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Engineering of Al/CuO Reactive Multilayer Thin Films for Tunable Initiation and Actuation

Carole Rossi2018-07-18Propellants Explosives Pyrotechnics

Abstract Sputter‐deposited Al/CuO multilayers represent the state‐of‐the‐art of energetic nanomaterials for tunable ignition and actuation because their theoretical energy densities are significantly higher than most conventional secondary explosives while being less sensitive to undesired initiation. Both the sensiti…

Diamond and Carbon-based Materials ResearchEnergetic Materials and CombustionBoron and Carbon Nanomaterials Research

Self-Healable Antifouling Zwitterionic Hydrogel Based on Synergistic Phototriggered Dynamic Disulfide Metathesis Reaction and Ionic Interaction

Sovan Lal Banerjee、Koushik Bhattacharya、Sarthik Samanta 等 4 位作者2018-07-18ACS Applied Materials & Interfaces

A self-healable antifouling hydrogel based on zwitterionic block copolymer was prepared via reversible addition-fragmentation chain transfer polymerization and Diels-Alder "click" chemistry. The hydrogel consists of a core-cross-linked zwitterionic block copolymer having poly(furfuryl methacrylate) as core and poly(di…

Surface Modification and SuperhydrophobicityPolymer Surface Interaction StudiesMarine Biology and Environmental Chemistry

Performance Improvements in Conjugated Polymer Devices by Removal of Water‐Induced Traps

Mark Nikolka、Guillaume Schweicher、John Armitage 等 11 位作者2018-07-18Advanced Materials

The exploration of a wide range of molecular structures has led to the development of high-performance conjugated polymer semiconductors for flexible electronic applications including displays, sensors, and logic circuits. Nevertheless, many conjugated polymer field-effect transistors (OFETs) exhibit nonideal device c…

Organic Electronics and PhotovoltaicsAdvanced Memory and Neural ComputingConducting polymers and applications

On/Off Fluorescent Chemosensor for Selective Detection of Divalent Iron and Copper Ions: Molecular Logic Operation and Protein Binding

G. Tamil Selvan、Chitra Varadaraju、Ramadoss Tamil Selvan 等 5 位作者2018-07-18ACS Omega

High Resolution Image Download MS PowerPoint Slide Here, naphthalene diamine-based β-diketone derivative (compound LH) was successfully used as a dual signaling probe for divalent cations, Fe 2+ and Cu 2+ ions, in bimodal methods (colorimetric and fluorometric). It showed fluorescent enhancement for Fe 2+ ion by photo…

Advanced biosensing and bioanalysis techniquesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Realistic Floquet Semimetal with Exotic Topological Linkages between Arbitrarily Many Nodal Loops

Linhu Li、Ching Hua Lee、Jiangbin Gong2018-07-18Physical Review Letters

Valence and conduction bands in nodal loop semimetals (NLSMs) touch along closed loops in momentum space. If such loops can proliferate and link intricately, NLSMs become exotic topological phases, which require nonlocal hopping and are therefore unrealistic in conventional quantum materials or cold atom systems alike…

Graphene research and applicationsTopological Materials and PhenomenaQuantum Mechanics and Non-Hermitian Physics

Mixed-Valence Cobalt(II/III) Metal–Organic Framework for Ammonia Sensing with Naked-Eye Color Switching

Jindan Zhang、Jun Ouyang、Yingxiang Ye 等 8 位作者2018-07-18ACS Applied Materials & Interfaces

The construction of colorimetric sensing materials with high selectivity, low detection limits, and great stability provides a significant way for facile device implementation of an ammonia (NH 3 ) sensor. Herein, with excellent alkaline stability and exposed N sites in molecule as well as with naked-eye color switchi…

Metal-Organic Frameworks: Synthesis and ApplicationsNanoplatforms for cancer theranosticsAdvanced Nanomaterials in Catalysis

Theoretical Mechanistic Investigation into Metal-Free Alternating Copolymerization of CO2 and Epoxides: The Key Role of Triethylborane

Dandan Zhang、Xiaoshuang Feng、Yves Gnanou 等 4 位作者2018-07-18Macromolecules

The copolymerization of carbon dioxide (CO 2 ) and epoxides has received much attention during the past decades for the production of aliphatic polycarbonates. Remarkably, the green synthesis of polycarbonates was recently demonstrated by copolymerization of CO 2 with epoxides under metal-free conditions. In this work…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisCO2 Reduction Techniques and Catalysts

Modeling and Optimal Design of Absorbent Enhanced Ammonia Synthesis

Matthew J. Palys、Alon V. McCormick、E. L. Cussler 等 4 位作者2018-07-18Processes

Synthetic ammonia produced from fossil fuels is essential for agriculture. However, the emissions-intensive nature of the Haber–Bosch process, as well as a depleting supply of these fossil fuels have motivated the production of ammonia using renewable sources of energy. Small-scale, distributed processes may better en…

Catalytic Processes in Materials ScienceWastewater Treatment and Nitrogen RemovalAmmonia Synthesis and Nitrogen Reduction

Beyond the blocking model to fit nanoparticle ZFC/FC magnetisation curves

Karen L. Livesey、Sergiu Ruta、Nicholas R. Anderson 等 6 位作者2018-07-18Scientific Reports

We consider the probability of a magnetic nanoparticle to flip its magnetisation near the blocking temperature, and use this to develop quasi-analytic expressions for the zero-field-cooled and field-cooled magnetisation, which go beyond the usual critical energy barrier approach to the superparamagnetic transition. Th…

Magnetic properties of thin filmsZnO doping and propertiesCharacterization and Applications of Magnetic Nanoparticles

Design of Nonfullerene Acceptors with Near‐Infrared Light Absorption Capabilities

Jaewon Lee、Seo‐Jin Ko、Martin Seifrid 等 10 位作者2018-07-18Advanced Energy Materials

Abstract A series of narrow bandgap electron acceptors is designed and synthesized for efficient near‐infrared (NIR) organic solar cells. Extending π‐conjugation of donor frameworks leads to an intense intramolecular charge transfer, resulting in broad absorption profiles with band edge reaching 950 nm. When blended w…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Phase-field model of pitting corrosion kinetics in metallic materials

Talha Qasim Ansari、Zhihua Xiao、Shenyang Hu 等 6 位作者2018-07-18npj Computational Materials

Abstract Pitting corrosion is one of the most destructive forms of corrosion that can lead to catastrophic failure of structures. This study presents a thermodynamically consistent phase field model for the quantitative prediction of the pitting corrosion kinetics in metallic materials. An order parameter is introduce…

Aluminum Alloy Microstructure PropertiesHigh Temperature Alloys and CreepSolidification and crystal growth phenomena

High‐Mobility Helical Tellurium Field‐Effect Transistors Enabled by Transfer‐Free, Low‐Temperature Direct Growth

Guanyu Zhou、Rafik Addou、Qingxiao Wang 等 14 位作者2018-07-18Advanced Materials

Abstract The transfer‐free direct growth of high‐performance materials and devices can enable transformative new technologies. Here, room‐temperature field‐effect hole mobilities as high as 707 cm 2 V −1 s −1 are reported, achieved using transfer‐free, low‐temperature (≤120 °C) direct growth of helical tellurium (Te)…

Perovskite Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesNanowire Synthesis and Applications

Carboxymethylcellulose/MOF-5/Graphene oxide bio-nanocomposite as antibacterial drug nanocarrier agent

Zahra Karimzadeh、Siamak Javanbakht、Hassan Namazi2018-07-18Bioimpacts

Introduction: In recent years, more attention was dedicated to developing new methods for designing of drug delivery systems. The aim of present work is to improve the efficiency of the antibacterial drug delivery process, and to realize and to control accurately the release. Methods: First, graphene oxide (GO) was pr…

Nanoparticle-Based Drug DeliveryAdvanced Drug Delivery SystemsGraphene and Nanomaterials Applications

Highly Selective and Permeable Microporous Polymer Membranes for Hydrogen Purification and CO2 Removal from Natural Gas

Shuangjiang Luo、Qinnan Zhang、Lingxiang Zhu 等 9 位作者2018-07-18Chemistry of Materials

This paper reports a new macromolecular design that incorporates hierarchical triptycene unit into thermally rearranged polybenzoxazole (TR-PBO) structures for highly selective and permeable gas separation membranes with great potential for H 2 purification and CO 2 removal from natural gas. We demonstrate that tripty…

Membrane Separation and Gas TransportCovalent Organic Framework ApplicationsMuon and positron interactions and applications

High-Performance Photodiode-Type Photodetectors Based on Polycrystalline Formamidinium Lead Iodide Perovskite Thin Films

Meng Zhang、Fan Zhang、Yue Wang 等 8 位作者2018-07-18Scientific Reports

Abstract Photodetectors based on three dimensional organic–inorganic lead halide perovskites have recently received significant attention. As a new type of light-harvesting materials, formamidinium lead iodide (FAPbI3) is known to possess excellent optoelectronic properties even exceeding those of methylammonium lead…

Perovskite Materials and Applications2D Materials and ApplicationsQuantum Dots Synthesis And Properties

A New Strategy for High‐Voltage Cathodes for K‐Ion Batteries: Stoichiometric KVPO4F

Haegyeom Kim、Dong‐Hwa Seo、Matteo Bianchini 等 10 位作者2018-07-18Advanced Energy Materials

Abstract The exploration of high‐energy‐density cathode materials is vital to the practical use of K‐ion batteries. Layered K‐metal oxides have too high a voltage slope due to their large K+–K+ interaction, resulting in low specific capacity and average voltage. In contrast, the 3D arrangement of K+, with polyanions s…

Advancements in Battery MaterialsLuminescence Properties of Advanced MaterialsAdvanced Battery Materials and Technologies

Recent Advances in the Design of Targeted Iridium(III) Photosensitizers for Photodynamic Therapy

Huaiyi Huang、Samya Banerjee、Peter J. Sadler2018-07-18ChemBioChem

Abstract Photodynamic therapy (PDT) is a noninvasive treatment for certain types of cancer, bacterial, fungal and viral infections, and skin diseases. In recent years, adaptation of this treatment so as to achieve more specific targeted cancer therapy in particular has attracted significant attention. We focus herein…

Nanoplatforms for cancer theranosticsPhotodynamic Therapy Research StudiesLuminescence and Fluorescent Materials

Hierarchically Porous Fe2CoSe4 Binary‐Metal Selenide for Extraordinary Rate Performance and Durable Anode of Sodium‐Ion Batteries

Zeeshan Ali、Muhammad Asif、Xiaoxiao Huang 等 5 位作者2018-07-18Advanced Materials

Abstract Owing to high energy capacities, transition metal chalcogenides have drawn significant research attention as the promising electrode materials for sodium‐ion batteries (SIBs). However, limited cycle life and inferior rate capabilities still hinder their practical application. Improvement of the intrinsic cond…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced Battery Materials and Technologies

Small System Collectivity in Relativistic Hadronic and Nuclear Collisions

James L. Nagle、William A. Zajc2018-07-18Annual Review of Nuclear and Particle Science

The bulk motion of nuclear matter at the ultrahigh temperatures created in heavy ion collisions at the Relativistic Heavy Ion Collider and the Large Hadron Collider is well described in terms of nearly inviscid hydrodynamics, thereby establishing this system of quarks and gluons as the most perfect fluid in nature. A…

Material Dynamics and PropertiesHigh-Energy Particle Collisions ResearchDust and Plasma Wave Phenomena

Colonization of Non-biodegradable and Biodegradable Plastics by Marine Microorganisms

Claire Dussud、Cindy Hudec、Matthieu George 等 15 位作者2018-07-18Frontiers in Microbiology

Plastics are ubiquitous in the oceans and constitute suitable matrices for bacterial attachment and growth. Understanding biofouling mechanisms is a key issue to assessing the ecological impacts and fate of plastics in marine environment. In this study, we investigated the different steps of plastic colonization of po…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionRecycling and Waste Management Techniques