Materials Literature
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The electrical transport properties of zinc oxide varistors are correlated with the chemistry of their grain boundaries. An adsorbed layer of bismuth, about 5 Å thick, is necessary to create potential barriers at the grain boundaries. The height of these potential barriers depends sensitively on the excess amount of o…
Via ellipsometry, the time-dependent profiles of liquid droplets spreading completely on plane solid substrates are measured in the range 0--200 \AA{}. Two different surfaces are used, a ``high-energy'' surface (wettable by water) and a ``low-energy'' surface (Langmuir-Blodgett layer of a double-bond-terminated fatty…
A series of interstitial ternary nitrides R 2 Fe 17 N y with 2.3<y<2.9 has been prepared for R=Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Lu and Y. The nitrides have structures related to those of Th 2 Zn 17 or Th 2 Ni 17 , but the unit cell volumes are 6-7% greater, and the magnetic ordering temperatures some 400 K high…
The study of magnetic phase transitions in insulating molecular solids provides new insights into mechanisms of magnetic coupling in the solid state and into critical phenomena associated with these transitions. Only a few such materials are known to display cooperative magnetic properties. The use of high-spin molecu…
The enzymatic degradation of cellulose is an important process, both ecologically and commercially. The three-dimensional structure of a cellulase, the enzymatic core of CBHII from the fungus Trichoderma reesei reveals an alpha-beta protein with a fold similar to but different from the widely occurring barrel topology…
Photoluminescence, thermoluminescence and temperature dependent EPR measurements on Zn 4 B 6 O 13 are reported and discussed. The photoluminescence properties show that the intrinsic violet emission of this compound may originate from a strongly localised self-trapped exciton state. Four types of UV-induced paramagnet…
We study the effects of hydrodynamic interactions on the diffusion of hard spheres in concentrated suspensions. Using a multiple-light-scattering technique that measures the early-time behavior, we find ${\mathit{D}}_{\mathrm{eff}}$/${\mathit{D}}_{0}$=1-(1.86\ifmmode\pm\else\textpm\fi{}0.07)\ensuremath{\varphi}, where…
Current interest in all-optical waveguide devices has created a need for suitable nonlinear materials and fabrication techniques. To meet this need, we have made optical waveguides using ion exchange in two glasses, which were designed both to have large optical nonlinearities and to be compatible with the ion-exchang…
Dans le cadre d'etude des sediments de l'habitat des bivalves dulcaquicoles, une technique d'echantillonnage des eaux interstitielles, primitivement decrite pour les lits rocheux d'eaux courantes par Husmann, a ete modifiee pour une utilisation a long terme dans les sables et graviers d'eaux courantes ou stagnantes.La…
Abstract The hydrothermal treatment of an (NH4)2O/MoO3 mixture at 200 °C (teflon autoclave) yields (NH 4 ) 2 Mo 2 O 7 , (NH 4 ) 8 Mo 10 O 34 and the title compound (NH 4 ) 2 Mo 4 O 13 (I).
The structure of yeast triosephosphate isomerase (TIM) has been solved at 3.0-A resolution and refined at 1.9-A resolution to an R factor of 21.0%. The final model consists of all non-hydrogen atoms in the polypeptide chain and 119 water molecules, a number of which are found in the interior of the protein. The struct…
Crystallization conditions are found and Czochralski method is used for the first time for growing single crystals of the trigonal acentric La3Ga5SiO14 compound with Ln3+ ions (Ln3+ = Pr3+, Ho3+, and Er3+). The behaviour of the Ln3+ activators in the grown disordered crystals is studied by analyzing the results of con…
Results are given of experimental and theoretical investigations of electron emission, observed under plastic deformation of colored alkali halide crystals. The emission is shown to be due to Auger process by the electrons pushed out of the surface from F-centres by dislocation. A comparison of theory and experiment p…
A new type of chalcone crystal was prepared. Anisotropic indices with wavelength dispersion were measured by the Brewster angle method. The two largest second-harmonic generation (SHG) tensor components were determined by the wedge method and compared with d11 of 2-methyl-4-nitroaniline. Calculated collinear and nonco…
The phenomenon termed fractoemission was monitored in soda-lime-silica glass specimens during slow crack growth. No electron, ion, or photon signals were detected until crack velocities reached approximately 10−2 m/s. These observations suggest that the more intense fractoemissions observed during fast fracture are du…
Investigations of the electromechanical properties of BTS-ceramics show unusual strain-field curves and extraordinary high weak-signal electrostrictive R coefficients. In the process of selecting two examples (BTS-10 and BTS-13) it is illustrated that the strain-field curves differ significantly from those of lead per…
A neutronographic study is made of magnetic structure and spin-orientational transitions in polycrystalline samples of the system BaCo2−xZnxFe16O27 (Co2−xZnxW). Along with this studies measurements of the macroscopic magnetic characteristics, X-ray dilatometry, and DTA are performed. The diagram of the magnetic state…
The internal tensile stress in polycrystalline diamond films deposited on silicon substrates has been measured from 100 to 700 K by a vibrating-membrane method. The stress increases strongly with temperature, in a manner consistent with the elastic accommodation of the differential thermal strain between diamond and s…
We present results on the resistivity \ensuremath{\rho}, specific heat ${\mathit{C}}_{\mathit{p}}$, and susceptibility \ensuremath{\chi} of ${\mathrm{K}}_{0.3}$${\mathrm{MoO}}_{3}$ near the Peierls transition ${\mathit{T}}_{\mathit{p}}$ at 180 K. Our resistivity measurements demonstrate that fluctuations intrinsic to…
The crystal structure of porin from Rhodobacter capsulatus strain 37b4 has been solved at 3.0 A (1 A = 0.1 nm) resolution by multiple isomorphous replacement and solvent-flattening. The three pores of the trimer are well defined in the electron density map. Each pore consists of a 16-stranded beta-barrel which travers…