Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe nature of the thermal transitions in poly(p-oxybenzoate)J. Economy, W. Volksen, C. Viney, R. Geiss, R. Siemens, and T. KarisCite this: Macromolecules 1988, 21, 9, 2777–2781Publication Date (Print):September 1, 1988Publication History Published online1 May 2002Published i…
The preparation, spectroscopic investigation, structure determination, conformational analysis, and modeling of the Dewar pyrimidinone photoproduct of thymidylyl-(3'----5')-thymidine, previously referred to as TpT3 [Johns, H. E., Pearson, M. L., LeBlanc, J. C., & Heilleiner, C. W. (1964) J. Mol. Biol. 9, 503-524], is…
A decagonal quasicrystal with a periodicity of 1·6 nm along the tenfold axis, similar to that in Al─Pd and Al─Co, has been found in a rapidly solidified Al6Ni alloy containing a few per cent of silicon. In addition, a new decagonal phase has been found in Al4Ni which has a periodicity of 0·4 nm along the tenfold axis.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReductive chemistry of nickel hydroporphyrins. Evidence for a biologically significant difference between porphyrins, hydroporphyrins, and other tetrapyrrolesAlan M. Stolzenberg and Matthew T. StershicCite this: J. Am. Chem. Soc. 1988, 110, 19, 6391–6402Publication Date (Pri…
X-ray scattering and optical studies reveal two key features of Surface Stabilized Ferroelectric Liquid Crystal (SSFLC) cell structure: (1) The temperature dependence of the layer thickness is an important effect in determining both the layer and director-polarization structure; and (2) There exists in some SSFLC cell…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffects of thermal history on crystallization of poly(ether ether ketone) (PEEK)Youngchul Lee and Roger S. PorterCite this: Macromolecules 1988, 21, 9, 2770–2776Publication Date (Print):September 1, 1988Publication History Published online1 May 2002Published inissue 1 Septem…
The requirements for ferroelectric liquid crystals (FLC) for an application in fast-switching electro-optic devices are summarized. Typical molecular structures for FLC-mixtures are discussed. New non-chiral SmC-substances as well as some chiral dopants are shown. Important material parameters which are presented incl…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface and bulk phase separation in block copolymers and their blends. Polysulfone/polysiloxaneNiranjan M. Patel, David W. Dwight, James L. Hedrick, Dean C. Webster, and James E. McGrathCite this: Macromolecules 1988, 21, 9, 2689–2696Publication Date (Print):September 1, 19…
Chiral smectic C compounds having an ester group in the central core, an optically active tail group (alkoxy or alkoxycarbonyl), and an electronegative substituent (halogen or cyano) ortho to the chiral tail were synthesized. The effect of the ortho substitution on the characteristics, especially on spontaneous polari…
The dislocation structure resulting from the compression of single crystals of Ni3(Al,Ti) at room temperature has been studied using transmission electron microscopy imaging methods. Deformed samples of ε = 1% and ε = 9% true strain were sliced parallel to (111) and (010) planes. Weak-beam imaging methods reveal the (…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA synthesis of taxusinRobert A. Holton, R. R. Juo, Hyeong B. Kim, Andrew D. Williams, Shinya. Harusawa, Richard E. Lowenthal, and Sadamu. YogaiCite this: J. Am. Chem. Soc. 1988, 110, 19, 6558–6560Publication Date (Print):September 1, 1988Publication History Published online1…
Abstract Sorption is the predominant process governing metal ion movement in soils and includes the following physical and chemical mechanisms: adsorption, precipitation and absorption. This research attempts to use the hard‐soft‐acid‐base principle to explain sorption selectivity of the metal cations Cd, Ni and Zn by…
In recent years development in the field of immunologic assays has been characterized by an expanding use of monoclonal antibodies [1] and two-site ‘sandwich’ type assays [2]. Concomitantly, the assay sensitivities and specificities have improved considerably, which has opened new possibilities and areas of applicatio…
Autophosphorylation of Ca2+/calmodulin-dependent protein kinase II converts the enzyme to a Ca2+-independent form. The time course for this conversion correlates with the autophosphorylation of a threonine residue located within a thermolytic phosphopeptide common to the alpha and beta/beta' subunits. In the present s…
A thermodynamically stable quasi-crystalline single phase with an icosahedral structure was found to be formed at atomic compositions of Al 65 Cu 20 Ru 15 and Al 65 Cu 20 Os 15 in conventionally solidified and fully annealed states as well as in a rapidly solidified state. The quasi-crystalline nature determined by X-…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAromatic-aromatic interactions in molecular recognition: a family of artificial receptors for thymine that shows both face-to-face and edge-to-face orientationsAlexander V. Muehldorf, Donna. Van Engen, John C. Warner, and Andrew D. HamiltonCite this: J. Am. Chem. Soc. 1988,…
Using site-directed mutagenesis we have created an altered calmodulin in which Gln-3 and Thr-146 have both been replaced by cysteines. We have reacted this protein with the bifunctional reagent, bismaleimidohexane, forming an intramolecular cross-link between the two cysteines. In the crystal structure of native calmo…
Recent aging studies performed on dilute and concentrated metal tritides are reviewed. Also, new results concerning property changes in metal tritides as a function of aging time are included. We mainly report on TEM studies of aged tritides, the swelling behavior, hardness measurements, selected mechanical properties…
Abstract Thiolate-bridged dinuclear cobalt(II), iron(II), and Manganese(II) complexes and trinuclear manganese(II) complexes of thiolic ligands, 2-[(2-aminoethyl)amino]ethanethiol, 2-[(3-aminopropyl)amino]ethanethiol, 2-[(2-pyridylmethyl)amino]ethanethiol, and 2-[[(2-pyridylethyl]amino]ethanethiol, were prepared and t…
Abstract Gum compounds of natural rubber (NR) and styrene‐butadiene rubber (SBR) are vulcanized at different temperatures and the cure characteristics and vulcanizate properties are compared. The optimum cure time at a particular vulcanization temperature could be expressed empirically in terms of that temperature usi…