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Vanadium-catalyzed epoxidations. 2. Highly stereoselective epoxidations of acyclic homoallylic alcohols predicted by a detailed transition-state model

Edward D. Mihelich、Karen Daniels、David Eickhoff1981-12-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVanadium-catalyzed epoxidations. 2. Highly stereoselective epoxidations of acyclic homoallylic alcohols predicted by a detailed transition-state modelEdward D. Mihelich, Karen Daniels, and David J. EickhoffCite this: J. Am. Chem. Soc. 1981, 103, 25, 7690–7692Publication Date…

Oxidative Organic Chemistry ReactionsOrganic Chemistry Cycloaddition ReactionsPolyoxometalates: Synthesis and Applications

The effect of phonon-grain boundary scattering on the lattice thermal conductivity and thermoelectric conversion efficiency of heavily doped fine-grained, hot-pressed silicon germanium alloy

D.M. Rowe、V. Shukla1981-12-01Journal of Applied Physics

The preparation of fine-grained high-density compacts of heavily doped n-type Si63.5Ge36.5 alloy and the measurement of their thermal diffusivity over the temperature range 300 to 1150 K are reported. The compacts investigated possessed grain sizes (L) in the range 10<L<25 μm, 5<L<10 μm, an…

Thermal Radiation and Cooling TechnologiesAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Sliding behaviour and dislocation structures in aluminium grain boundaries

Hiroyuki Kokawa、Tadao Watanabe、Seiichi Karashima1981-12-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

Dislocation structures of grain boundaries whose sliding behaviour had already been studied, have been observed by transmission electron microscopy of the slid grain boundaries. The ordered (coincidence) and random boundaries exhibited quite different sliding behaviour and dislocation structures. In the case of ordere…

Microstructure and mechanical propertiesCopper Interconnects and ReliabilityMetal and Thin Film Mechanics

Bibliografía

Equipo Editorial1981-12-01Materiales de Construccion

Distribution of Iodine in Doped Polyacetylene Filme

A. Jánossy、L. Pogány、S. Pekker 等 4 位作者1981-12-01Molecular crystals and liquid crystals

The distribution of iodine in polyacetylene doped under conditons typical for most published work is investigated by energy dispersive X-ray analysis under an electron microscope. The 9.1 GHz dielectric constant of a series of iodine doped (CH)x is measured as a function of temperature. From the X-ray analysis we conc…

Transition Metal Oxide NanomaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Electronic Excitations in Polyacetylene

Shahrokh Etemad、A. J. Heeger、L. Lauchlan 等 5 位作者1981-12-01Molecular crystals and liquid crystals

Recent experimental results on light scattering and absorption in polyacetylene are reviewed, and interpreted in terms of the soliton model. The data indicate that injection of an electron-electron (hole-hole) pair by chemical doping or photoinjection of an electron-hole pair invariably distort the lattice leading to…

Analytical Chemistry and SensorsConducting polymers and applicationsMechanical and Optical Resonators

Transport, Magnetic and Structural Studies of Polyacetylene

Alan J. Heeger、A. G. Maciarmid1981-12-01Molecular crystals and liquid crystals

Experimental progress is reviewed with emphasis on magnetic and transport studies. The magnetic results are fully consistent with the soliton doping mechanism; the decrease in Curie-law contribution has been demonstrated; the Pauli term remains small (Y < 0.07) and is apparently zero in the limit of completely uniform…

Mechanical and Optical ResonatorsOrganic Electronics and PhotovoltaicsConducting polymers and applications

Reaction between nitrogen oxide (NOx) and ammonia on iron oxide-titanium oxide catalyst

Akira Kato、Shimpei Matsuda、Tomoichi Kamo 等 6 位作者1981-12-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReaction between nitrogen oxide (NOx) and ammonia on iron oxide-titanium oxide catalystAkira Kato, Shimpei Matsuda, Tomoichi Kamo, Fumito Nakajima, Hiroshi Kuroda, and Tsuneo NaritaCite this: J. Phys. Chem. 1981, 85, 26, 4099–4102Publication Date (Print):December 1, 1981Publ…

Iron oxide chemistry and applicationsCatalytic Processes in Materials Science

Responses of cat corneal sensory receptors to mechanical and thermal stimulation.

Carlos Belmonte、Fernando Giráldez1981-12-01The Journal of Physiology

1. The afferent responses evoked by mechanical and thermal stimulation of the cat cornea were recorded extracellularly from strands of long and mixed ciliary nerves under deep anaesthesia. 94% of the units studied (n = 53) responded consistently to both stimuli. 2. Conduction velocities, measured by electrical stimula…

Molecular spectroscopy and chiralityPhotochromic and Fluorescence ChemistryNeurobiology and Insect Physiology Research

Epitaxial crystallization of polyethylene on organic substrates: A reappraisal of the mode of action of selected nucleating agents

J. C. Wittmann、Bernard Lotz1981-12-01Journal of Polymer Science Polymer Physics Edition

Abstract Electron microscopy and electron diffraction studies show that polyethylene crystallizes epitaxially onto crystals of homologous series of (i) condensed aromatic hydrocarbons and (ii) linear polyphenyls. The contact planes of the PE chain‐folded lamellae with the (001) faces of the substrate crystals are foun…

Polymer Nanocomposites and PropertiesFiber-reinforced polymer compositesPolymer crystallization and properties

The Continuous Damage Theory of Brittle Materials, Part 1: General Theory

Dusan Krajcinovic、Geale Fonseka1981-12-01OpenAlex

The paper focuses on the establishment of the damage law consistent with the adopted physical interpretation of the damage. The model is developed within the framework of the general thermodynamics theory. In addition, the model incorporates a rigorous mathematical description of the damage growth kinematics including…

High-Velocity Impact and Material BehaviorFatigue and fracture mechanicsStructural Response to Dynamic Loads

Lanthanide ion luminescence probes of the structure of biological macromolecules

William DeW. Horrocks、Daniel R. Sudnick1981-12-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLanthanide ion luminescence probes of the structure of biological macromoleculesWilliam D. Horrocks, Jr. and Daniel R. SudnickCite this: Acc. Chem. Res. 1981, 14, 12, 384–392Publication Date (Print):December 1, 1981Publication History Published online1 May 2002Published inis…

Radioactive element chemistry and processingMolecular Sensors and Ion DetectionLanthanide and Transition Metal Complexes

Unit-cell refinement from powder diffraction scans

G. S. Pawley1981-12-01OpenAlex

A procedure for the refinement of the crystal unit cell from a powder diffraction scan is presented. In this procedure knowledge of the crystal structure is not required, and at the end of the refinement a list of indexed intensities is produced. This list may well be usable as the starting point for the application o…

X-ray Diffraction in CrystallographyCrystallography and molecular interactionsNuclear Physics and Applications

Polymorphic transitions in single crystals: A new molecular dynamics method

Michele Parrinello、A. Rahman1981-12-01OpenAlex

A new Lagrangian formulation is introduced. It can be used to make molecular dynamics (MD) calculations on systems under the most general, externally applied, conditions of stress. In this formulation the MD cell shape and size can change according to dynamical equations given by this Lagrangian. This new MD technique…

Enzyme Structure and FunctionProtein Structure and DynamicsMicrostructure and mechanical properties