Materials Literature
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We present a study of the electrical transport in porous Si layers prepared by anodic etching of two different kinds of (100) p-type Si substrates. It is shown that by choosing a sufficiently thick layer, the problem of injection from the contacts can be eliminated. In this way we measure the intrinsic transport prope…
Cathodoluminescence has been investigated in diamond films, prepared by microwave plasma assisted chemical-vapor deposition. Results are presented for various diamond films differing in crystalline structure and doping. In the energy range 2.0--2.7 eV a series of 13 sharp luminescence lines has been observed at temper…
A general and practical model for heat generation that can be used in the heat conduction equation for nonisothermal semiconductor device simulations is presented. The model is developed for cubic semiconductors with position-dependent, multivalley, and multiband band structures, Fermi-Dirac statistics and an accurate…
Abstract When 4,4'‐bis (3,4‐dicyanophenoxy) biphenyl is heated with small amounts of aromatic amine or amidine salts, a highly crosslinked polytriazine is obtained. This polymer has been shown to be the same as that reported when bisphthalonitriles are heated with amines. Salts promote this reaction more readily and t…
Photoemission and bremsstrahlung isochromat spectra have been measured on TiO 2 (rutile) and SrTiO 3 . The magnitudes of the fundamental band gaps estimated from the combined spectra agree well with the results of the photoabsorption and the energy-band calculations. The profiles of the observed spectra do not reveal…
The pair correlation functions g(r) of liquid water obtained at pressures of up to 7.7 kbar at a constant temperature of 20 °C are discussed. A variety of evidence of the very strong effect of pressure on the structure of liquid water has been found. In particular, an unusual pressure dependence of the shortest interm…
Optical properties have been studied in amorphous thin films of various Ge-based chalcogenide glasses with a view to investigating the effect of Te isovalence substitution in the Ge-S-Se system. Te either completely replaces S to give Ge 2.5 Te 2.5 Se 95 and Ge 5 Te 5 Se 90 or partially replaces Se to give Ge 2.5 S 2.…
Free-radical side-chain brominations of alkylaromatics in supercritical carbon dioxide (SC-CO(2)) are reported. Direct bromination of toluene and ethylbenzene form the corresponding benzyl bromides in high yield. The observed selectivity in SC-CO(2) is similar to that observed in conventional organic solvents. Also, S…
This paper reviews recent developments in highly magnetostrictive terbium-dysprosium-iron alloys. This includes discussion of domain structure, the magnetization process, microstructure, sample preparation, magnetostriction, effects of different chemical compositions on magnetic properties of the alloys, and possible…
The F1-ATPase from Bacillus PS3 (TF1) hydrolyzes 50 microM ATP in three kinetic phases. An initial burst rapidly decelerates to a partially inhibited, intermediate phase, which, in turn, gradually accelerates to an uninhibited, final steady-state rate. Lauryl dimethylamine oxide (LDAO) stimulates the final rate over 4…
The folding of the small protein barstar, which is the intracellular inhibitor to barnase in Bacillus amyloliquefaciens, has been studied by equilibrium unfolding methods. Barstar is shown to exist in two conformations: the A form, which exists at pH values lower than 4, and the N state, which exists at pH values abov…
The structure of RP 71955, a new tricyclic 21 amino acid peptide active against human immunodeficiency virus 1, was determined. Its amino acid composition was inferred from the results of fast atom bombardment mass spectrometry, nuclear magnetic resonance, Raman spectroscopy, and amino acid analysis. Its sequence coul…
Abstract In the present study, the dose‐rate effects of γ‐irradiation in air on two isotactic polypropylene grades of different molecular weight distribution, used for medical devices, were investigated. The thermal, mechanical, rheological, and photometric properties of these materials were examined using DSC, stress…
This paper deals with the application of simulated annealing to rock magnetism. The implementation of the algorithm is discussed in detail. It is shown that the technique can be used to determine stable micromagnetic structures by finding very low energy states which are not easily found using other optimization techn…
Abstract This article presents crystallization kinetics studies on a cocrystallizing polymer highdensity polyethylene (HDPE)/linear lowd‐ensity polyethylene (LLDPE) blend. The nonisothermal crystallization exotherms obtained by differential scanning calorimetry (DSC) were analyzed to investigate the effect of cocrysta…
The electrical characteristics of chemically vapor deposited (CVD) diamond films were measured as a function of film thickness. The samples studied were polycrystalline with the average grain size increasing from approximately 1 μm on the substrate side to approximately 30 μm on the growth surface for the thickest sam…
We report on a novel technique for synthesizing large quantities of single-shell carbon nanotubes in a dc arc with a composite anode of graphite and copper. Based on systematic studies involving a varying diameter and distribution of copper rods inside the graphite anode, we have correlated the presence of copper to t…
Abstract Polycondensation of dimethylolurea leads to the formation of a gel or a film according to the experimental conditions. Both forms of the polymer would be characterized by a specific chemical structure, i.e., dimethylene ether or diaminomethylene, respectively. We studied both forms of dimethylolurea polymer b…
We report on a small angle neutron scattering study of the flux-line lattice in single crystal 2H-${\mathrm{NbSe}}_{2}$. As the magnetic field is tilted away from the crystalline c axis, we find distortions in the flux lattice as would be expected for a mass anisotropy \ensuremath{\Gamma}=10.1\ifmmode\pm\else\textpm\f…
The itinerant electron ferromagnetism in La 1-x Sr x CoO 3 (0.1<or=x<or=0.5) has been reinvestigated. AC magnetic susceptibility studies on these systems have been carried out for the first time. The nature of the susceptibility indicates the freezing of superparamagnetic clusters at low values of x (<0.3) and long-ra…