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Petrophysical characteristics of the sandstones used in the construction of the Monumental Heritage of Ciudad Rodrigo, Salamanca. Spain

M. J. Varas、E. Molina、M. A. Vicente2003-03-01Materiales de Construccion

Knowledge of the petrophysical characteristics of stones used in construction is evidently advantageous in the sense that it can help avoid wasting time and future disappointments when attempting to assess the results both in restoration work and in actual construction work. However, if the material used is sandstone,…

X-ray Study of Freezing and Melting of Water Confined within SBA-15

Kunimitsu Morishige、Hiroshi Iwasaki2003-03-01Langmuir

To examine the freezing and melting behavior of water in partially filled pores of porous silica, we performed X-ray diffraction measurements of water confined inside the cylindrical pores of SBA-15 with a pore radius of 3.9 nm as a function of temperature and pore filling. The freezing temperature increased continuou…

Zeolite Catalysis and SynthesisAerogels and thermal insulationMesoporous Materials and Catalysis

Spinning and Characterization of Conducting Microfibers

Hidenori Okuzaki、Masayoshi Ishihara2003-03-01Macromolecular Rapid Communications

Abstract Conducting microfibers of poly(3,4‐ethylenedioxythiophene) doped with poly(4‐styrene sulfonate), having a diameter ranging between 4.6 and 16 μm, were fabricated by a wet‐spinning technique. The as‐spun microfiber had no notable orientation of polymer chains with poor crystallinity, and electrical conductivit…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAdvanced Sensor and Energy Harvesting Materials

Theory of Composites. Cambridge Monographs on Applied and Computational Mathematics

GW Milton、AT Sawicki2003-03-01Applied Mechanics Reviews

3R27. Theory of Composites. Cambridge Monographs on Applied and Computational Mathematics. - GW Milton (Dept of Math, Univ of Utah, Salt Lake City UT). Cambridge UP, Cambridge, UK. 2002. 719 pp. ISBN 0-521-78125-6. $80.00. AT Sawicki (Inst of Hydro-Eng, Koscierska 7, Gdansk-Oliwa, 80-953, Poland).This is a book about…

Material Properties and ApplicationsAdvanced Mathematical Modeling in EngineeringComposite Material Mechanics

Defect structures in MgB2 wires introduced by hot isostatic pressing

X. Z. Liao、A. Serquis、Y. T. Zhu 等 9 位作者2003-03-01arXiv

The microstructures of MgB2 wires prepared by the powder-in-tube technique and subsequent hot isostatic pressing were investigated using transmission electron microscopy. Large amount of crystalline defects including small angle twisting, tilting, and bending boundaries, in which high densities of dislocations reside,…

SuperconductivityMaterials Science

Electron Spin-Relaxation Times of Phosphorus Donors in Silicon

A. M. Tyryshkin、S. A. Lyon、A. V. Astashkin 等 4 位作者2003-03-01arXiv

Pulsed electron paramagnetic resonance measurements of donor electron spins in natural phosphorus-doped silicon (Si:P) and isotopically-purified 28Si:P show a strongly temperature-dependent longitudinal relaxation time, T1, due to an Orbach process with DeltaE = 126 K. The 2-pulse echo decay is exponential in 28Si:P,…

Materials Science

Condensation and Slow Dynamics of Polar Nanoregions in Lead Relaxors

D. La-Orauttapong、O. Svitelskiy、J. Toulouse2003-03-01arXiv

It is now well established that the unique properties of relaxor ferroelectrics are due to the presence of polar nanoregions (PNR's). We present recent results from Neutron and Raman scattering of single crystals of PZN, PZN-xPT, and PMN. Both sets of measurements provide information on the condensation of the PNR's a…

Materials Science

Novel Inorganic−Organic-Layered Structures: Crystallographic Understanding of Both Phase and Morphology Formations of One-Dimensional CdE (E = S, Se, Te) Nanorods in Ethylenediamine

Zhaoxiang Deng、Libo Li、Yadong Li2003-03-01Inorganic Chemistry

A novel class of inorganic-organic-layered structures, CdE.0.5en (E = S, Se, Te; en = ethylenediamine), were obtained through reactions between elemental S, Se, or Te and Cd(2+) at appropriate solvothermal temperatures. These compounds contain atomic sheets of inorganic CdE frameworks spaced by ethylenediamine molecul…

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

A new approach to the diagnosis of solid insulation systems based on PD signal inference

A. Cavallini、G.C. Montanari、A. Contin 等 4 位作者2003-03-01IEEE Electrical Insulation Magazine

The authors have developed digital instrumentation that can measure the amplitude, shape, phase, and number of pulses per cycle. Examples are given of results obtained from an induction motor, a hydrogenerator, a polymeric cable system with a defective joint, and a high-voltage current transformer.

Electrostatic Discharge in ElectronicsHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Control of Biodegradability of Polylactide via Nanocomposite Technology

Suprakas Sinha Ray、Kazunobu Yamada、Masami Okamoto 等 4 位作者2003-03-01Macromolecular Materials and Engineering

Abstract Polymer/layered silicate nanocomposite technology is not only suitable for the significant improvement of mechanical and various other materials properties of virgin polymers, it is also suitable to enhance the rate of biodegradation of biodegradable polymers such as polylactide. The biodegradability of polyl…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Electrospinning of Collagen Type II: A Feasibility Study

Jamil A. Matthews、Eugene D. Boland、Gary E. Wnek 等 5 位作者2003-03-01Journal of Bioactive and Compatible Polymers

Collagen is the natural scaffolding found in all tissues and has been explored extensively for use as a tissue engineering scaffold with limited success. In this feasibility study, the electrospinning of collagen type II and subsequent chondrocyte seeding was investigated for potential use in cartilage tissue engineer…

Silk-based biomaterials and applicationsElectrospun Nanofibers in Biomedical ApplicationsCollagen: Extraction and Characterization

Relaxor ferromagnetic behavior below the antiferromagnetic transition in La0.5Ca0.5MnO3

R. Mahendiran、A. Maignan、C. Martin 等 5 位作者2003-03-01arXiv

A detailed reinvestigation of magnetization in La0.5Ca0.5MnO3 reveals that although a field of H = 7 T applied at T = 5 K after zero field cooling is insufficient to convert the low temperature charge ordered antiferromagnetic phase into ferromagnetic, annealing in a magnetic field as small as H = 1 T induces ferromag…

Materials Science

Synthesis of Highly Porous Yttria‐Stabilized Zirconia by Tape‐Casting Methods

Martha Boaro、John M. Vohs、Raymond J. Gorte2003-03-01Journal of the American Ceramic Society

Porous ceramics of Y 2 O 3 ‐stabilized ZrO 2 (YSZ) were prepared by tape‐casting methods using both pyrolyzable pore formers and NiO followed by acid leaching. The porosity of YSZ wafers increased in a regular manner with the mass of graphite or polymethyl methacrylate (PMMA) to between 60% and 75% porosity. SEM indic…

Catalytic Processes in Materials ScienceAdvanced ceramic materials synthesisAdvancements in Solid Oxide Fuel Cells

Chemically modified smectites

Peter Komadel2003-03-01Clay Minerals

Abstract This paper summarizes recent results obtained on chemical modifications of smectites. These include replacement of exchangeable cations with protons, a process connected with smectite autotransformation – attack of protons on the layers and liberation of central atoms from the octahedral and tetrahedral sheet…

Clay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

Leucine Biosynthesis in Fungi: Entering Metabolism through the Back Door

Gunter B. Kohlhaw2003-03-01Microbiology and Molecular Biology Reviews

After exploring evolutionary aspects of branched-chain amino acid biosynthesis, the review focuses on the extended leucine biosynthetic pathway as it operates in Saccharomyces cerevisiae. First, the genes and enzymes specific for the leucine pathway are considered: LEU4 and LEU9 (encoding the alpha-isopropylmalate syn…

Enzyme Structure and FunctionFungal and yeast genetics researchMicrobial Metabolic Engineering and Bioproduction

Nanomechanics of carbon nanotubes and composites

Deepak Srivastava and、Chenyu Wei、Kyeongjae Cho2003-03-01OpenAlex

Computer simulation and modeling results for the nanomechanics of carbon nanotubes and carbon nanotube-polyethylene composite materials are described and compared with experimental observations. Young’s modulus of individual single-wall nanotubes is found to be in the range of 1 TPa within the elastic limit. At room t…

Carbon Nanotubes in CompositesNanotechnology research and applicationsForce Microscopy Techniques and Applications

Compatibilization of Immiscible Poly(propylene)/Polystyrene Blends Using Clay

Yong Wang、Qin Zhang、Qiang Fu2003-03-01OpenAlex

Abstract Inorganic clay was investigated as a compatibilizer for immiscible poly(propylene)/polystyrene blends. A substantial decrease in the number of polystyrene particles was seen after adding small amounts of an organically treated clay (2–5 wt.‐%) to the blends. A possible mechanism for this kind of compatibiliza…

Polymer composites and self-healingPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Predicting iron losses in soft magnetic materials with arbitrary voltage supply: an engineering approach

Aldo Boglietti、Andrea Cavagnino、M. Lazzari 等 4 位作者2003-03-01OpenAlex

We propose a new approach for predicting iron losses in soft magnetic materials with any voltage supply, starting from the knowledge of the iron losses with a sinusoidal or pulsewidth modulation supply. The model is based on the separation of the loss contributions due to hysteresis, eddy currents, and excess losses w…

Non-Destructive Testing TechniquesMagnetic Properties and ApplicationsElectric Motor Design and Analysis

Size Evolution of Alkanethiol-Protected Gold Nanoparticles by Heat Treatment in the Solid State

Takami Shimizu、Toshiharu Teranishi、Hasegawa Satoshi 等 4 位作者2003-03-01OpenAlex

A simple method is proposed to control the size of alkanethiol-protected Au nanoparticles by heat treatment in the solid state. The mean diameter of the Au nanoparticles prepared by Brust's two-phase method (∼1.5 nm) was evolved to 3.4−9.7 nm by heating to 150−250 °C in air. The uniform growth of nanoparticles was not…

Nanocluster Synthesis and Applicationsnanoparticles nucleation surface interactionsGold and Silver Nanoparticles Synthesis and Applications