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Direct Synthesis of Six-Monolayer (1.9 nm) Thick Zinc-Blende CdSe Nanoplatelets Emitting at 585 nm

Wooje Cho、Siyoung Kim、Igor Coropceanu 等 10 位作者2018-09-26Chemistry of Materials

Here, quasi-two-dimensional semiconductor nanoplatelets (NPLs) have garnered widespread interest because of their uniquely narrow emission spectra and favorable characteristics for optical gain and lasing.(1–5) Strongly quantum confined along thickness, NPLs exhibit the electronic structure of quantum wells determined…

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures

Critical Evaluation of Starch-Based Antibacterial Nanocomposites as Agricultural Mulch Films: Study on Their Interactions with Water and Light

Danila Merino、Tomy J. Gutiérrez、Andrea Y. Mansilla 等 5 位作者2018-09-26ACS Sustainable Chemistry & Engineering

High Resolution Image Download MS PowerPoint Slide In order to evaluate the potentiality of novel formulations based on starch to be used as agricultural mulch films, native and oxidized corn starch nanocomposites were prepared by extrusion using natural (Bent) and chitosan-modified bentonite (Bent-CS) fillers. The na…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced CompositesPolymer-Based Agricultural Enhancements

Biomedical Applications for Gold Nanoclusters: Recent Developments and Future Perspectives

Navdeep Kaur、Robby Nur Aditya、Arshdeep Singh 等 4 位作者2018-09-26Nanoscale Research Letters

Gold nanoclusters (AuNCs) have been extensively applied as a fluorescent probe for biomedical applications in imaging, detection, and therapy due to their unique chemical and physical properties. Fluorescent probes of AuNCs have exhibited high compatibility, superior photostablility, and excellent water solubility whi…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

An Aggregation-Induced Emission-Based “Turn-On” Fluorescent Probe for Facile Detection of Gaseous Formaldehyde

Xujie Zhao、Chendong Ji、Le Ma 等 6 位作者2018-09-26ACS Sensors

Gaseous formaldehyde (FA), a common indoor pollutant, presents a serious threat to human health. As an efficient tool for FA detection, fluorescent probes exhibit the advantages of low cost, ease of use, facile operation, etc. However, previously developed FA fluorescent probes are mostly based on fluorophores with ag…

Luminescence and Fluorescent MaterialsSulfur Compounds in BiologyAdvanced Chemical Sensor Technologies

Layer-by-layer assembled polymeric thin films as prospective drug delivery carriers: design and applications

Sohyeon Park、Uiyoung Han、Daheui Choi 等 4 位作者2018-09-26Biomaterials Research

BACKGROUND: The main purpose of drug delivery systems is to deliver the drugs at the appropriate concentration to the precise target site. Recently, the application of a thin film in the field of drug delivery has gained increasing interest because of its ability to safely load drugs and to release the drug in a contr…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction Studies3D Printing in Biomedical Research

An overview of the chemical modifications of chitosan and their advantages

Tomás Jesús Madera-Santana、Carlos Hernán Herrera-Méndez、Jesús Rubén Rodríguez‐Núñez2018-09-26Green Materials

The use of chitosan, a natural polymer, has recently increased due to its antimicrobial and antifungal character, null toxicity, biocompatibility and ability to form biofilms and hydrogels. The areas of application and research include biomedical, pharmaceutical, biomaterials, water treatment and haircare and skincare…

Nanocomposite Films for Food PackagingPolymer Surface Interaction StudiesPolydiacetylene-based materials and applications

Physical and Biological Determinants of the Fabrication of Molluscan Shell Microstructures

António Checa2018-09-26Frontiers in Marine Science

Molluscs are grand masters in the fabrication of shells, because these are composed of the largest variety of microstructures found among invertebrates. Molluscan microstructures are highly-ordered aggregates of either calcite or aragonite crystals with varied morphologies and three-dimensional arrangements. Classical…

Calcium Carbonate Crystallization and InhibitionCephalopods and Marine BiologyOcean Acidification Effects and Responses

Colloidal CdSe Nanoplatelets, A Model for Surface Chemistry/Optoelectronic Property Relations in Semiconductor Nanocrystals

Shalini Singh、Renu Tomar、Stephanie ten Brinck 等 8 位作者2018-09-26Journal of the American Chemical Society

While the surface termination of quasi-spherical metal chalcogenide nanocrystals or quantum dots has been widely investigated, it remains unclear whether the ensuing surface chemistry models apply to similar nanocrystals with anisotropic shapes. In this work, we report on the surface-chemistry of 2D CdSe nanoplatelets…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Thermal-Driven Self-Healing and Recyclable Waterborne Polyurethane Films Based on Reversible Covalent Interaction

Yuanlai Fang、Xiaosheng Du、Yuxu Jiang 等 7 位作者2018-09-26ACS Sustainable Chemistry & Engineering

By introducing novel stimuli-responsive Diels–Alder (DA) diol into polymer chains, a series of environmentally friendly, self-healing, and recyclable waterborne polyurethanes based on DA/retro-DA reactions (WPU-DA-x) were successfully prepared through a modified acetone process. The properties and appearance of the re…

Polymer composites and self-healingSynthetic Organic Chemistry MethodsPolydiacetylene-based materials and applications

Megahertz serial crystallography

Max O. Wiedorn、Dominik Oberthür、Richard Bean 等 100 位作者2018-09-26Nature Communications

The new European X-ray Free-Electron Laser is the first X-ray free-electron laser capable of delivering X-ray pulses with a megahertz inter-pulse spacing, more than four orders of magnitude higher than previously possible. However, to date, it has been unclear whether it would indeed be possible to measure high-qualit…

Advanced Electron Microscopy Techniques and ApplicationsEnzyme Structure and FunctionAdvanced X-ray Imaging Techniques

Recent Advances of Plasmonic Nanoparticles and their Applications

Jianxun Liu、Huilin He、Dong Xiao 等 9 位作者2018-09-26Materials

In the past half-century, surface plasmon resonance in noble metallic nanoparticles has been an important research subject. Recent advances in the synthesis, assembly, characterization, and theories of traditional and non-traditional metal nanostructures open a new pathway to the kaleidoscopic applications of plasmoni…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanocluster Synthesis and Applications

Anthracene-Resorcinol Derived Covalent Organic Framework as Flexible White Light Emitter

Sattwick Haldar、Debanjan Chakraborty、Bibhisan Roy 等 9 位作者2018-09-26Journal of the American Chemical Society

The ordered modular structure of a covalent organic framework (COF) facilitates the selective incorporation of electronically active segments that can be tuned to function cooperatively. This designability inspires developing COF-based single-source white light emitters, required in next-generation solid-state lightin…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsCovalent Organic Framework Applications

MXene Sorbents for Removal of Urea from Dialysate: A Step toward the Wearable Artificial Kidney

Fa‐Yan Meng、Mykola Seredych、Chi Chen 等 11 位作者2018-09-26ACS Nano

The wearable artificial kidney can deliver continuous ambulatory dialysis for more than 3 million patients with end-stage renal disease. However, the efficient removal of urea is a key challenge in miniaturizing the device and making it light and small enough for practical use. Here, we show that two-dimensional titan…

Advanced Photocatalysis TechniquesMXene and MAX Phase MaterialsGraphene and Nanomaterials Applications

Polymeric Nanocomposites and Nanocoatings for Food Packaging: A Review

Cornelia Vasile2018-09-26Materials

Special properties of the polymeric nanomaterials (nanoscale size, large surface area to mass ratio and high reactivity individualize them in food packaging materials. They can be processed in precisely engineered materials with multifunctional and bioactive activity. This review offers a general view on polymeric nan…

Nanocomposite Films for Food PackagingConducting polymers and applicationsbiodegradable polymer synthesis and properties

Data-Driven Design of Ecofriendly Thermoelectric High-Entropy Sulfides

Ruizhi Zhang、Francesco Gucci、Hongyu Zhu 等 5 位作者2018-09-26Inorganic Chemistry

Abstract High-entropy compounds with compositional complexity can be designed as new thermoelectric materials. Here a data-driven model was developed, which chose suitable elements to reduce the enthalpy of formation and hence to increase the chance of single phase formation. Using this model, two high-entropy sulfide…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsHigh Entropy Alloys Studies

Removal of GenX and Perfluorinated Alkyl Substances from Water by Amine-Functionalized Covalent Organic Frameworks

Woojung Ji、Leilei Xiao、Yuhan Ling 等 8 位作者2018-09-26Journal of the American Chemical Society

Per- and polyfluorinated alkyl substances (PFAS), such as perfluorooctanoic acid (PFOA), perfluorooctanesulfonate (PFOS), and ammonium perfluoro-2-propoxypropionate (GenX), contaminate ground and surface waters throughout the world. The cost and performance limitations of current PFAS removal technologies motivate eff…

Luminescence and Fluorescent MaterialsPer- and polyfluoroalkyl substances researchCovalent Organic Framework Applications

Phthalorubines: Fused‐Ring Compounds Synthesized from Phthalonitrile

Wei Zheng、Yuan Zhao、Wen‐Hao Zhuang 等 7 位作者2018-09-25Angewandte Chemie

Abstract A series of dibenzo[a,f][1,3,5]triazino[2,1,6‐cd] pyrrolizine compounds have been synthesized from phthalonitriles by a facile intramolecular cyclization process using “half‐phthalocyanine” precursors, and they were characterized by X‐ray crystallography, 1H NMR spectroscopy, UV/Vis, and theoretical calculati…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesPhotochromic and Fluorescence Chemistry

From Reticular Chemistry Design to Density Functional Theory Modeling for New Zeolitic Imidazolate Framework Topologies: Mechanical Stability, Electronic Structure, and CO2 Selectivity

Hieu T. Hoang、Ha L. Nguyen、Thắng Bách Phan 等 7 位作者2018-09-25The Journal of Physical Chemistry C

Adopting the knowledge and resource of reticular chemistry, we introduce a series of new zeolitic imidazolate framework (ZIF) structures within three topological categories, pth, pts, and ast, constructed by the square-planar and tetrahedral building blocks. Systematic metalation is considered with various cations (i.…

Metal-Organic Frameworks: Synthesis and ApplicationsBoron and Carbon Nanomaterials ResearchOrganic and Molecular Conductors Research

Preparation and biological evaluation of a novel pH-sensitive poly (β-malic acid) conjugate for antitumor drug delivery

Youbei Qiao、Liu B、Yifan Peng 等 5 位作者2018-09-25International Journal of Molecular Medicine

Poly (β‑malic acid), referred to as PMLA, has been synthesized and introduced as a polymeric drug carrier due to its desirable biological properties. In the present study, a novel pH‑sensitive polymer‑drug conjugate based on PMLA, PMLA‑Hz‑doxorubicin (DOX), was prepared, and another conjugate, PMLA‑ami‑DOX, was synthe…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryDendrimers and Hyperbranched Polymers

Improvement of Dissipative Particle Dynamics method by taking into account the particle size

Somaye Yaghoubi、Ebrahim Shirani、Ahmadreza Pishevar2018-09-25Scientia Iranica

In this paper, flow past a single Dissipative Particle Dynamics (DPD) particle with low Reynolds number is investigated and it is inquired that whether a single DPD particle immersed in a fluid, has an intrinsic size. Then a minimum length scale is determined such that the hydrodynamic behavior based on standard DPD f…

Block Copolymer Self-AssemblyFluid Dynamics Simulations and InteractionsLattice Boltzmann Simulation Studies