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In Situ Spectroscopic Studies of Highly Transparent Nanoparticle Dispersions Enable Assessment of Trithiocarbonate Chain-End Fidelity during RAFT Dispersion Polymerization in Nonpolar Media

Erik Jan Cornel、Sandra van Meurs、Timothy Smith 等 5 位作者2018-09-25Journal of the American Chemical Society

High Resolution Image Download MS PowerPoint Slide We report the synthesis of highly transparent poly(stearyl methacrylate)-poly(2,2,2-trifluoroethyl methacrylate) (PSMA–PTFEMA) diblock copolymer nanoparticles via polymerization-induced self-assembly (PISA) in nonpolar media at 70 °C. This was achieved by chain-extend…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Molten Salts Derived Copper Tungstate Nanoparticles as Bifunctional Electro‐Catalysts for Electrolysis of Water and Supercapacitor Applications

Jahangeer Ahmed、Tansir Ahamad、Norah Alhokbany 等 8 位作者2018-09-25ChemElectroChem

Abstract Herein, we report molten salts derived, cube‐shaped CuWO4 nanoparticles (50±5 nm) as multi‐functional catalysts in electrochemical and photo‐electrochemical studies. The formation of pure phase cube‐shaped CuWO4 nanoparticles (CWO‐NPs) is analyzed by X‐ray diffraction, Raman spectroscopy, X‐ray photo‐electron…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Layer-Structured POSS-Modified Fe-Aminoclay/Carboxymethyl Cellulose Composite as a Superior Adsorbent for the Removal of Radioactive Cesium and Cationic Dyes

Muruganantham Rethinasabapathy、Sung‐Min Kang、Ilsong Lee 等 7 位作者2018-09-25Industrial & Engineering Chemistry Research

In this work, multifunctional Fe-aminoclay (FeAC)/carboxymethyl cellulose (CMC)/ polyhedral oligomeric silsesquioxane (POSS) composite (FeAC/CMC/POSS) with layered structure was successfully synthesized and utilized as adsorbent for the removal of cesium ions (Cs + ) and cationic dyes methylene blue (MB) and chrysoidi…

Radioactive element chemistry and processingCovalent Organic Framework ApplicationsChemical Synthesis and Characterization

Hexagonal Boron Nitride/Blue Phosphorene Heterostructure as a Promising Anode Material for Li/Na-Ion Batteries

Jinna Bao、Linsheng Zhu、Haochi Wang 等 11 位作者2018-09-25The Journal of Physical Chemistry C

Blue phosphorene (blue-P), an allotrope of black phosphorene, is prone to oxidize under ambient conditions, which significantly hinders its incorporation in anode for Li/Na ion batteries (LIBs/NIBs). Combining blue-P and hexagonal boron nitride (h-BN) together to construct h-BN/blue-P heterostructure (BN/P) can break…

Advancements in Battery Materials2D Materials and ApplicationsMXene and MAX Phase Materials

Exceeding 14% Efficiency for Solution-Processed Tandem Organic Solar Cells Combining Fullerene- and Nonfullerene-Based Subcells with Complementary Absorption

Bing Guo、Wanbin Li、Guoping Luo 等 9 位作者2018-09-25ACS Energy Letters

For a highly efficient tandem organic solar cell, it is important for the subcells to minimize the absorption overlap and generate high and balanced currents. Considering the strong absorption and high external quantum efficiency at the short wavelength, developing a highly efficient blend system with a wide-bandgap (…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Methanol to Gasoline Conversion over CuO/ZSM-5 Catalyst Synthesized Using Sonochemistry Method

Ehsan Kianfar、Mahmoud Salimi、Saeed Hajimirzaee 等 4 位作者2018-09-25International Journal of Chemical Reactor Engineering

Abstract In this research, the catalytic conversion of methanol to gasoline range hydrocarbons has been studied over CuO (5 %)/ZSM-5 and CuO (7 %)/ZSM-5 catalysts prepared via sonochemistry methods. Conversion of methanol to gasoline (MTG) has been carried out in a fixed bed reactor under atmospheric pressure and 400˚…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

The emulsifying performance of mildly derived mixtures from sunflower seeds

Dimitris Karefyllakis、Heidi Octaviana、Atze Jan van der Goot 等 4 位作者2018-09-25Food Hydrocolloids

Sustainability driven production of food ingredients is in the center of discussion the past years, with plants being a promising source, since they are widely available and have smaller environmental impact compared to animals. However, plant material consists of a sturdy configuration comprising many components, lik…

Food composition and propertiesProteins in Food SystemsPickering emulsions and particle stabilization

Stochastic printing failures in extreme ultraviolet lithography

Peter De Bisschop2018-09-25Journal of Micro/Nanolithography MEMS and MOEMS

Stochastic effects in lithography are known to be the cause of critical dimension (CD) variability, quantified, e.g., by linewidth roughness or local CD uniformity, but—when the CDs are small—they can also lead to printing failures, and hence have a significant impact on yield. We will focus on these printing failures…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesIntegrated Circuits and Semiconductor Failure Analysis

Protective Roles of Thymoquinone Nanoformulations: Potential Nanonutraceuticals in Human Diseases

Ali H. El‐Far、Soad K. Al Jaouni、Weikun Li 等 4 位作者2018-09-25Nutrients

The focus on nanotechnology for improved bioavailability and drug delivery is of increasing importance for control of different human diseases. Therefore, numerous nanoformulations have been developed for the oral bioavailability of different drugs. This review introduces applications of nanomedicine to enhance the bi…

Nanoparticles: synthesis and applicationsBioactive Compounds and Antitumor AgentsNigella sativa pharmacological applications

Hybrid Full-Color Inorganic Light-Emitting Diodes Integrated on a Single Wafer Using Selective Area Growth and Adhesive Bonding

Chang‐Mo Kang、Jun Yeob Lee、Duk‐Jo Kong 等 10 位作者2018-09-25ACS Photonics

In recent years, research into implementing microdisplays for use in virtual reality and augmented reality has been actively conducted worldwide. Specifically, inorganic light-emitting diodes (LED) have many advantages in microdisplays, so much effort has been made to implement them in various ways. However, it is sti…

ZnO doping and propertiesGaN-based semiconductor devices and materialsOrganic Light-Emitting Diodes Research

Reversible Band Gap Narrowing of Sn‐Based Hybrid Perovskite Single Crystal with Excellent Phase Stability

Dianxing Ju、Xiaopeng Zheng、Jialiang Liu 等 10 位作者2018-09-25Angewandte Chemie International Edition

Abstract An intriguing reversible band gap narrowing behavior of the lead‐free hybrid perovskite single crystal DMASnI3(DMA=CH3NH2CH3+) from yellow to black is observed without phase transformation. We discuss the transformation mechanism in detail. More interestingly, the transformed samples in black can rapidly self…

Perovskite Materials and Applications2D Materials and ApplicationsChalcogenide Semiconductor Thin Films

Bandgap Engineering of Single‐Crystalline Perovskite Arrays for High‐Performance Photodetectors

Hanfei Gao、Jiangang Feng、Yueyang Pi 等 9 位作者2018-09-25Advanced Functional Materials

Abstract Bandgap engineering of single‐crystal lead halide perovskites with remarkable optoelectronic properties, solution processability, and low‐cost nature has been in the forefront of extensive optoelectronic applications. Yet one imminent challenging is to pattern micro‐ and nanostructured perovskite arrays with…

ZnO doping and propertiesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Carbonyl–Olefin Cross‐Metathesis Through a Visible‐Light‐Induced 1,3‐Diol Formation and Fragmentation Sequence

Lena Pitzer、Frederik Sandfort、Felix Strieth‐Kalthoff 等 4 位作者2018-09-25Angewandte Chemie International Edition

A visible-light-mediated approach to carbonyl-olefin cross-metathesis is described. Photoinduced hole catalysis was used to promote the formation of 1,3-diols from aldehydes and styrenes, which were then readily fragmented under acidic conditions to form the cross-metathesis products. The use of 1,3-diols as intermedi…

Radical Photochemical ReactionsPolyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry Methods

Superior High-Rate and Ultralong-Lifespan Na3V2(PO4)3@C Cathode by Enhancing the Conductivity Both in Bulk and on Surface

Lina Zhao、Hailei Zhao、Xuanyou Long 等 5 位作者2018-09-25ACS Applied Materials & Interfaces

Na 3 V 2 (PO 4 ) 3 has shown great promise in next-generation cathode materials for sodium-ion batteries owning to its fast Na + diffusion in the three-dimensional open NASICON framework and high theoretical energy density. However, Na 3 V 2 (PO 4 ) 3 suffers from undesirable rate performance and unstable cyclability…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Near-Infrared Laser-Driven in Situ Self-Assembly as a General Strategy for Deep Tumor Therapy

Fuhua Liu、Yong Cong、Guobin Qi 等 6 位作者2018-09-25Nano Letters

Nanotherapeutics have encountered some bottleneck problems in cancer therapy, such as poor penetration and inefficient accumulation in tumor site. We herein developed a novel strategy for deep tissue penetration in molecular level and near-infrared (NIR) laser guided in situ self-assembly to solve these challenges. Fo…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsPhotodynamic Therapy Research Studies

Controllable Epitaxial Growth of Core–Shell PbSe@CsPbBr3 Wire Heterostructures

Chao Fan、Xing Xu、Ke Yang 等 6 位作者2018-09-25Advanced Materials

Abstract 1D semiconductor core–shell wire heterostructures are crucial for high‐performance optical and optoelectronic device applications, but they are limited to the traditional semiconductor families. Here, the conformal epitaxy of CsPbBr3 shell on PbSe wire core is realized to form the core–shell PbSe@CsPbBr3 wire…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Transplanting Mesenchymal Stem Cells for Treatment of Ischemic Stroke

Fan Wang、Hailiang Tang、Jianhong Zhu 等 4 位作者2018-09-25Cell Transplantation

Stroke is a major disease that leads to high mortality and morbidity. Given the ageing population and the potential risk factors, the prevalence of stroke and socioeconomic burden associated with stroke are expected to increase. During the past decade, both prophylactic and therapeutic strategies for stroke have made…

Mesenchymal stem cell researchElectrospun Nanofibers in Biomedical ApplicationsExtracellular vesicles in disease

Synthesis of Bimetallic Gold-Silver (Au-Ag) Nanoparticles for the Catalytic Reduction of 4-Nitrophenol to 4-Aminophenol

Nurafaliana Berahim、Wan Jefrey Basirun、Bey Fen Leo 等 4 位作者2018-09-25Catalysts

Bimetallic gold-silver nanoparticles as unique catalysts were prepared using seed colloidal techniques. The catalytic capabilities of the nanoparticles were ascertained in the reduction of 4-nitrophenol to 4-aminophenol in the presence of sodium borohydride. Our results clearly showed that the rate of 4-NP reduction t…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials for catalytic reactions

Novel Defense Mechanisms in the Armor of the Scales of the “Living Fossil” Coelacanth Fish

Haocheng Quan、Wen Yang、Eric Schaible 等 5 位作者2018-09-25Advanced Functional Materials

Abstract Here, experiments and analysis revealing the unique defense mechanisms of the coelacanth, a lobe‐finned fish termed a “living fossil”, are reported, as it was considered to be extinct until 1938, but extant for 400 million years. This defense is provided by primitive elasmoid scales having a rare double‐twist…

Paleontology and Evolutionary BiologyCalcium Carbonate Crystallization and InhibitionIchthyology and Marine Biology

Extensive reuse of soda-lime waste glass in fly ash-based geopolymers

N. Toniolo、A. Rincón、Judith A. Roether 等 6 位作者2018-09-25Construction and Building Materials

The possibility of extensive incorporation of soda-lime waste glass in the synthesis of fly ash-based geopolymers was investigated. Using waste glass as silica supplier avoids the use of water glass solution as chemical activator. The influence of the addition of waste glass on the microstructure and strength of fly a…

Concrete and Cement Materials ResearchRecycling and utilization of industrial and municipal waste in materials productionNuclear materials and radiation effects