermal properties reported. Isoxazolines were synthesized using [3+2] 1,3-dipolar cycloaddition from nitrile oxide and alkenes with subsequent MnO2-oxidation yielded the corresponding isoxazoles. The title compounds obt…

Fluorine in Organic ChemistrySynthesis and properties of polymersSynthesis and Reactions of Organic Compounds

Localized Modes in Optics of Chiral Liquid Crystals

V. A. Belyakov2015-05-03Molecular Crystals and Liquid Crystals

The localized opical modes in photonic liquid crystals are studied for the certainty at the example of chiral liquid crystals (CLCs). The chosen here model (absence of dielectric interfaces in the studied structures) allows one to get rid off the polarization mixing at the surfaces of the CLC layer and the defect stru…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Determination of antioxidant activities in fruit juices based on rapid colorimetric measurement and characterisation of gold nanoparticles

Ju Chou、Xiaofu Li、Yifan Yin 等 4 位作者2015-05-03International Journal of Environmental & Analytical Chemistry

A simple and green synthesis of gold nanoparticles (AuNPs) was achieved in tea solution and fruit juices with auric tetrachloride (HAuCl4) without the addition of any other chemicals. Natural antioxidants present in tea leaves and fruit juices were able to reduce Au3+ ions to form AuNPs spheres with an average diamete…

Electrochemical sensors and biosensorsAdvanced Nanomaterials in CatalysisMedicinal Plants and Neuroprotection

Some Physical Characteristics of Strain Hardening in Severe Plastic Deformation

Yan Beygelzimer、László S. Tóth、John J. Jonas2015-05-03Advanced Engineering Materials

It is shown here using group theory principles that the Hencky strain is not an appropriate measure for tests involving simple shear, for which the von Mises formulation should be used exclusively. It is also shown analytically that the application of self‐similarity principles to Stages III–IV indicates that these ob…

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesMetallurgy and Material Forming

Development of <i>Sansevieria trifasciata</i> - Carbon Fiber Reinforced Polymer Hybrid Nanocomposites

Krishna Sameer B. Raghava、M. Ashok Kumar、V. Nikill Murthy 等 4 位作者2015-05-03International Letters of Chemistry Physics and Astronomy

This paper presents studies on experimental values of tensile strength properties of hybrid nanocomposites were studied and compared with theoretical values. It was observed that, experimental strengths were fallen shorter than the theoretical values. Nanocomposites were fabricated by filling MMT nanoclay by weight ra…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties