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A study of the influence of additives on the process of formation and corrosive properties of tripolyphosphate coatings on steel

E. N. Vlasova、Vadym Кovalenko、Valerii Kotok 等 5 位作者2017-10-31Eastern-European Journal of Enterprise Technologies

The anodic behavior of cold­rolled low­carbon steel in the aqueous STPP solution with aluminum hydroxide, borax, and glycerin additives at room temperature has been studied.It was revealed that the potentiodynamic curves that characterize the anodic behavior of steel st05kp samples shows up to three passivation platea…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsLubricants and Their Additives

Force and Mass Dynamics in Non-Newtonian Suspensions

Melody X. Lim、Jonathan Barés、Hu Zheng 等 4 位作者2017-10-31Physical Review Letters

Above a certain solid fraction, dense granular suspensions in water exhibit non-Newtonian behavior, including impact-activated solidification. Although it has been suggested that solidification depends on boundary interactions, quantitative experiments on the boundary forces have not been reported. Using high-speed vi…

Material Dynamics and PropertiesGranular flow and fluidized bedsSports Dynamics and Biomechanics

Mechanical properties of silica, graphite and carbon fiber reinforced composites

Mustafa Ahmed Rijab、Ekhlas I. Kader、Ali A. Hamod 等 4 位作者2017-10-31International Journal of Engineering and Technology

The research aims to study the mechanical properties included impact strength and flexural strength of composite materials consists of epoxy resin with phenolic formaldehyde resin reinforced by graphite or silica particles or both, and reinforced with carbon fibers of a standard format (-90, 0, +90). The results obtai…

Material Selection and PropertiesErgonomics and Human FactorsChemistry Education and Research

Reactivity of Monolayer Protected Silver Clusterstoward Excess Ligand: A Calorimetric Study

Ananya Baksi、Megalamane S. Bootharaju、Pratap K. Chhotaray 等 8 位作者2017-10-31The Journal of Physical Chemistry C

Abstract Reactivity of monolayer protected atomically precise clusters of noble metals is of significant research interest. To date very few experimental data are available on the reaction thermodynamics of such clusters. Here we report a calorimetric study of the reaction of glutathione (GSH) protected silver cluster…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Oxidative Corrosion of the UO2(001) Surface by Nonclassical Diffusion

Joanne E. Stubbs、Craig A. Biwer、Anne M. Chaka 等 7 位作者2017-10-31Langmuir

Uranium oxide is central to every stage of the nuclear fuel cycle, from mining through fuel fabrication and use, to waste disposal and environmental cleanup. Its chemical and mechanical stability are intricately linked to the concentration of interstitial O atoms within the structure and the oxidation state of U. We h…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties

The Use of Size Exclusion Chromatography to Monitor Protein Self-Assembly

Alaa Adawy、Matthew R. Groves2017-10-31Crystals

High resolution size exclusion chromatography (SEC) coupled with static light scattering (SLS) analyses were conducted to study the effect of the mobile phase ionic strength and protein concentration on the output of SEC experiments. The results highlight the effect of small changes in the mobile phase composition on…

Protein Structure and DynamicsProtein purification and stabilityEnzyme Structure and Function

Absorption Characteristics of the Electromagnetic Wave and Magnetic Properties of the La0.8Ba0.2FexMn½(1-x)Ti½(1-x)O3 (x = 0.1–0.8) Perovskite System

Wisnu Ari Adi、Azwar Manaf、Ridwan Ridwan2017-10-31International Journal of Technology

This paper reports on the magnetic properties and electromagnetic characterization of La0.8Ba0.2FexMn½(1-x)Ti½(1-x)O3 (x = 0.1–0.8). The La0.8Ba0.2FexMn½(1-x)Ti½(1-x)O3 (x = 0.1–0.8) materials were prepared using a mechanical alloying method.

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsElectromagnetic wave absorption materials

Encapsulating Iodine and Copper into Copper(I) Clusters Stabilized by Dichalcogenolate Ligands: Stability, Structure, and Optical Properties

Camille Latouche、Jian‐Hong Liao、Yijuan Li 等 8 位作者2017-10-31Inorganic Chemistry

The stability of large ligated copper(I) clusters of undeca- and dodecanuclearity encapsulating iodide and stabilized by dithio- and diseleno-phosph(in)ates was investigated by density functional theory (DFT) calculations. A bonding analysis is provided, which shows strong iono-covalent bonding between the iodide and…

Nanocluster Synthesis and ApplicationsAdvanced Nanomaterials in CatalysisInorganic Chemistry and Materials

Influences of pre-torsion deformation on microstructure and mechanical properties of pure titanium subjected to subsequent tension deformation

Jie Liu、Fuguo Li、Han Chen2017-10-31Chinese Journal of Aeronautics

A series of experimental studies was carried out to investigate the influences of pre-torsion on microstructure evolution, mechanical properties, and fracture appearance of pure titanium subjected to subsequent tension deformation. An introduction of pre-torsion strain can improve the materials’ mechanical properties…

Microstructure and mechanical propertiesMetallurgy and Material FormingTitanium Alloys Microstructure and Properties

Comparison among Constituent Phases in Superlattice Metal Hydride Alloys for Battery Applications

K. Young、T. Ouchi、Jean Nei 等 5 位作者2017-10-31Batteries

The effects of seven constituent phases—CeNi3, NdNi3, Nd2Ni7, Pr2Ni7, Sm5Ni19, Nd5Co19, and CaCu5—on the gaseous phase and electrochemical characteristics of a superlattice metal hydride alloy made by induction melting with a composition of Sm14La5.7Mg4.0Ni73Al3.3 were studied through a series of annealing experiments…

Hydrogen Storage and MaterialsMXene and MAX Phase MaterialsAmmonia Synthesis and Nitrogen Reduction

Observation of photoluminescence from large-scale layer-controlled 2D ß-Cu 2 S synthesized by the vapor-phase sulfurization of copper thin films

Rauf Shahzad、Tae‐Wan Kim、Jihun Mun 等 4 位作者2017-10-31Nanotechnology

Abstract Two-dimensional (2D) copper chalcogenides (Cu 2− x X where X = S, Se, Te) have had much attention regarding various applications due to their remarkable optical and electrical properties, abundance, and environmentally friendly natures. This work indicates that highly uniform Cu 2− x S (where 0 < x < 1)…

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

On the growth of witherite and its replacement by the Mg-bearing double carbonate norsethite: Implications for the dolomite problem

Michael Lindner、Guntram Jordan2017-10-31American Mineralogist

Witherite [BaCO 3 ] and norsethite [BaMg(CO 3 ) 2 ] are perceived as chemical and structural analogs of aragonite [CaCO 3 ] and dolomite [CaMg(CO 3 ) 2 ], respectively. However, norsethite, unlike dolomite, readily precipitates from aqueous solutions at ambient conditions. This is of special interest as the dehydratio…

Geological and Geochemical AnalysisCalcium Carbonate Crystallization and InhibitionClay minerals and soil interactions

Comparing Structure and Dynamics of Solvation of Different Iron Oxide Phases for Enhanced Magnetic Resonance Imaging

Mateus A. Gonçalves、Lizandro de Sousa Santos、Fernando Cunha Peixoto 等 6 位作者2017-10-31ChemistrySelect

Abstract Cancer is a global epidemic that significantly affects all ages and socioeconomic groups. One of the great difficulties of cancer is its diagnosis, mainly in the initial phase. Currently, the most used and effective technique for cancer diagnosis is Magnetic Resonance Imaging (MRI). For a better visualization…

Crystallography and molecular interactionsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Cross-Linked Polyamides Synthesized through a Michael Addition Reaction Coupled with Bulk Polycondensation

Chenfeng Yi、Jingbo Zhao、Zhiyuan Zhang 等 4 位作者2017-10-31Industrial & Engineering Chemistry Research

A simple route is described to synthesize cross-linked polyamides (cPAs) with excellent mechanical properties at mild conditions through a Michael addition reaction coupled with bulk polycondensation. A Michael addition of methyl acrylate with 1,6-hexanediamine was conducted in a bulk state at a N–H/C═C molar ratio of…

biodegradable polymer synthesis and propertiesDendrimers and Hyperbranched PolymersSynthesis and properties of polymers

Low-density polyethylene/sugarcane fiber composites from recycled polymer and treated fiber by steam explosion

Guilherme Luis Ribeiro、Meriene Gandara、Diego David Pinzón Moreno 等 4 位作者2017-10-31Journal of Natural Fibers

Low-density polyethylene (LDPE) has caused serious environmental damages, and it has been a challenge for waste management in large cities. The LDPE recycling as composites with natural fibers such as sugarcane fibers (SCF) has been an interesting alternative to conciliate economic aspects with environmental benefits.…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studies

Stabilization of Collagen Fibrils by Gelatin Addition: A Study of Collagen/Gelatin Dense Phases

François Portier、Claire Teulon、Agnieszka Nowacka‐Perrin 等 6 位作者2017-10-31Langmuir

Collagen and its denatured form, gelatin, are biopolymers of fundamental interest in numerous fields ranging from living tissues to biomaterials, food, and cosmetics. This study aims at characterizing mixtures of those biopolymers at high concentrations (up to 100 mg·mL –1 ) at which collagen has mesogenic properties.…

Silk-based biomaterials and applicationsCollagen: Extraction and CharacterizationBone and Dental Protein Studies

Hypercrosslinked silole‐containing microporous organic polymers with N‐functionalized pore surfaces for gas storage and separation

Ge Shu、Chong Zhang、Yuda Li 等 7 位作者2017-10-31Journal of Applied Polymer Science

ABSTRACT Novel hypercrosslinked microporous organic polymers (MOPs) derived from N‐functionalized siloles as basic building units have been designed and synthesized via Friedel–Crafts alkylation reaction. The resulting N‐functional silole‐containing polymer networks exhibit high thermal stabilities and moderate Brunau…

Metal-Organic Frameworks: Synthesis and ApplicationsMembrane Separation and Gas TransportCovalent Organic Framework Applications

Poly(organo)phosphazenes: recent progress in the synthesis and applications in tissue engineering and drug delivery

Rizwan Ullah Khan、Li Wang、Haojie Yu 等 10 位作者2017-10-31Russian Chemical Reviews

It is a highly desirable goal of researchers to develop effective biomaterials with minimum recovery time and affordable treatment expense for tissue engineering and drug delivery. In this scenario, numerous synthetic and natural polymers have been used. Among those synthetic polymers, polyorganophosphazenes (POPs) ha…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesFlame retardant materials and properties

Linear and Third‐Order Nonlinear Optical Properties of Triazobenzene‐1,3,5‐triazinane‐2,4,6‐trione (Isocyanurate) Derivatives

Bartosz Woźniak、Marta Dudek、Olivier Mongin 等 8 位作者2017-10-31ChemPlusChem

Abstract The synthesis of three new isocyanurate derivatives 2‐X (X=NO 2 , H, NMe 2 ) with azobenzene arms terminated by various X substituents is reported, and their linear and nonlinear absorption properties are studied. It is shown that mixtures that contain increased contents of cis ‐azo isomers can be reversibly…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryNonlinear Optical Materials Studies

Efficient Screening Methodology for Protein Crystallization Based on the Counter-Diffusion Technique

Luis A. González-Ramírez、C.R. Ruiz-Martinez、R.A. Estremera-Andujar 等 8 位作者2017-10-31Crystal Growth & Design

We report an efficient screening methodology based on the capillary counter-diffusion technique (CCD), which was evaluated using two different practical approaches. The first consisted of kits prepared with the most successful crystallizing agents (PEG and ammonium sulfate) buffered at different pHs ranging from 4 to…

Protein Structure and DynamicsEnzyme Structure and FunctionCrystallization and Solubility Studies