Materials Literature
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We report different mesoporosity-dependent and functional group-dependent cytotoxicity and endocytosis of various silica nanomaterials on suspended and adherent cells. This dependency further varied with incubation time and particle dosage, and appeared to be associated with the particles' endocytotic efficiency and t…
Gradient-corrected density functional theory (DFT) computations were performed to investigate the geometry, electronic property, formation energy, and reactivity of Stone-Wales (SW) defects in zigzag-edge and armchair-edge boron nitride nanoribbons (BNNRs). The formation energies of SW defects increase with an increas…
We propose a new scaling theory for general quantum breakdown phenomena. We show, taking Landau-Zener type breakdown as a particular example, that the breakdown phenomena can be viewed as a quantum phase transition for which the scaling theory is developed. The application of this new scaling theory to Zener type brea…
Rietveld profiles, Moessbauer spectra and x-ray absorption fine structure (XAFS) were analyzed through the structural phase transition at Ts = 355 K in HoBaCo4O7. Excess of the oxygen content over O7 was avoided via annealing the samples in argon flow at 600 degree C. Space groups (S.G.) Pbn21c and P63mc were used to…
We have mapped the molecular-atomic transition in liquid hydrogen using first principles molecular dynamics. We predict that a molecular phase with short-range orientational order exists at pressures above 100 GPa. The presence of this ordering and the structure emerging near the dissociation transition provide an exp…
Quantum transport properties through some multilevel quantum dots sandwiched between two metallic contacts are investigated by the use of Green's function technique. Here we do parametric calculations, based on the tight-binding model, to study the transport properties through such bridge systems. The electron transpo…
An external magnetic field has been applied in laterally coupled dots (QDs) and we have studied the QD properties related to charge decoherence. The significance of the applied magnetic field to the suppression of electron-phonon relaxation and dephasing rates has been explored. The coupled QDs have been studied by va…
Starting with a microscopic model based on the Kohn-Luttinger Hamiltonian and kinetic $p\text{\ensuremath{-}}d$ exchange combined with Boltzmann formula for conductivity we identify the scattering from magnetic Mn combined with the strong spin-orbit interaction of the GaAs valence band as the dominant mechanism of the…
Silks have a great potential as sustainable, ecologically benign commercial polymers. Here we discuss this fascinating bio-material by merging the biologist's with the polymer scientist's views i.e. combine insights into the characterisation and understanding of evolved structure, property and function in natural silk…
NaYbF(4): RE upconversion (UC) fluorescent nanoparticles (NPs) were synthesized with variable rare-earth dopants (RE= Er(3+), Tm(3+), or Ho(3+), or a combination of these ions), from rare-earth stearate precursors in a water-ethanol-oleic acid system by using a two-phase solvothermal method. The NPs were shown to emit…
Ag(2)O particles with different polyhedral shapes including octahedron, truncated octahedron, and cube were successfully synthesized by a simple wet-chemical method using silver nitrate, ammonia, and sodium hydroxide as raw materials at room temperature. Simply by tuning the concentration of starting materials, the sh…
The mechanical properties of self-assembled fibrillar networks are influenced by the specific intermolecular interactions that modulate fiber entanglements. We investigate how changing these interactions influences the mechanics of self-assembled nanofiber gels composed of peptide amphiphile (PA) molecules. PAs develo…
Heteroatom doping (e.g., boron and nitrogen) of graphitic carbon lattices affects various physicochemical properties of sp 2 carbon materials. The influence of nitrogen doping in carbon nanotubes (N-CNTs) on their electrochemical and electrical properties such as the differential capacitance, density of states at the…
Fluorescence targeted imaging in vivo has proven useful in tumor recognition and drug delivery. In the process of in vivo imaging, however, a high autofluorescence background could mask the signals from the fluorescent probes. Herein, a high contrast upconversion luminescence (UCL) imaging protocol was developed for t…
The stability of proteins in aqueous solution is routinely enhanced by cosolvents such as glycerol. Glycerol is known to shift the native protein ensemble to more compact states. Glycerol also inhibits protein aggregation during the refolding of many proteins. However, mechanistic insight into protein stabilization an…
ADVERTISEMENT RETURN TO ISSUEReviewNEXTSingle-Electron Transfer and Single-Electron Transfer Degenerative Chain Transfer Living Radical PolymerizationBrad M. Rosen and Virgil Percec*View Author Information Roy & Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania…
We developed a simple chemical method to obtain bulk quantities of N-doped, reduced graphene oxide (GO) sheets through thermal annealing of GO in ammonia. X-ray photoelectron spectroscopy (XPS) study of GO sheets annealed at various reaction temperatures reveals that N-doping occurs at a temperature as low as 300 degr…
In this paper, the influence of deep cryogenic treatment (DCT) on mechanical properties of two commercial steels is analysed. Hardened AISI 302 stainless steel and 18NiCrMo5 carburized steel specimens were subjected to DCT after standard treatments. For both materials, the fatigue behaviour is a key property consideri…
A metal-organic coordination polymer, [Mn(C6O6H10)(H2O)] n (1), has been synthesized and characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction. Thermogravimetric analysis and EPR spectrum of the compound have also been studied. Light pink crystals of the complex are monoclinic,…
Abstract In this work, ring opening insertion polymerization (ROIP) of ε‐caprolactone (ε‐CL) using a series of hydrogen phosphonates (H‐phosphonates) as initiators was investigated. The ROIP occurred by a coordination‐insertion mechanism containing two steps. First, the carbonyl carbon was attacked by the phosphorus a…