Materials Literature
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We present a theory which explains (in the quasistatic limit) the experimentally observed [R. Gordon, {\it et al}, Phys. Rev. Lett. {\bf 92}, 037401 (2004)] squared dependence of the depolarization ratio on the aspect ratio of the holes, as well as other features of extraordinary light transition. We calculated the ef…
Intrinsic and experimental mechanisms frequently lead to broadening of spectral features in excited-state spectroscopies. For example, intrinsic broadening occurs in x-ray absorption spectroscopy (XAS) measurements of heavy elements where the core-hole lifetime is very short. On the other hand, nonresonant x-ray Raman…
We have fabricated a lateral double barrier magnetic tunnel junction (MTJ) which consists of a single self-assembled InAs quantum dot (QD) with ferromagnetic Co leads. The MTJ shows clear hysteretic tunnel magnetoresistance (TMR) effect, which is evidence for spin transport through a single semiconductor QD. The TMR r…
Alkali-metal atoms (Li, Na, K, Rb, Cs), dimers, and $(2\ifmmode\times\else\texttimes\fi{}2)$ monolayers on a graphite (0001) surface have been studied using density functional theory, pseudopotentials, and a periodic substrate. The adatoms bind at the hollow site (graphite hexagon), with Li lying closest to $(1.84\pha…
Oscillatory Zoning (OZ) is a phenomenon exhibited by many geologically formed crystals. It is characterized by quasiperiodic oscillations in the composition of a solid solution, caused by self-organization. We present a model for OZ. The growth mechanism applied includes species diffusion through the solution bulk, pa…
We propose a mesoscopic model that explains the discrepancy (at a factor of 2–3) between experimentally measured yield stresses of bcc metals at low temperatures and typical Peierls stresses determined by atomistic simulations of isolated screw dislocations. The model involves a Frank–Read-type source emitting disloca…
This review details the recent advancements in the design of mesoporous silica nanomaterials for controlled release drug, gene and neurotransmitter delivery applications. The high surface area (>900 m2/g), tunable pore diameter (2-20 nm) and uniform mesoporous structure (hexagonal channels or cubic pores) of the mesop…
Neutron powder diffraction and single crystal x-ray resonant magnetic scattering measurements suggest that Dy plays an active role in enhancing the ferroelectric polarization in multiferroic DyMnO3 above T(Dy)(N)=6.5 K. We observe the evolution of an incommensurate ordering of Dy moments with the same periodicity as t…
With the use of first-principles simulations, low barrier CO oxidation reactions are predicted to occur via a Langmuir−Hinshelwood or an Eley−Rideal mechanism, on two-dimensional gold nanocluster islands adsorbed on two-layer MgO films that are supported on Mo(100). Underlying the emergent catalytic activity, predicte…
We have performed a comprehensive analysis of water molecules at the protein-ligand interfaces observed in 392 high-resolution crystal structures. There are a total of 1829 ligand-bound water molecules in these 392 complexes; 18% are surface water molecules, and 72% are interfacial water molecules. The number of ligan…
Liposomes have a decade-long clinical presence as nanoscale delivery systems of encapsulated anthracycline molecules. However, their use as delivery systems of nanoparticles is still in the preclinical development stages. Liposome-nanoparticle hybrid constructs present great opportunities in terms of nanoscale deliver…
Tissue-engineered oral mucosal equivalents have been developed for clinical applications and also for in vitro studies of biocompatibility, mucosal irritation, disease, and other basic oral biology phenomena. This paper reviews different tissue-engineering strategies used for the production of human oral mucosal equiv…
This review considers research related to internal sizing agents. Such chemicals, when added as emulsions or in micellar form to slurries of cellulosic fibers before paper is made, can make the product resist water and other fluids. Significant progress has been achieved to elucidate the modes of action of alkylketene…
Abstract 1D poly(3,4‐ethylenedioxythiophene) (PEDOT) nanomaterials, including ellipsoidal nanoparticles, nanorods, and nanotubes, are fabricated via chemical oxidation polymerization in reverse (water‐in‐oil) microemulsions. The reverse cylindrical micelles are prepared with sodium bis(2‐ethylhexyl) sulfosuccinate (AO…
A model is proposed to study the electronic structure of slightly curved graphene sheets with an arbitrary number of pentagon-heptagon pairs and Stone-Wales defects based on a cosmological analogy. The disorder induced by curvature produces characteristic patterns in the local density of states that can be observed in…
We study the fluctuation properties and return-time statistics on inhomogeneous scale-free networks using packets moving with two different dynamical rules; random diffusion and locally navigated diffusive motion with preferred edges. Scaling in the fluctuations occurs when the dispersion of a quantity at each node or…
A combination of Cu L-edge and S K-edge X-ray absorption data and density functional theory (DFT) calculations has been correlated with 33S electron paramagnetic resonance superhyperfine results to obtain the dipole integral (Is) for the S 1s-->3p transition for the dithiolene ligand maleonitriledithiolate (MNT) in (T…
Intense research has led to a more comprehensive understanding of cancer at the genetic, molecular, and cellular levels providing an avenue for methods of increasing antitumor efficacy of drugs while reducing systemic side effects. Nanoparticulate technology is of particular use in developing a new generation of more…
Electrical conductivity (σdc) of the cellular Si∕SiC ceramic composites has been measured over a temperature range of 25–1073K, while the thermoelectric power (S) has been measured over 25–300K. Remarkably, these cellular compounds developed through the biomimetic route—where the ceramic system grows within a plant bi…
Cubic GaN layers were grown by plasma-assisted molecular beam epitaxy on 3C-SiC (001)substrates. In situ reflection high energy electron diffraction was used to quantitatively determine the Ga coverage of the GaN surface during growth. Using the intensity of the electron beam as a probe,optimum growth conditions of c-…