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A physical interpretation of impedance at conducting polymer/electrolyte junctions

Eleni Stavrinidou、Michele Sessolo、Bjørn Winther‐Jensen 等 5 位作者2014-01-01AIP Advances

We monitor the process of dedoping in a planar junction between an electrolyte and a conducting polymer using electrochemical impedance spectroscopy performed during moving front measurements. The impedance spectra are consistent with an equivalent circuit of a time varying resistor in parallel with a capacitor. We sh…

Fuel Cells and Related MaterialsConducting polymers and applicationsAnalytical Chemistry and Sensors

In situ111In-doping for achieving biocompatible and non-leachable 111In-labeled Fe3O4 nanoparticles

Jianfeng Zeng、Bing Jia、Ruirui Qiao 等 7 位作者2014-01-01Chemical Communications

The present study reports a new approach for synthesizing (111)In-radiolabeled biocompatible Fe3O4 nanoparticles. Radioactive (111)In is doped in situ into the lattice of Fe3O4 nanoparticles to achieve robust radiolabeling for accurately tracing PEGylated Fe3O4 particles in vivo.

Nanoparticle-Based Drug DeliveryRadiopharmaceutical Chemistry and ApplicationsMedical Imaging and Pathology Studies

Dinuclear magnesium, zinc and aluminum complexes supported by bis(iminopyrrolide) ligands: synthesis, structures, and catalysis toward the ring-opening polymerization of ε-caprolactone and rac-lactide

Weili Kong、Zhong‐Xia Wang2014-01-01Dalton Transactions

Synthesis and characterization of novel dinuclear magnesium, zinc and aluminum complexes supported by bis(iminopyrrolide) ligands and their catalysis toward the ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) and rac-lactide (rac-LA) were carried out. The ligand precursors [(5-Bu(t)-2-C4H2NH)CH=N(CH2)2]2NH…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

A REVIEW ON THE FABRICATION AND PROPERTIES OF PLATINUM NANOPARTICLES

Russian Federation2014-01-01OpenAlex

A review on chemical and physical preparation of platinum nanoparticles and some applications with these nanoparticles is presented. Application perspectives such fields as nano- catalysts, electrical conductivity, optics and nonlinear optics are demonstrated. Different param- eters and condition of various fabricatio…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Fe 3 O 4 nanoparticles prepared by the seeded-growth route for hyperthermia: electron magnetic resonance as a key tool to evaluate size distribution in magnetic nanoparticles

Idoia Castellanos-Rubio、Maite Insausti、Eneko Garaio 等 7 位作者2014-01-01Nanoscale

Monodispersed Fe3O4 nanoparticles have been synthesized by a thermal decomposition method based on the seeded-growth technique, achieving size tunable nanoparticles with high crystallinity and high saturation magnetization. EMR spectroscopy becomes a very efficient complementary tool to determine the fine details of s…

Nanoparticle-Based Drug DeliveryMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applications

Analysis of cellular responses of macrophages to zinc ions and zinc oxide nanoparticles: a combined targeted and proteomic approach

Sarah Triboulet、Catherine Aude-Garcia、Lucie Armand 等 14 位作者2014-01-01Nanoscale

Two different zinc oxide nanoparticles, as well as zinc ions, are used to study the cellular responses of the RAW 264 macrophage cell line. A proteomic screen is used to provide a wide view of the molecular effects of zinc, and the most prominent results are cross-validated by targeted studies. Furthermore, the altera…

Nanoparticles: synthesis and applicationsImmune cells in cancerAdvanced Nanomaterials in Catalysis

Ultraporous interweaving electrospun microfibers from PCL–PEO binary blends and their inflammatory responses

Yanfang Li、Marina Rubert、Hüsnü Aslan 等 8 位作者2014-01-01Nanoscale

Production of one dimensional nanomaterials with secondary morphology exhibiting unique functions is challenging. Here we report for the first time that a nanoscale immiscible polymer blend solution electrojet can assemble into ultraporous interweaving microfibers. This intriguingly novel morphology originated from a…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Homotropic and heterotropic allosteric regulation of supramolecular chirality

Mohit Kumar、Subi J. George2014-01-01Chemical Science

Homotropic/heterotropic allosteric control over the handedness of dipicolylethylenediamine-functionalized perylene bisimide assemblies was obtained with chiral ATP and achiral PPi guests binding.

Synthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Enhancement of Mechanical and Dynamic Mechanical Properties of Hydrophilic Nanoclay Reinforced Polylactic Acid/Polycaprolactone/Oil Palm Mesocarp Fiber Hybrid Composites

Chern Chiet Eng、Nor Azowa Ibrahim、Norhazlin Zainuddin 等 6 位作者2014-01-01International Journal of Polymer Science

In previous studies, the effect of the addition of 1 wt% hydrophilic nanoclay on polylactic acid (PLA)/polycaprolactone (PCL)/oil palm mesocarp fiber (OPMF) biocomposites was investigated by tensile properties, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). The current studies focus on the e…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Hollow nickel-coated silica microspheres containing rhodium nanoparticles for highly selective production of hydrogen from hydrous hydrazine

Jung Bo Yoo、Han Sol Kim、Seung Hee Kang 等 5 位作者2014-01-01Journal of Materials Chemistry A

Hollow nickel-coated microspheres containing Rh nanoparticles (Rh/Ni@SiO <sub>2</sub> ) generate hydrogen (H <sub>2</sub> ) from hydrazine (H <sub>2</sub> NNH <sub>2</sub> ) with over 99% selectivity within 1.5 h at 25 °C.

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionNanomaterials for catalytic reactions

Synthesis and antibacterial properties of a hybrid of silver–potato starch nanocapsules by miniemulsion/polyaddition polymerization

Shima Taheri、Grit Baier、Peter Majewski 等 7 位作者2014-01-01Journal of Materials Chemistry B

Controlled synthesis of hollow polymeric nanocapsules has attracted significant attention in a wide range of applications. This paper reports a facile method for the synthesis of hybrid starch nanocapsules decorated with silver nanoparticles using the inverse miniemulsion polyaddition technique. Silver nanoparticles a…

Nanoparticles: synthesis and applicationsbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

A short-range ordered–disordered transition of a NiOOH/Ni(OH) 2 pair induces switchable wettability

Ya‐Huei Chang、Nga Yu Hau、Chang Liu 等 7 位作者2014-01-01Nanoscale

By virtue of its amorphous structure with a short-range order feature, the inorganic nanoporous nickel oxyhydroxide (NiOOH) can reversibly and rapidly switch wettability by alternate treatments of environmental chamber (superhydrophobic) and UV/ozone (superhydrophilic). The switchable mechanism of the NiOOH/Ni(OH)2 pa…

ZnO doping and propertiesSurface Modification and SuperhydrophobicityTransition Metal Oxide Nanomaterials

The structure and amorphization of germanane

Shishi Jiang、Elisabeth Bianco、Joshua E. Goldberger2014-01-01Journal of Materials Chemistry C

Germanane, a direct band gap, high electron mobility germanium graphane analogue, has attracted considerable interest for optoelectronics. Here, temperature dependent pair distribution function analysis shows, upon annealing, the two-dimensional germanane framework begins to amorphize. The amorphization onset is indep…

Graphene research and applications2D Materials and ApplicationsGa2O3 and related materials

Effect of external electric fields on the phase behavior of colloidal silica rods

Anke Kuijk、Thomas Troppenz、Laura Filion 等 7 位作者2014-01-01Soft Matter

We examine the effect of external electric fields on the behavior of colloidal silica rods. We find that the electric fields can be used to induce para-nematic and para-smectic phases, and to reduce the number of defects in smectic phases. At high field strengths, a new crystal structure was observed that consisted of…

Liquid Crystal Research AdvancementsPlant Diversity and EvolutionPlant and animal studies

Site-selective adsorption of phthalocyanine on h-BN/Rh(111) nanomesh

Marcella Iannuzzi、Fabien Tran、Roland Widmer 等 8 位作者2014-01-01Physical Chemistry Chemical Physics

Experiment and computer simulations were conducted in order to study the adsorption of the phthalocyanine molecules H2Pc and CuPc on the h-BN/Rh(111) nanomesh. We combine STM investigations with the exploration of the potential energy surface as resulting from density functional theory calculations. Both approaches in…

Advancements in Battery MaterialsGraphene research and applicationsBoron and Carbon Nanomaterials Research

Colloidal synthesis and photocatalytic properties of orthorhombic AgGaS2 nanocrystals

Cong-Min Fan、Michelle D. Regulacio、Chen Ye 等 8 位作者2014-01-01Chemical Communications

AgGaS2 (AGS) nanocrystals that exist in the orthorhombic phase were successfully prepared for the first time through a one-pot colloidal synthetic strategy using suitable coordinating solvents. These orthorhombic AGS nanocrystals were found to display great potential in visible-light-driven photocatalysis.

Advanced Photocatalysis TechniquesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Agro-Industrial Waste Materials as Substrates for the Production of Poly(3-Hydroxybutyric Acid)

Artun Sukan、Ipsita Roy、Tajalli Keshavarz2014-01-01Journal of Biomaterials and Nanobiotechnology

Accumulation of recalcitrant plastics in the environment has become a world-wide problem in today’s societies. Rapid depletion of natural resources for synthetic plastics along with environmental concerns has directed research towards finding alternatives to petroleum-based polymers. Poly(3-hydroxybutyric acid) P(3HB)…

Biofuel production and bioconversionEnzyme Catalysis and Immobilizationbiodegradable polymer synthesis and properties