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Two-photon absorption and photoinduced second-harmonic generation in Sb_2Te_3–CaCl_2–PbCl_2 glasses

I.V. Kityk、J. Kasperczyk、K.J. Pluciński1999-10-01Journal of the Optical Society of America B

Photoinduced nonlinear optical phenomena in Sb2Te3–CaCl2–PbCl2 glasses have been studied by experimental and theoretical quantum chemistry and molecular dynamics methods. Additionally, photoinduced two-photon absorption (TPA) and second-harmonic generation (SHG) were measured in the IR region from 5.8 to 18 µm. A CO l…

Glass properties and applicationsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Water transfer properties of two‐layer weft knitted fabric

Hai‐Ru Long1999-10-01International Journal of Clothing Science and Technology

The aim of this study is to investigate the water (moisture vapor and liquid) transfer properties of two‐layer weft knitted fabric and some related factors. Some experimental fabrics with specific yarns and stitch densities were prepared. Water vapor permeability rate through the fabrics and liquid water transfer from…

Textile materials and evaluations

Hydrothermal recycling of PVC in a bubbling fluidized bed reactor: the influence of bed material and temperature

Mathias J. P. Slapak、J.M.N. van Kasteren、Bart A. A. H. Drinkenburg1999-10-01Polymers for Advanced Technologies

Hydrothermal recycling is conversion of poly(vinyl chloride) (PVC) at high temperatures in a steam atmosphere into hydrogen chloride, a mixture of hydrocarbons and syngas. Hydrochloric acid can be recovered and the mixture of hydrocarbons and syngas can be used for energy recovery. A bench-scale bubbling fluidized bed…

Extraction and Separation ProcessesRecycling and Waste Management TechniquesPolymer Science and PVC

Generation of high pretilt angle and surface anchoring strength in nematic liquid crystal on a rubbed polymer surface

Dae‐Shik Seo1999-10-01Journal of Applied Physics

The generation of high pretilt angles in nematic liquid crystal (LC), 4-n-pentyl-4-cyanobiphenyl (5CB), on the rubbed surface of polyimide (PI) containing trifluoromethyl moieties, was investigated. High pretilt angles of 5CB are strongly related to the low surface energy caused more by the existence of trifluoromethy…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsSynthesis and properties of polymers

Porosity Characteristics of Chars Derived from Different Lignocellulosic Materials

Laila B. Khalil1999-10-01Adsorption Science & Technology

Sixteen agricultural waste products were subjected to pyrolysis at 550°C under a nitrogen atmosphere. The precursors which were treated in this manner were fruit stones and nut shells (peach, apricot and olive stones; date pits, almond, hazel nut and pistacio shells), fibrous materials (sugar cane bagasse, date palm b…

Food composition and propertiesAdvanced Cellulose Research StudiesLignin and Wood Chemistry

An evaluation of the transition temperature range of super-elastic orthodontic NiTi springs using differential scanning calorimetry

O. Barwart1999-10-01European Journal of Orthodontics

Differential scanning calorimetry (DSC) was used to determine the transition temperature ranges (TTR) of four types of super-elastic orthodontic nickel-titanium coil springs (Sentalloy). A knowledge of the TTR provides information on the temperature at which a NiTi wire or spring can assume superelastic properties and…

Dental materials and restorationsShape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

Continuum mechanics characterization of plastic deformation-induced oxide film rupture

D. G. Kolman、John R. Scully1999-10-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

The film rupture behaviour of dynamically strained metastable Ti-15wt% Mo-3wt% Nb-3wt% Al in the solution-treated and aged (STA) (β + α) condition that is prone to coplanar slip was examined. Film rupture was detected by rapid data acquisition (10 000 Hz, 40 nA resolution) of repassivation current transients on fatigu…

Metal and Thin Film MechanicsHydrogen embrittlement and corrosion behaviors in metalsTitanium Alloys Microstructure and Properties

Use of controlled radical polymerization of butadiene with AIBN and TEMPO for the determination of the NMR characteristics of hydroxymethyl groups

Jean-Laurent Pradel、Bruno Améduri、Bernard Boutevin1999-10-01Macromolecular Chemistry and Physics

The controlled radical polymerization of butadiene initiated with 2,2′-azoisobutyronitrile (AIBN) and in the presence of 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) is presented. The produced oligomers which have number average degrees of polymerization ranging between 3 and 12 were characterized by NMR. This led to…

Advanced Polymer Synthesis and CharacterizationConducting polymers and applicationsAnalytical Chemistry and Sensors

Optimised post-weld heat treatment procedures and heat input for welding 17–4PH stainless steel

A.K. Bhaduri、T. P. S. Gill、G. Srinivasan 等 4 位作者1999-10-01Science and Technology of Welding & Joining

Post-weld heat treatment (PWHT) procedures and heat input during welding of 17–4PH stainless steel, using matching chemistry consumables, have been optimised in relation to its microstructural condition before welding based on room temperature tensile properties. The 17–4PH stainless steel was welded in two different…

Microstructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Characterization of Dendrimers by X-Ray Photoelectron Spectroscopy

Caroline Demathieu、Mohamed M. Chehimi、Jean-François Lipskier 等 5 位作者1999-10-01Applied Spectroscopy

A series of P=S-containing dendrimers (starburst macromolecules) were characterized by X-ray photoelectron spectroscopy (XPS). This technique is a unique tool for the identification of specific groups from these starbursts such as P=S, aromatic rings, C–O, and C=O. Surface elemental and chemical composition is found t…

Mass Spectrometry Techniques and ApplicationsMolecular Junctions and NanostructuresDendrimers and Hyperbranched Polymers

Horizontal chevron domain formation and smectic layer reorientation in SmC* liquid crystals stabilized by polymer networks

Ingo Dierking、L. Komitov、S. T. Lagerwall 等 5 位作者1999-10-01Liquid Crystals

The influence of a polymer network, stabilizing an initial texture of horizontal chevron geometry, on the in-plane smectic C* layer reorientation process is studied for different applied electric field conditions. As expected, the reorientation of smectic layers is strongly slowed down and eventually suppressed by the…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationPlant Reproductive Biology

Mechanism of DC Offset Voltage Generation in Hybrid-Aligned Nematic Liquid Crystal Displays

Yasuharu Tanaka、Yökö Gotö、Yasufumi Iimura1999-10-01Japanese Journal of Applied Physics

In order to study the mechanism of DC offset voltage generation in a hybrid-aligned nematic liquid crystal display (HAN-LCD), we theoretically and experimentally studied the electrooptic characteristics of a HAN sample. The results showed that decreasing the thickness of a LC alignment film strongly reduces the genera…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

Control of orientation in liquid crystalline epoxies via magnetic field processing

D. M. Lincoln、Elliot P. Douglas1999-10-01Polymer Engineering and Science

Abstract We demonstrate control over the orientation of the 4,4′‐bis(2,3‐epoxypropoxy)‐α‐methylstilbene (EPAMS)/sulfanilamide (SAA) epoxy system. A statistical experimental design was generated and analyzed to determine the effects of the time in the magnetic field, field strength, and the amount of B‐staging. A regre…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesSynthesis and properties of polymers

Glassy Liquid Crystal Films as Broadband Polarizers and Reflectors via Spatially Modulated Photoracemization

S. H. Chen、John C. Mastrangelo、R. J. Jin1999-10-01Advanced Materials

Chiral-nematic glassy liquid crystals (GLCs) are of interest because of their unique supramolecular structure and associated optical properties. However, the constant-pitch films produced so far have a bandwidth limited to less than 100 nm in the visible. The introduction of a pitch gradient, indicated by theory to in…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsOptical Polarization and Ellipsometry

Dynamic Fracture Toughness of Cellulose-Fiber-Reinforced Polypropylene: Preliminary Investigation of Microstructural Effects

Craig M. Clemons、Daniel F. Caulfield、A. Jeffrey Giacomin1999-10-01Journal of Elastomers & Plastics

In this study, the microstructure of injection-molded polypropylene reinforced with cellulose fiber was investigated. Scanning electron microscopy of the fracture surfaces and X-ray diffraction were used to investigate fiber orientation. The polypropylene matrix was removed by solvent extraction, and the lengths of th…

Mechanical Behavior of CompositesPolymer crystallization and propertiesNatural Fiber Reinforced Composites

Effect of coupling agent and filler particle size on melt rheology of polymer‐bonded Nd‐Fe‐B magnets

Joshua U. Otaigbe、Hyun Seog Kim、Jun Xiao1999-10-01Polymer Composites

Abstract The effect of coupling agents and filler particle size on melt rheology of poly(phenylene sulfide)‐bonded neodymium‐iron‐boron (Nd‐Fe‐B) alloy magnets was studied with oscillatory flow experiments to accelerate efforts to optimize their processing. The minimum viscosity of the polymer‐bonded magnets near 290°…

Magnetic Properties and ApplicationsMagnetic Properties of AlloysSuperconducting Materials and Applications

Pt as Mediator of Strong Antiferromagnetic Coupling between Two CuII Ions in a Heteronuclear CuIIPtIICuII Complex of the Model Nucleobase 1-Methylcytosinate

Alexander Hegmans、Ennio Zangrando、E. Freisinger 等 9 位作者1999-10-01Chemistry - A European Journal

Trinuclear CuIIPtCuII complexes (see scheme) are formed with four bridging 1-methylcytosinate nucleobases. These compounds are diamagnetic as a result of the strong exchange interaction (J≅1000 cm−1 (2 b)), despite a separation of approximately 5 Å between the CuII centers.

Magnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsElectron Spin Resonance Studies

High Electrical Conductivity and High Fracture Strength of Sc 2 O 3 ‐Doped Zirconia Ceramics with Submicrometer Grains

Masanori Hirano、Shinzi Watanabe、Etsuro KATO 等 6 位作者1999-10-01Journal of the American Ceramic Society

The microstructure, crystal phase, electrical conductivity, and mechanical strength of less than 7‐mol%‐Sc 2 O 3 ‐doped zirconia ceramics fabricated by comparatively low‐temperature sintering at 1200–1300°C for 1 h were investigated. Zirconia ceramics having a uniform microstructure (grain size < 0.5 μm) stabilized…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsElectronic and Structural Properties of Oxides

Role of Metal Phthalocyanine in Redox Complex Conductivity of Polyaniline and Aniline Black

Francis P. Xavier、Anto R. Inigo、George J. Goldsmith1999-10-01Journal of Porphyrins and Phthalocyanines

Polyaniline (PA) and aniline black (AB) were prepared in powder form by the chemical method of oxidative polymerization, from which free-standing thin films were obtained by solvent evaporation using N-methyl pyrrolidinone ( NMP ). The thin films contained 2, 4, 6 or 8 wt% AB. Electrical measurements showed that the s…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Matching X-ray source, optics and detectors to protein crystallography requirements

C. Nave1999-10-01Acta Crystallographica Section D Biological Crystallography

A review of the requirements for collecting X-ray diffraction data from protein crystals is given, with an emphasis on the properties of the crystal and its diffraction pattern. The size, unit-cell dimensions and perfection of the crystals can all be related to the required size and divergence of the incident X-ray be…

Enzyme Structure and FunctionAdvanced X-ray Imaging TechniquesX-ray Spectroscopy and Fluorescence Analysis