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Mask-Assisted Seeded Growth of Segmented Metallic Heteronanostructures

Cameron C. Crane、Jing Tao、Feng Wang 等 5 位作者2014-11-10The Journal of Physical Chemistry C

Controlling the deposition of exotic metals in the seeded growth of multimetal nanostructures is challenging. This work describes a seeded growth method assisted by a mask for synthesis of segmented binary or ternary metal nanostructures. Silica is used as a mask to partially block the surface of a seed and a second m…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing Technologiesnanoparticles nucleation surface interactions

Different Synthesis Protocols for Co3O4–CeO2 Catalysts—Part 1: Influence on the Morphology on the Nanoscale

Jingxia Yang、Liliana Lukashuk、Johanna Akbarzadeh 等 8 位作者2014-11-10Chemistry - A European Journal

Co3 O4 -modified CeO2 (Co/Ce 1:4) was prepared by a combination of sol-gel processing and solvothermal treatment. The distribution of Co was controlled by means of the synthesis protocol to yield three different morphologies, namely, Co3 O4 nanoparticles located on the surface of CeO2 particles, coexistent Co3 O4 and…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

C-dot sensitized Eu 3+ luminescence from Eu 3+ -doped LaF 3 –C dot nanocomposites

Tuhin Samanta、Chanchal Hazra、Venkataramanan Mahalingam2014-11-10New Journal of Chemistry

C-dot sensitized strong Eu <sup>3+</sup> luminescence is observed in Eu <sup>3+</sup> -doped LaF <sub>3</sub> –C-dot nanocomposites <italic>via</italic> energy transfer.

Luminescence Properties of Advanced MaterialsCarbon and Quantum Dots ApplicationsNanocluster Synthesis and Applications

High energy product in Battenberg structured magnets

S. Bance、Harald Oezelt、T. Schrefl 等 14 位作者2014-11-10Applied Physics Letters

Multiphase nano-structured permanent magnets show a high thermal stability of remanence and a high energy product while the amount of rare-earth elements is reduced. Non-zero temperature micromagnetic simulations show that a temperature coefficient of remanence of −0.073%/K and that an energy product greater than 400…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsMagnetic Properties of Alloys

Abnormal luminescent property of Mn 2+ in α-LiZnBO 3 :Mn 2+

Hongrun Wang、Li Wu、Li Wu 等 9 位作者2014-11-10Dalton Transactions

Mn(2+)-activated red phosphor α-LiZnBO3:Mn(2+) was synthesized by solid state reaction. ESR spectra prove that the doped ions are Mn(2+). The doped Mn(2+) ion is inclined to occupy Zn(2+) site, which is a tetrahedral coordination. The diffuse reflection spectra indicate that α-LiZnBO3:Mn(2+) has strong absorption in t…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesInorganic Fluorides and Related Compounds

Solubilities of Adipic Acid and Succinic Acid in a Glutaric Acid + Acetone or n -Butanol Mixture

Yanyan Li、Yatao Wang、Zhuoyuan Ning 等 6 位作者2014-11-10Journal of Chemical & Engineering Data

In order to provide thermodynamic data for mixed dibasic acid separation technology, the solubilities of adipic acid (AA) and succinic acid (SA) in glutaric acid (GA) + acetone mixture and GA + n -butanol mixture were measured by dynamic method at atmospheric pressure. The mass fraction of GA ( w GA ) ranged from (0 t…

Analytical Chemistry and ChromatographyCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Poroelastic Theory Applied to the Adsorption-Induced Deformation of Vitreous Silica

Benoît Coasne、Coralie Weigel、A. Polian 等 9 位作者2014-11-10The Journal of Physical Chemistry B

When vitreous silica is submitted to high pressures under a helium atmosphere, the change in volume observed is much smaller than expected from its elastic properties. It results from helium penetration into the interstitial free volume of the glass network. We present here the results of concurrent spectroscopic expe…

Geological and Geochemical AnalysisGlass properties and applicationsCatalysis and Oxidation Reactions

Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn( ii ) bisporphyrin

Sk Asif Ikbal、Sanfaori Brahma、Sankar Prasad Rath2014-11-10Chemical Communications

For the first time, a clear and unambiguous rationalization of chirality induction, inversion and subsequent amplification process has been demonstrated for the 1 : 1 sandwich and 2 : 3 host-guest supramolecular complexes consisting of Zn(II) host and chiral diamines as guests that has so far remained the most outstan…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

Green synthesis of reduced graphene oxide and its reinforcing effect on natural rubber composites

Lianbin Wu、Peng Qu、Ruifeng Zhou 等 5 位作者2014-11-10High Performance Polymers

A green and facile approach to produce graphene using an environmentally friendly reagent, namely proanthocyanidin (PC) as a reducing agent was developed. The obtained graphene (PC-rGO) was characterized using Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis and X-ray photoelectro…

Graphene research and applicationsPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Rapid reversible phototuning of lasing frequency in dye-doped cholesteric liquid crystal

T. V. Mykytiuk、Igor P. Iľchishin、O. Yaroshchuk 等 6 位作者2014-11-10Optics Letters

Lasing in induced cholesteric liquid crystal (CLC) containing highly photosensitive azo chiral dopant (ChD) and pyrromethene laser dye was investigated. Due to the absence of excitation energy transfer from the dye molecules to the molecules of ChD in such a system, a low lasing threshold was achieved. When using viol…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochemistry and Electron Transfer Studies

Formation of core–shell-structured Zn 2 SnO 4 –carbon microspheres with superior electrochemical properties by one-pot spray pyrolysis

Young Jun Hong、Yun Chan Kang2014-11-10Nanoscale

Core-shell structured Zn2SnO4-carbon microspheres with different carbon contents are prepared by one-pot spray pyrolysis without any further heating process. A Zn2SnO4-carbon composite microsphere is prepared from one droplet containing Zn and Sn salts and polyvinylpyrrolidone (PVP). Melted PVP moves to the outside of…

ZnO doping and propertiesSupercapacitor Materials and FabricationGas Sensing Nanomaterials and Sensors

Field-effect and capacitive properties of water-gated transistors based on polythiophene derivatives

Rossella Porrazzo、Sebastiano Bellani、Alessandro Luzio 等 7 位作者2014-11-10APL Materials

Recently, water-gated organic field-effect transistors (WGOFET) have been intensively studied for their application in the biological field. Surprisingly, a very limited number of conjugated polymers have been reported so far. Here, we systematically explore a series of polythiophene derivatives, presenting different…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Benzothiadiazole‐Containing Conjugated Polyelectrolytes for Biological Sensing and Imaging

Ruoyu Zhan、Bin Liu2014-11-10Macromolecular Chemistry and Physics

This article summarizes the recent advances of benzothiadiazole (BT)‐containing conjugated polyelectrolytes (CPEs) for biological sensing and imaging. After a brief introduction of the molecular design principles, the application of linear BT‐containing CPEs as multicolor or light‐up probes for visual sensing of biomo…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Giant increase of critical current density and vortex pinning in Mn doped KxFe2−ySe2 single crystals

Mingtao Li、La Chen、Wen‐Long You 等 5 位作者2014-11-10Applied Physics Letters

We report a comparative study of the critical current density (Jc) and vortex pinning among pure and Mn doped KxFe2−ySe2 single crystals. It is found that the Jc values can be greatly improved by Mn doping and post-quenching treatment when comparing to pristine pure sample. In contrast to pure samples, an anomalous se…

Physics of Superconductivity and MagnetismCorporate Taxation and AvoidanceIron-based superconductors research

Spatial Structuring of a Supramolecular Hydrogel by using a Visible‐Light Triggered Catalyst

Chandan Maity、Wouter E. Hendriksen、Jan H. van Esch 等 4 位作者2014-11-10Angewandte Chemie

Abstract Spatial control over the self‐assembly of synthetic molecular fibers through the use of light‐switchable catalysts can lead to the controlled formation of micropatterns made up of hydrogel structures. A photochromic switch, capable of reversibly releasing a proton upon irradiation, can act as a catalyst for i…

Supramolecular Chemistry and ComplexesSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Preparation of superhydrophobic nanocalcite crystals using Box–Behnken design

Said M. El‐Sheikh、Ahmed Barhoum、Samya El-Sherbiny 等 6 位作者2014-11-10Arabian Journal of Chemistry

Superhydrophobic nanocalcite crystals were prepared via an adjusted aqueous reaction of CaO, CO2 gas and sodium oleate. Box–Behnken design was used to optimize the preparation parameters such as CaO concentration, CO2 gas flow rate and surfactant concentration. The results revealed that the produced CaCO3 is indexed t…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesLayered Double Hydroxides Synthesis and Applications

Effect of Incorporating Aromatic and Chiral Groups on the Dielectric Properties of Poly(dimethyltin esters)

Aaron F. Baldwin、Rui Ma、Tran Doan Huan 等 6 位作者2014-11-10Macromolecular Rapid Communications

High-dielectric constant materials are critical for numerous applications such as photovoltaics, photonics, transistors, and capacitors. There are numerous polymers used as dielectric layers in these applications but can suffer from having a low dielectric constant, small band gap, or ferroelectricity. Here, the struc…

Ferroelectric and Piezoelectric MaterialsDielectric materials and actuatorsSynthesis and properties of polymers

Washcoating of cordierite honeycomb with vanadia–tungsta–titania mixed oxides for selective catalytic reduction of NO with NH 3

Bo Liu、Jun Du、Xiaowei Lv 等 5 位作者2014-11-10Catalysis Science & Technology

The application of monolithic coated catalysts to NO <sub>x</sub> abatement is a crucial issue for practical applications to enhance the mechanical strength, economize the cost, facilitate recycling <italic>etc</italic> ., compared with the conventional monolithic extrusive catalysts.

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Introducing a Large Polar Tetragonal Distortion into Ba-Doped BiFeO3by Low-Temperature Fluorination

Oliver Clemens、Robert Kruk、Eric A. Patterson 等 9 位作者2014-11-10Inorganic Chemistry

This article reports on the synthesis and crystallographic and magnetic structure of barium-doped BiFeO3 compounds with approximate composition Bi(1-x)Ba(x)FeO(3-x/2), as well as those of the fluorinated compounds Bi(1-x)Ba(x)FeO(3-x)F(x) (both with x = 0.2, 0.3), prepared by low-temperature fluorination of the oxide…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAdvanced Condensed Matter Physics