Materials Literature
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The locus of points on the (α,κ/σT) plane for a two-band (electrons and holes) semiconductor as the concentration of doping agent is changed, is a curve that forms a closed loop, where α is the Seebeck coefficient, κ the thermal conductivity, σ the electrical conductivity, and T the absolute temperature. The value of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of Boron NitrideT. E. O'ConnorCite this: J. Am. Chem. Soc. 1962, 84, 9, 1753–1754Publication Date (Print):May 1, 1962Publication History Published online1 May 2002Published inissue 1 May 1962https://pubs.acs.org/doi/10.1021/ja00868a065https://doi.org/10.1021/ja0086…
The thermodielectric converter, a device employing a ferroelectric material as the active element in converting thermal to electrical energy, is analyzed. The efficiency and power-handling capacity are calculated for operation of a ferroelectric material in the induced-ferroelectric region on the basis of an idealizat…
The infrared transmission of degenerate arsenic-doped germanium was measured at liquid-helium and at room temperature. The 4.2\ifmmode^\circ\else\textdegree\fi{}K data were used to calculate the energy gap of the degenerate material. For this, two operations were necessary: (1) to subtract the large effect of free car…
In order to obtain some informations on the electronic structure of Mn 4 N, the magnetic properties of Mn 4 N compounds, partially substituted by In and Sn respectively, are studied by a newly devised magnetic torsion balance. These compounds show very complicated temperature- and composition-dependences of saturation…
Some ferroelectric and crystallographical properties of the compound ${\mathrm{Ba}}_{2}$${\mathrm{Bi}}_{4}$${\mathrm{Ti}}_{5}$${\mathrm{O}}_{18}$ are presented. The compound represents a new structure with the unit cell consisting of one ${\mathrm{Bi}}_{2}$${\mathrm{O}}_{2}^{2+}$ layer and five perovskite layers. From…
Abstract It was reported in a preceding paper7) that the Ando soils from Uemura, Choyo, and Kawanishi contained an unknown mineral colloid which was distinctly different in some respects from coexisting allophane. In the Uemura soil, this clay fraction made up more than 20 per cent of the total clay and more than 6 pe…
Moderately strong, very broad absorption bands observed in dilute lanthanide bromide solutions in nearly anhydrous ethanol are interpreted as electron transfer from the highest filled M.O. to the partly filled 4f shell in the case of Nd(III), Sm(III), Eu(III), Tm(III) and Yb(III). Good agreement is obtained with a the…
Abstract The dynamic shear modulus at very high strains, ( G ∞ ), of carbon black filler loaded vulcanizates is regarded as due to the product of two factors: ( a ) a hydrodynamic interaction due to filler particles, and ( b ) a second factor for which evidence is given suggesting that it arises from a few strong link…
On the basis of 190 runs made up to 1860°C in sealed noble‐metal containers the following revisions have been made in the equilibrium diagram for the system A1 2 O 3 –SiO 2 . Mullite melts congruently at 1850°C. The extent of equilibrium solid solution in mullite at solidus temperature is from approximately 60 mole %…
A set of best values for t he te mperatures a nd enthalpies of fusion alld transition for the n-paraffins is presented. From a n a nalysis of these data a general qualitative t heory of the phase behavior of the n-paraffins is developed. Four di stinct. crystal structures-h exagonal, t riclinic, monoclinic, and orthor…
Trap depths and densities can be determined from the analysis of the dependence of space-charge-limited currents on applied electric field in insulators. Values obtained from space-charge-limited current measurements are compared with those obtained from thermally stimulated currents and from photocurrent decay on the…
In Hartree-Fock theory and its various generalizations, it is customary to solve an eigenvalue problem involving an effective one-body Hamiltonian. The eigenvectors determine the Fock-Dirac density matrix, which also appears in the effective Hamiltonian, and solution proceeds iteratively until self-consistency is achi…
Compositions in the system KNbO 3 ‐NaNbO 2 have been hot‐pressed to yield ceramics with relative densities greater than 99%. Because these materials lack any degree of pyroplastic behavior, temperatures approaching those required for air sintering are needed. These hot‐pressed specimens exhibit a finer microstructure…
Abstract Electron microscope observations on some polycrystalline metals suggest that after small to moderate deformation, recrystallization occurs by the migration of the original grain boundaries. A theory based on this mechanism can account for the known form of the recrystallization kinetics without necessarily in…
P-type semiconducting diamonds can be formed at high pressures and temperatures out of mixtures of graphite and catalyst metal (Ni, Fe, etc.) to which small amounts of B, Be, or Al have been added. The crystals may have resistivities of as low as 103 ohm-cm with activation energies for conduction ranging between 0.1 a…
IT IS WELL KNOWN THAT THE ENERGY, DIPOLE MOMENT, AND MANY OTHER PROPERTIES OF AN ATOM OR MOLECULE CAN BE CALCULATED IF THE PAIR DENSITY MATRIX, A FUNCTION OF 12 VARIABLES, IS AVAILABLE. For a system with N electrons and therefore 3N degrees of freedom, this is a great simplification, at least in principle if not yet i…
An investigation of the magnetic structure and properties of Mn${\mathrm{Cr}}_{2}$${\mathrm{O}}_{4}$ has been carried out by means of neutron diffraction and an evaluation of the suitability of various proposed theoretical models has been made. From room-temperature diffraction patterns it is established that Mn${\mat…
Semiconducting crystals of cubic BN may be prepared at high pressures and temperatures by adding small amounts of selected impurities to the synthesis mixture (hexagonal boron nitride plus lithium or magnesium nitride). P-type crystals, blue in color, can be prepared by adding Be; they may have resistivities of about…
Using a simple one-dimensional model of H bonds, vibrational-energy eigenvalues, eigenfunctions, transition moments, and absorption intensities are calculated for a series of symmetric and asymmetric double-minimum (D.M.) potentials. On the basis of the results obtained, the necessary requirements for observing double…