Materials Literature
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The model of human Fc fragment was refined at 2.9-A resolution. Two different automated procedures for crystallographic refinement were used [Deisenhofer, J., & Steigemann, W. (1975) Acta Crystallogr., Sec. B B31, 238; Jack, A., & Levitt, M. (1978) Acta Crystallogr., Sect. A A34, 931]. The final R value is 0.22. The d…
Polarized reflectance measurements from the far infrared to the visible are reported for ${(\mathrm{TMTSF})}_{2}$P${\mathrm{F}}_{6}$. At low temperatures, both parallel and perpendicular polarizations show plasma edges in the infrared with metallic reflection below these edges, indicating two- or three-dimensional beh…
Structural phase transitions in K 2 CO 3 have been investigated using light scattering techniques. The Raman spectrum of the high-temperature hexagonal phase consists of a very broad structureless band which suggests that the system is highly anharmonic. Below the hexagonal-monoclinic transition at T cl =693K the auth…
Powdered and single crystal specimens of dysprosium manganate, DyMn 2 O 5 , have been studied by neutron diffraction at temperatures between ambient and 4.2K. Magnetic transitions are observed at 44K, 18K and 8.4K. Both manganese and dysprosium moments are ordered below 8.4K, where the magnetic structure has been refi…
Standard x-ray diffraction in which a reflection goemetry is used is shown to have a simple interpretation and adequate sensitivity for determining the structure of monolayers. It has been utilized to verify that subsurface strain occurs in Ge(001)-(2\ifmmode\times\else\texttimes\fi{}1) reconstruction.
The luminescence properties of yttrium niobate are reported. Two emission bands are observed, one in the blue and the other in the yellow spectral region. Decay measurements on the blue emission, which is the intrinsic niobate luminescence, provide evidence that this luminescence cannot be described with a tetrahedral…
The refractive index of pure and GeO2-doped silica glasses was measured at wavelengths from 0.4 μm to 2.1 μm, over a temperature range from 20°C to 540°C. Values for the thermal coefficient of the refractive index (about 1.2×10−5/°C at 1.3 μm) were almost identical for both glasses. The data showed that material dispe…
The production of significant concentrations of O(3P) in the gas phase reaction of hydrogen atoms with ozone in a fast flow discharge system at 1.1±0.1 Torr total pressure in Ar and at room temperature has been reported earlier. These yields were observed to be independent of the concentration of known deactivators of…
Ground state oxygen atoms, generated by visible photolysis of ozone, have been reacted with CH3SCH3 and CH3SH in argon matrices. For CH3SCH3, a stepwise addition to form DMSO and dimethylsulfone was observed. Methanethiol reactions with O atoms were more complex, leading to production of CH3SOH, CH3OSH, CH3S(O)H, and…
$3d$ core-level x-ray photoelectron spectrum (XPS) of Eu in Eu${\mathrm{Cu}}_{2}$${\mathrm{Si}}_{2}$ exhibits two sets of simple spin-orbit split structures. We have assigned these structures to two different valence states of Eu (${\mathrm{Eu}}^{2+}$ and ${\mathrm{Eu}}^{3+}$) in Eu${\mathrm{Cu}}_{2}$${\mathrm{Si}}_{2…
The elastic structure factor of an unpinned charge-density wave (CDW) is derived. Both phase and amplitude excitations are studied. Phase modes cause a reduction of the intensity of CDW satellite peaks of any order. Amplitude modes, however, do not alter appreciably the intensity of the first-order CDW satellite. In f…
We present a thorough investigation of nonradiative energy-transfer processes in various rare-earth ($R$) pentaphosphates ($R{\mathrm{P}}_{5}{\mathrm{O}}_{14}$). Using time-resolved fluorescence spectroscopy, different crystals with high and low concentration of the interacting ${R}^{3+}$ ions were investigated. It tu…
Morphological instability occurring during high-velocity Si crystal growth from an impurity containing melt is examined in detail. The experimental conditions are achieved by annealing an ion-implanted Si layer with pulsed laser radiation. Computer modeling is employed to understand the heat flow and impurity diffusio…
The feasability of using poly(α-hydroxy-acid)s (poly-(glycolic acid), poly(L-lactic acid), L and D-lactic acid stereocopolymers and copolymers of glycolic and L- and D-lactic acids) for processing bioresorbable bone plates, screws, nails etc..., is questioned in regard to the requirements for effective applications an…
We modify Knauss and Wilson's approach to the theory of lattice thermal conductivity of anharmonic crystals and show that the Zwanzig-Mori projection-operator method then gives a result similar to that obtained from Green's-function methods.
A tristability is observed in the electric-field-induced liquid-crystal (LC) cholesteric-to-nematic phase transformation. The stable memory associated with the tristability has a potential application to display devices. The N-C relaxation characteristics, which determine the tristability, are found to be related to t…
In the previous paper [J. Chem. Phys. 70, 4199 (1979)] the high-spin ⇄ low-spin transitions were studied by using the model based on the static treatment of intramolecular distortion, in which the discontinuous spin transitions may be induced by the Jahn–Teller effect. In the present paper the intramolecular distortio…
Measurements of low-temperature specific heat $C$, thermal conductivity $\ensuremath{\kappa}$, and dielectric dispersion have been made on crystalline samples of the superionic conductor ${\mathrm{Li}}_{3}$N, the oxygen conductor ${\mathrm{Y}}_{2}$${\mathrm{O}}_{3}$-stabilized Zr${\mathrm{O}}_{2}$, and the relaxation…
We have investigated phosphorescence, thermoluminescence, and photostimulated luminescence in manganese activated zinc silicate phosphors, both with and without arsenic doping. Both phosphorescence and photostimulated luminescence intensities are found to decay as the reciprocal of the time, a result which requires a…
Observed 7-eV satellites in the x-ray---photoemission spectra of U${\mathrm{Ga}}_{2}$ and other $B$-group compounds are shown to be due to two-hole final states as confirmed by existing Auger data. The presence of these satellites is an indication for a weak $\mathrm{fd}$ hybridization and, when compared to uranium---…