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TOPICAL REVIEW: Active nanocharacterization of nanofunctional materials by scanning tunneling microscopy

Daisuke Fujita and Keisuke Sagisaka2008-01-01Science and Technology of Advanced Materials

Recent developments in the application of scanning tunneling microscopy (STM) to nanofabrication and nanocharacterization are reviewed. The main focus of this paper is to outline techniques for depositing and manipulating nanometer-scale structures using STM tips. Firstly, the transfer of STM tip material through the…

Folate Functionalized Boron Nitride Nanotubes and their Selective Uptake by Glioblastoma Multiforme Cells: Implications for their Use as Boron Carriers in Clinical Boron Neutron Capture Therapy

Ciofani Gianni、Raffa Vittoria、Menciassi Arianna 等 4 位作者2008-01-01Nanoscale Research Letters

Abstract Boron neutron capture therapy (BNCT) is increasingly being used in the treatment of several aggressive cancers, including cerebral glioblastoma multiforme. The main requirement for this therapy is selective targeting of tumor cells by sufficient quantities of10B atoms required for their capture/irradiation wi…

Nanocolumnar Preferentially Oriented PSZT Thin Films Deposited on Thermally Grown Silicon Dioxide

Mitchell DRG、Sriram S、Bhaskaran M 等 5 位作者2008-01-01Nanoscale Research Letters

Abstract We report the first instance of deposition of preferentially oriented, nanocrystalline, and nanocolumnar strontium-doped lead zirconate titanate (PSZT) ferroelectric thin films directly on thermal silicon dioxide. No intermediate seed or activation layers were used between PSZT and silicon dioxide. The deposi…

Evolution of ZnS Nanoparticles via Facile CTAB Aqueous Micellar Solution Route: A Study on Controlling Parameters

Gradzielski Michael、Mehta SK、Kumar Sanjay 等 5 位作者2008-01-01Nanoscale Research Letters

Abstract Synthesis of semiconductor nanoparticles with new photophysical properties is an area of special interest. Here, we report synthesis of ZnS nanoparticles in aqueous micellar solution of Cetyltrimethylammonium bromide (CTAB). The size of ZnS nanodispersions in aqueous micellar solution has been calculated usin…

Fabrication and Properties of Ethylene Vinyl Acetate-Carbon Nanofiber Nanocomposites

George JinuJacob、Bhowmick Anil2008-01-01Nanoscale Research Letters

Abstract Carbon nanofiber (CNF) is one of the stiffest materials produced commercially, having excellent mechanical, electrical, and thermal properties. The reinforcement of rubbery matrices by CNFs was studied in the case of ethylene vinyl acetate (EVA). The tensile strength was greatly (61%) increased, even for very…

Synthesis and Luminescence Properties of Core/Shell ZnS:Mn/ZnO Nanoparticles

Jiang Daixun、Cao Lixin、Liu Wei 等 7 位作者2008-01-01Nanoscale Research Letters

Abstract In this paper the influence of ZnO shell thickness on the luminescence properties of Mn-doped ZnS nanoparticles is studied. Transmission electron microscopy (TEM) images showed that the average diameter of ZnS:Mn nanoparticles is around 14 nm. The formation of ZnO shells on the surface of ZnS:Mn nanoparticles…

Synthesis of Indium Nanowires by Galvanic Displacement and Their Optical Properties

Hope Greg、Liang Chaolun、Li Haohua 等 7 位作者2008-01-01Nanoscale Research Letters

Abstract Single crystalline indium nanowires were prepared on Zn substrate which had been treated in concentrated sulphuric acid by galvanic displacement in the 0.002 mol L−1In2(SO4)3-0.002 mol L−1SeO2-0.02 mol L−1SDS-0.01 mol L−1citric acid aqueous solution. The typical diameter of indium nanowires is 30 nm and most…

Cu-Doping Effects in CdI2Nanocrystals: The Role of Cu-Agglomerates

Miah M2008-01-01Nanoscale Research Letters

Abstract Cu-doping effects in CdI2nanocrystals are studied experimentally. We use the photostimulated second harmonic generation (PSSHG) as a tool to investigate the effects. It is found that the PSSHG increases with increasing Cu content up to 0.6% and then decreases due to the formation of the Cu-agglomerates. The P…

Grafting of Poly(methyl methacrylate) Brushes from Magnetite Nanoparticles Using a Phosphonic Acid Based Initiator by Ambient Temperature Atom Transfer Radical Polymerization (ATATRP)

Babu Kothandapani、Dhamodharan Raghavachari2008-01-01Nanoscale Research Letters

AbstractPoly(methyl methacrylate) in the brush form is grown from the surface of magnetite nanoparticles by ambient temperature atom transfer radical polymerization (ATATRP) using a phosphonic acid based initiator. The surface initiator was prepared by the reaction of ethylene glycol with 2-bromoisobutyrl bromide, fol…

Synthesis and Characterization of ZnO Nanorods and Nanodisks from Zinc Chloride Aqueous Solution

Yin Shu、Takabatake Kouta、Zhnag Peilin 等 5 位作者2008-01-01Nanoscale Research Letters

Abstract ZnO nanorods and nanodisks were synthesized by solution process using zinc chloride as starting material. The morphology of ZnO crystal changed greatly depending on the concentrations of Zn2+ion and ethylene glycohol (EG) additive in the solution. The effect of thermal treatment on the morphology was investig…

Synthesis and Microstructural Investigations of Organometallic Pd(II) Thiol-Gold Nanoparticles Hybrids

Cervellino Antonio、Vitaliano Rosa、Fratoddi Ilaria 等 11 位作者2008-01-01Nanoscale Research Letters

Abstract In this work the synthesis and characterization of gold nanoparticles functionalized by a novel thiol-organometallic complex containing Pd(II) centers is presented. Pd(II) thiol,trans, trans-[dithiolate-dibis(tributylphosphine)dipalladium(II)-4,4′-diethynylbiphenyl] was synthesized and linked to Au nanopartic…

FTIR and Raman Spectroscopy of Carbon Nanoparticles in SiO2, ZnO and NiO Matrices

Mwakikunga BW、Katumba G、Mothibinyane TR2008-01-01Nanoscale Research Letters

Abstract Coatings of carbon nanoparticles dispersed in SiO2, ZnO and NiO matrices on aluminium substrates have been fabricated by a sol–gel technique. Spectrophotometry was used to determine the solar absorptance and the thermal emittance of the composite coatings with a view to apply these as selective solar absorber…

Optimization, Yield Studies and Morphology of WO3Nano-Wires Synthesized by Laser Pyrolysis in C2H2and O2Ambients—Validation of a New Growth Mechanism

Sideras-Haddad E、Forbes A、Mwakikunga BW 等 4 位作者2008-01-01Nanoscale Research Letters

Abstract Laser pyrolysis has been used to synthesize WO3nanostructures. Spherical nano-particles were obtained when acetylene was used to carry the precursor droplet, whereas thin films were obtained at high flow-rates of oxygen carrier gas. In both environments WO3nano-wires appear only after thermal annealing of the…

Preparation and Characterization of Stimuli-Responsive Magnetic Nanoparticles

Wang ShiXing、Zhou Yang、Guan Wen 等 4 位作者2008-01-01Nanoscale Research Letters

AbstractIn this work, the main attention was focused on the synthesis of stimuli-responsive magnetic nanoparticles (SR-MNPs) and the influence of glutathione concentration on its cleavage efficiency. Magnetic nanoparticles (MNPs) were first modified with activated pyridyldithio. Then, MNPs modified with activated pyri…

Nanophotothermolysis of Poly-(vinyl) Alcohol Capped Silver Particles

Tripathy SurajKumar2008-01-01Nanoscale Research Letters

AbstractLaser-induced thermal fusion and fragmentation of poly-(vinyl) alcohol (PVA)-capped silver nanoparticles in aqueous medium have been reported. PVA-capped silver nanoparticles with an average size of 15 nm were prepared by chemical reduction technique. The laser-induced photo-fragmentation of these particles ha…

Preparation and Characteraction of New Magnetic Co–Al HTLc/Fe3O4Solid Base

You Jia、WANG Jun、Li Zhanshuang 等 6 位作者2008-01-01Nanoscale Research Letters

AbstractNovel magnetic hydrotalcite-like compounds (HTLcs) were synthesized through introducing magnetic substrates (Fe3O4) into the Co–Al HTLcs materials by hydrothermal method. The magnetic Co–Al HTLcs with different Fe3O4contents were characterized in detail by XRD, FT-IR, SEM, TEM, DSC, and VSM techniques. It has…

Double Rashba Quantum Dots Ring as a Spin Filter

Chi Feng、Yuan Xiqiu、ZHENG Jun2008-01-01Nanoscale Research Letters

AbstractWe theoretically propose a double quantum dots (QDs) ring to filter the electron spin that works due to the Rashba spin–orbit interaction (RSOI) existing inside the QDs, the spin-dependent inter-dot tunneling coupling and the magnetic flux penetrating through the ring. By varying the RSOI-induced phase factor,…

Cathodoluminescence and Cross-sectional Transmission Electron Microscopy Studies for Deformation Behaviors of GaN Thin Films Under Berkovich Nanoindentation

Teng I-Ju、Lu Jian-Ming、Jian Sheng-Rui2008-01-01Nanoscale Research Letters

AbstractIn this study, details of Berkovich nanoindentation-induced mechanical deformation mechanisms of metal-organic chemical-vapor deposition-derived GaN thin films have been systematic investigated with the aid of the cathodoluminescence (CL) and the cross-sectional transmission electron microscopy (XTEM) techniqu…

Sulfur Nanoparticles Synthesis and Characterization from H2S Gas, Using Novel Biodegradable Iron Chelates in W/O Microemulsion

Harle Arti、Deshpande Aniruddha、Khomane Ramdas 等 6 位作者2008-01-01Nanoscale Research Letters

AbstractSulfur nanoparticles were synthesized from hazardous H2S gas using novel biodegradable iron chelates in w/o microemulsion system. Fe3+–malic acid chelate (0.05 M aqueous solution) was studied in w/o microemulsion containing cyclohexane, Triton X-100 andn-hexanol as oil phase, surfactant, co-surfactant, respect…