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Molybdenum and tungsten complexes with unusual coordination modes of a dibenzotetraaza[14]annulene ligand. From bidentate to tridentate scorpiand coordination by reaction with acetonitrile and from bidentate to tetradentate coordination via electrochemistry

Jean‐Marc Giraudon、Dominique Mandon、J. Sala‐Pala 等 7 位作者1990-02-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolybdenum and tungsten complexes with unusual coordination modes of a dibenzotetraaza[14]annulene ligand. From bidentate to tridentate scorpiand coordination by reaction with acetonitrile and from bidentate to tetradentate coordination via electrochemistryJean Marc Giraudon…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

Inhibition of Barium Sulfate Deposition by Polycarboxylates of Various Molecular Structures

M. C. van dor Leeden、G.M. van Rosmalen1990-02-01SPE Production Engineering

Summary To establish a relationship between the molecular structure of polycarboxylates and their growth-retarding influence on barium sulfate, seeded-suspension-growth experiments were performed at various inhibitor concentrations and pH values. Two types of polycarboxylates with a molecular structure based on either…

Calcium Carbonate Crystallization and InhibitionLayered Double Hydroxides Synthesis and ApplicationsElectrophoretic Deposition in Materials Science

Extinction in finite perfect crystals: case of a sphere

M. Haddad、P. Becker1990-02-01Acta Crystallographica Section A Foundations of Crystallography

The extinction factor in finite perfect crystals is calculated from pure dynamical theory. In particular, a detailed solution is proposed for a sphere, in which case the extinction factor depends on the Bragg angle θ and the parameter ( R / Λ ), where R is the radius of the crystal and Λ the extinction length. An appr…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsX-ray Diffraction in Crystallography

Raman intensities and interference effects for thin films adsorbed on metals

Joel W. Ager、Douglas Veirs、Gerd M. Rosenblatt1990-02-01The Journal of Chemical Physics

Large oscillations in the vibrational Raman intensity have been observed for thin films adsorbed on a metal substrate as a function of film thickness. The systems studied, N2 and O2 physisorbed on Ag(111) at 14±1 K, have previously been shown to be unenhanced, i.e., the observations are not caused by the surface enhan…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesRandom lasers and scattering media

Nonlinear Optical Effects in Polymer Dispersed Liquid Crystals

G. Cipparrone、Cesare Umeton、G. Arabia 等 5 位作者1990-02-01Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics

We report the observation of optical nonlinearities induced by thermal effects in polymer dispersed liquid crystals. Experimental data about optical switching of a low power laser beam are presented and discussed

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesNonlinear Optical Materials Studies

A Review of Treatment Process Options to Meet the EC Sludge Directive

A. M. Bruce、E. B. Pike、W. J. FISHER1990-02-01Water and Environment Journal

ABSTRACT New UK regulations from June 1989 will enforce the provisions of an EC Directive on the use of sewage sludge in agriculture. Among the requirements is one that sludge should be treated before surface application to farmland. Treatment is needed to reduce ‘significantly’ both the fermentability of sludge and t…

Metallurgy and Material Science

Effect of Powder Characteristics on Microstructures and Dielectric Properties of (Ba,Nb)‐Doped Titania Ceramics

Jenn‐Ming Wu、Chi‐Jen Chen1990-02-01Journal of the American Ceramic Society

The effect of powder characteristics on the microstructures and dieletric properties of (Ba,Nb)‐doped TiO 2 ceramics was investigated. Two powders were prepared: one by coprecipitation and the other from mixing of reagent oxides. The powder characteristics were determined by TEM, X‐ray powder diffraction, SEM, and cen…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesMicrowave Dielectric Ceramics Synthesis

Structure and Reduction and Mixed Copper‐Aluminum Oxide

V. Patrick、George R. Gavalas1990-02-01Journal of the American Ceramic Society

Mixed oxides of copper and aluminum were prepared in porous form by the citrate process under various calcination conditions. The oxide samples were characterized by several techniques to determine chemical structure and texture. Atomic absorption spectroscopy provided the fractions of copper soluble and insoluble in…

ZnO doping and propertiesCatalytic Processes in Materials ScienceIndustrial Gas Emission Control

Direct metalation of p-bromopolystyrene using highly reactive copper and the preparation and reaction of highly reactive copper bound to an insoluble polymer

Richard A. O’Brien、Reuben D. Rieke1990-02-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDirect metalation of p-bromopolystyrene using highly reactive copper and the preparation and reaction of highly reactive copper bound to an insoluble polymerRichard A. O'Brien and Reuben D. RiekeCite this: J. Org. Chem. 1990, 55, 3, 788–790Publication Date (Print):February 1…

Organometallic Complex Synthesis and CatalysisSynthesis and properties of polymers

Inhibition of Oxidation of Iron in Environments Containing Chlorine at 1100 and 1200 K

S. Y. Lee、M. J. McNallan1990-02-01Journal of The Electrochemical Society

The oxidation of iron in gas mixtures consisting of Ar, , and at 1100 and 1200 K has been investigated by thermogravimetric analysis and examination of the corrosion products of the process by scanning electron microscopy and x‐ray diffraction analysis. The results of the experiments have been compared with theoretica…

High-Temperature Coating BehaviorsThermal and Kinetic AnalysisIndustrial Gas Emission Control

Zinc Oxide Thin Films Prepared by the Electron-Cyclotron-Resonance Plasma Sputtering Method

Yoshio Manabe、Tsuneo Mitsuyu1990-02-01Japanese Journal of Applied Physics

Zinc oxide (ZnO) thin films have been prepared by a sputtering deposition utilizing electron-cyclotron-resonance (ECR) plasma. An X-ray diffraction analysis indicated that the ZnO films were highly c -axis oriented. The electrical resistivity of ZnO films is as high as 2.5 MΩcm. It is confirmed that the ZnO films exhi…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsAcoustic Wave Resonator Technologies

Transformation of the octagonal quasicrystal into the β-Mn-type crystalline structure

Ning Wang、K. H. Kuo1990-02-01Philosophical Magazine Letters

A series of electron diffraction patterns displaying continuous transformation of the octagonal quasicrystal into the β-Mn type structure were obtained in a rapidly quenched Cr-Ni-Si alloy. This transformation is interpreted in terms of a gradual introduction of short-range periodical translational order to the octago…

Microstructure and mechanical propertiesIntermetallics and Advanced Alloy PropertiesQuasicrystal Structures and Properties

Long and Short-Range Effects in SERS from Silver

I. Mrozek、A. Otto1990-02-01Europhysics Letters (EPL)

A clean silver island film prepared in UHV was covered at about 28 K first with one monolayer of C 5 D 5 N and afterwards exposed to a quantity of C 5 H 5 N corresponding to 4 monolayers (or vice versa ). Raman scattering showed an intensity enhancement of about 2 orders of magnitude confined to the isotopic species a…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanocluster Synthesis and Applications

Kinetics of Oxygen Gas Evolution on Hydrous Rhodium Oxide Films

E. J. O’Sullivan、L.D. Burke1990-02-01Journal of The Electrochemical Society

The activity of rhodium for oxygen gas evolution in base is significantly enhanced by the presence of a thick, hydrous oxide film which is produced by repetitive potential cycling. An increase in oxygen evolution rate of up to three orders of magnitude was obtained on growing these films; the latter were found to be s…

Electrocatalysts for Energy ConversionSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Fluorine generation by gamma radiolysis of a fluoride salt mixture

L.M. Toth、L. K. Felker1990-02-01Radiation effects and defects in solids

Fluoride salt mixtures of composition, LiF–BeF2–ZrF4–UF4 (64.5, 30.3, 5.0, 0.13 mol%) were irradiated using 107–108 R/h gamma radiation to achieve high doses. Under these conditions, F2 is released from the salt and accumulates as an F2 overpressure until a 2 mol% damage limit in the crystal is reached. At this point,…

Luminescence Properties of Advanced MaterialsNuclear Materials and PropertiesNuclear materials and radiation effects

Progress in Electron Probe Microanalysis

G. F. Bastin、H. J. M. Heijligers1990-02-01Materialwissenschaft und Werkstofftechnik

No abstract.

Electron and X-Ray Spectroscopy TechniquesSurface and Thin Film PhenomenaAdvanced Materials Characterization Techniques

Quantum mechanical calculations on molecular sieves. 2. Model cluster investigation of silicoaluminophosphates

Éric G. Derouane、J. G. Fripiat、Roland von Ballmoos1990-02-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTQuantum mechanical calculations on molecular sieves. 2. Model cluster investigation of silicoaluminophosphatesEric G. Derouane, J. G. Fripiat, and R. Von BallmoosCite this: J. Phys. Chem. 1990, 94, 4, 1687–1692Publication Date (Print):February 1, 1990Publication History Publ…

Mesoporous Materials and CatalysisCrystal Structures and PropertiesClay minerals and soil interactions

Neutron diffraction and transmission electron microscopy study of hydrogen-induced phase transformations in Zr3Al

W. J. Meng、J. Faber、P.R. Okamoto 等 6 位作者1990-02-01Journal of Applied Physics

Hydrogen-induced phase transformations of the equilibrium intermetallic compound Zr3 Al have been studied by in situ elastic neutron scattering, x-ray diffraction, and transmission electron microscopy (TEM). TEM observations reveal two distinct modes of amorphous phase formation in Zr3 Al upon hydrogenation, namely, h…

Magnesium Alloys: Properties and ApplicationsHydrogen Storage and MaterialsIntermetallics and Advanced Alloy Properties

Influence of addition of potassium chloride to silver colloids

P. X. Zhang、Yurui Fang、W. N. Wang 等 5 位作者1990-02-01Journal of Raman Spectroscopy

Abstract The influence on silver colloids of the addition of KCI was directly investigated by means of transmission electron microscopy (TEM). It was found that the particle size increased and the surfaces of the crystal particles of the silver became covered with an overlayer. Additionally, the pattern of aggregation…

Gold and Silver Nanoparticles Synthesis and ApplicationsIron oxide chemistry and applicationsCopper-based nanomaterials and applications

A Linear Relationship between the Glass Transition Temperature and Local Distortion of Calcium Gallate, Barium Gallate, and Calcium Aluminate Glasses

Tetsuaki Nishida、Hiroshi Ide、Yoshimasa Takashima1990-02-01Bulletin of the Chemical Society of Japan

Abstract The isomer shift in the 57Fe-Mössbauer spectra of xCaO·(90−x)Ga2O3·10Fe2O3 (x=40–60) and xBaO ·(90−x)Ga2O3·10Fe2O3(x=65–70) glasses decreases gradually from 0.28 to 0.16 mm s−1 with increasing CaO or BaO contents. This indicates a formation of nonbridging oxygen atoms in the GaO4 and FeO4 tetrahedra. Large qu…

Glass properties and applicationsPhase-change materials and chalcogenidesPigment Synthesis and Properties