Materials Literature
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While azo compounds are widely employed as radical initiators, they have rarely been used as stimuli-responsive motifs in macromolecular constructs. In this study, an azo-based cross-linker was prepared and reacted with poly(vinyl alcohol) to afford a series of stimuli-responsive organogels. Irradiation of these mater…
N-doped carbon composites prepared by calcining TCNQ-based Sr-MOF, as supercapacitors electrode and LIBs anodes, they exhibited excellent specific capacitance and cycle durability.
An environmentally friendly, controlled and metal-free process to synthesize P(VDF–TrFE) from P(VDF–CTFE) is successfully developed with tris(trimethylsilyl)silane.
Laser treatment of Se/Bi heterostructure: Bi 2 Se 3 nanofilm formation K G Mikheev
The homoleptic sandwich compounds - Mo and W biscorroles - have afforded a novel platform for experimental studies of relativistic effects. A 200 mV difference in reduction potential and a remarkable 130 nm shift of a near-IR spectral feature have been identified as manifestations of relativistic effects on the proper…
<italic>In situ</italic> luminescence measurements allow monitoring the phase transitions of biologically relevant calcium phosphates with high sensitivity, independent of synchrotron radiation.
(ππ*) excitation. Conversion between the E and Z isomers through collisional excitation, which is calculated to occur through both inversion and torsion pathways, is investigated experimentally by colliding the molecular ions with nitrogen buffer gas over a range of electric fields. This study demonstrates the versati…
Titanium and its alloys are widely used in cranioplasty because they are biocompatible with excellent mechanical properties and favor the osseointegration with the bone. However, when Titanium alloys have to be worked several problems occurred from a manufacturing point of view: the standard procedure for obtaining Ti…
Considerable research approaches have focused on improving the crystallinity of conducting polymers to enhance the electrical conductivity. However, it is difficult to control the arrangement of polymer chains without the use of expensive and complex methods because of the intrinsic morphology of polymers. Herein, we…
We report a simple and scalable technique for the preparation of patchy particles with tunable patch coverage. These particles are categorized as inverse patchy colloidal particles (IPCs) as the patches repel each other while patch and non-patch surfaces attract. We demonstrate the effect of patch coverage, concentrat…
(YBCO) epitaxial thin films prepared using the chemical solution deposition (CSD) methodology by the trifluoroacetate route, was investigated by electrical conductivity relaxation measurements. We show that the oxygenation kinetics of YBCO films is limited by the surface exchange process of oxygen molecules prior to b…
), and this is detrimental to proton conductivity. Due to its larger ionic radius, Y exhibits a greater tendency than Sc to self-compensate at the Sr site. We also investigated the proton-dopant association. The binding energy of a proton to a negatively charged acceptor impurity is 0.41 eV for Sc and 0.31 eV for Y, i…
In this study, Al2O3, CuO, and TiO2 nanoparticles (NPs) were individually administered to 60 mature female rats via oral gavage (0, 0.5, 5, and 50 mg/kg b.w. per day) for 14 days and then responses of ATPases in the erythrocytes, total oxidant status (TOS), total antioxidant status (TAS), and liver enzyme (alkaline ph…
A new flexible monomer-based COF has been designed and synthesized and its structure and gas adsorption properties have been carefully investigated.
Lithium ferrite (Li0.5Fe2.5O4) powder was prepared by solid state reaction method, which was finally pressed and sintered at 1150°C. The spinel structure of the lithium ferrite was confirmed by X-ray diffraction and grain size estimation was obtained from scanning electron microscope (SEM). Fourier transform infrared…
A peculiar time evolution of contact angle of water on reconstructive polymer surface was analyzed.
Cl(PNP)]. Spectroscopic, structural and magnetic data in combination with multireference computations indicate strong temperature independent paramagnetism, which arises from an energetically well separated ground state that mixes with excited states through spin-orbit coupling.
Gels formed by a gemini dicationic amphiphile incorporate a serine protease inhibitor, which could be used in a new approach to the treatment of Rosacea, within the fibres as well as in the space between them, affecting a number of gel properties but most importantly inducing remarkable fibre coiling at the microscopi…
Microcapsules with high mechanical stability and elasticity are desirable in a variety of contexts. We report a single-step method to fabricate such microcapsules by microfluidic interfacial complexation between high stiffness cellulose nanofibrils (CNF) and an oil-soluble cationic random copolymer. Single-capsule com…
Adiabatic molecular spin-quenching during the approach of O <sub>2</sub> to Cu(111) and Cu <sub>ML</sub> /Ru(0001) surfaces.