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Investigations of tin( II ) halide aqueous solutions and solvent extracts by 119 Sn nuclear magnetic resonance spectroscopy: characterisation of the trihalogenostannate( II ) anions [SnX 3 ] – , [SnX 2 Y] – , and [SnX(Y)Z] – (X, Y, or Z = Cl, Br, or I)

Jan M. Coddington、Michael J. Taylor1989-01-01Journal of the Chemical Society Dalton Transactions

The 119Sn chemical shifts of all ten trihalogenostannate(II) anions [SnClxBryIz]–(x+y+z= 3) are observed in diethyl ether extracts of tin(II) mixed-halide systems measured at –60°C. The tin(II) nuclear shielding order I < Br < Cl is the opposite of that found in tin(iv) halide systems. At room temperature, the tin res…

Crystal Structures and PropertiesRadioactive element chemistry and processingSolid-state spectroscopy and crystallography

Purification and characterisation of NAD-glutamate dehydrogenase from Aspergillus nidulans

Lewis Stevens、Doris Duncan、Patricia Robertson1989-01-01FEMS Microbiology Letters

NAD-Glutamate dehydrogenase has been purified from mycelia of A. nidulans. The enzyme comprises subunits of 110 kDa. It is located in the cytosol. It is completely denatured by 1.0 M guanidine hydrochloride, and is not renatured by subsequent dilution. Isophthalate is a strong competitive inhibitor and the enzyme is a…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismGABA and Rice Research

Contrôle électrochimique de la morphologie. Adhérence, brillance et croissance des films de polythiophène

Toribio F. Otero、E. de Larreta-Azelain1989-01-01Journal de Chimie Physique

L’emploi de différentes techniques électrochimiques nous a permis l’obtention de couches de polythiophène avec différentes morphologies, adhérences, brillances, etc. L’emploi de courant alternatif de fréquence croissante donne lieu à des structures de plus en plus plates, adhérentes et brillantes. Le résultat est simi…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsPolymer composites and self-healing

The effect of powder properties on the dry impact blending preparation method.

Hirotaka Honda、Takashi Matsuno、Masumi KOISHI1989-01-01Journal of the Society of Powder Technology Japan

This study deals with a surface modification method in a dry powder/powder handling system. The method is a dry impact blending method which is capable of changing an interactive mixture to composite or encapsulated particles. The effect of powder properties in this method was observed in terms of SEM observations.Nyl…

Polymer crystallization and propertiesHigh-Velocity Impact and Material BehaviorPolymer Foaming and Composites

Pyroelectric, dielectric, piezoelectric, and elastic properties of trigonal guanidinium tetrafluoroborate, C(NH2)3BF4

S. Haussühl1989-01-01Zeitschrift für Kristallographie

Single crystals of guanidinium tetrafluoroborate of optical quality and dimensions up to 60 × 60 × 30 mm have been grown from aqueous solutions. They possess a distinct polar morphology of point symmetry group 3 m and strong pyroelectric, piezoelectric, electrooptic and nonlinear optic effects similar to those observe…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Systematic study of the temperature dependence of the saturation magnetization in Fe, Fe-Ni and Co-based amorphous alloys

M. Liniers、J. Flores、F. J. Bermejo 等 6 位作者1989-01-01IEEE Transactions on Magnetics

Magnetization versus temperature in the temperature interval 2-200 K was measured for amorphous alloys of three different compositions: Fe/sub 81.5/B/sub 14.5/Si/sub 4/, Fe/sub 40/Ni/sub 38/Mo/sub 4/B/sub 18/, and Co/sub 70/Fe/sub 5/Ni/sub 2/Mo/sub 3/B/sub 5/Si/sub 15/. The measurements were performed by means of a SQ…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Short Polyester Fiber Reinforced Natural Rubber Composites

Ajit Kumar Senapati、Sunil K. Narayanankutty、B. Pradhan 等 4 位作者1989-01-01International Journal of Polymeric Materials

The effect of fiber orientation, concentration and L/D ratio on the mechanical properties of short polyester fiber-natural rubber composites have been studied. High anisotropy in the mechanical properties were observed with respect to fiber orientation. Tensile strength, tear resistance and compression set were higher…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Chemistry and catalysis at the metal/metal oxide interface

J. P. S. Badyal、Roger M. Nix、Trevor Rayment 等 4 位作者1989-01-01Faraday Discussions of the Chemical Society

Under appropriate conditions, single-crystal observations are capable of yielding information about reaction mechanisms and transport phenomena which can assist in understanding the behaviour of practical, high metal area, supported catalysts. In the case of chemical catalysis by metals, the literature contains a numb…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions

Bauschinger effect and back stress in a dual phase steel.

M. T.、Baode Sun、Yo Tomota1989-01-01ISIJ International

To clarify the Bauschinger effect behavior in a dual phase steel and the influence of strain again on it, tension-compression tests were carried out using a Mn-V low alloy steel. This steel shows extremely large transient softening and considerable amount of permanent softening. The strain againg at 448 K has been fou…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsMetallurgical and Alloy Processes

Hydrazine and substituted hydrazines as corrosion inhibitors for lead in acetic acid

S. Sankarapapavinasam、F. Pushpanaden、M.F. Ahmed1989-01-01British Corrosion Journal

The effect of hydrazine (Hy) and substituted hydrazines (phenyl hydrazine (PHy ), 2,4-dinitrophenyl hydrazine (2,4-DNPHy), 4-nitrobenzoyl hydrazine (4-NBHy), and tosyl hydrazine (THy)) on the corrosion of lead in acetic acid has been investigated. The inhibitive efficiency ranking of these compounds from both weight l…

Corrosion Behavior and InhibitionConcrete Corrosion and Durability

Bedeutung der Kalium‐Verarmung in der Rhizosphäre und der Tonminerale für die Freisetzung von nichtaustauschbarem Kalium und dessen Bestimmung mit HCl

Ting-Khai Kong、Diedrich Steffens1989-01-01Zeitschrift für Pflanzenernährung und Bodenkunde

Abstract An vier verschiedenen Böden (Basalt‐Braunerde, C‐Horizont einer Keuper‐Braunerde, Marschboden, Löß‐Parabraunerde) wurde untersucht, inwieweit in Wurzelnähe die Fraktionen des austauschbaren K und des HCl‐löslichen nichtaustauschbaren K durch den K‐Entzug von Weidelgras ( Lolium perenne ) abgesenkt werden. Nac…

Soil and Unsaturated FlowClay minerals and soil interactionsChemical Synthesis and Characterization

Ein neuer Strukturtyp bei Barium‐Lanthanoid‐Aluminaten: Ba6Dy2Al4O15

I. Rüter、Hk. Müller‐Buschbaum1989-01-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Mit Einkristall‐Röntgenbeugungsmethoden wurde an Ba 6 Dy 2 Al 4 O 15 ein neuer Strukturtyp gefunden. Es kristallisiert orthorhombisch, Raumgruppe D –Cmcm, a = 5,898; b = 10,183; c = 14,877 Å, Z = 2. Den Aufbau dieser Verbindung bestimmt ein BaO‐Gerüst mit einer 8+1‐Sauerstoffkoordination um Ba 2+ , ferner eck…

Luminescence Properties of Advanced MaterialsNuclear materials and radiation effectsInorganic Chemistry and Materials

Resonant fluorescence line narrowing in La 1-x Nd x P 5 O 14 glass

Yi He Zhang、Liang Zhao、liu yanbin1989-01-01Chinese Physics Letters

The absorption spectra and fluorescence spectra of La 1-x Nd x P 5 O 14 (LNPP) glass were studied. The fluorescence from the level of interest 4 F 3/2 (1) state shows an exponential decay and linear concentration quenching. Time resolved fluorescence line narrowing was observed for LNPP glass with different x values.…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsQuantum optics and atomic interactions

Combined method based on finite differences and charge simulation for calculating electric fields

M. Abdel‐Salam、Mohamed Th. El-Mohandes1989-01-01IEEE Transactions on Industry Applications

A combined method based on the finite-difference method (FDM) and the charge-simulation method (CSM) is proposed for electric field calculation. In this method, the entire field is divided into two domains, which are analyzed separately with FDM and CSM. These domains are coupled together using the continuity conditio…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaAerosol Filtration and Electrostatic Precipitation

Phase diagrams of cholesteric liquid crystals obtained with a generalized Landau-de Gennes theory

Lech Longa、Didier P. Monselesan、H-R. Trebin1989-01-01Liquid Crystals

Phase diagrams of chiral nematic liquid crystals are studied within the framework of a generalized Landau-Ginzburg-de Gennes theory. Using the parametrization of Grebel, Hornreich, and Shtrikman for the tensor order parameter Q, all relevant elastic terms are included for the helicoidal phase and the blue phases of ch…

Liquid Crystal Research AdvancementsPlant Reproductive BiologyMolecular spectroscopy and chirality

Comparison of chemical cleaning methods of aluminum alloy vacuum chambers for electron storage rings

A. G. Mathewson、J.-P. Bacher、K. Booth 等 10 位作者1989-01-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Three chemical precleaning methods suitable for aluminum alloy vacuum chambers for electron storage rings have been compared. The methods ranged from vapor degreasing with no chemical attack to light alkaline etching and strong alkaline etching in NaOH. The techniques used to evaluate and compare the three treatments…

Particle Detector Development and PerformanceAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Synthesis, e.s.r. spectrum and magnetic properties of a heterobinuclear complex containing the {Fe III (µ-O)(µ-MeCO 2 ) 2 Mn III } 2+ core

Ursula Bossek、Thomas Weyhermüller、Karl Wieghardt 等 5 位作者1989-01-01Journal of the Chemical Society Chemical Communications

The hydrolysis reaction of a 1:1 mixture of LFeCl3 and LMnCl3(L =N,N′N″-trimethyl-1,4,7-triazacyclononane) in aqueous sodium acetate solution yields green [LFeIII(µ-O)(µ-MeCO2)2MnIIIL]2+(90%) which displays strong intramolecular antiferromagnetic exchange coupling (J=–145 cm–1) yielding a doublet ground state; an e.s.…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Electronic states and potential energy surfaces of silver dihydride: comparison with gold dihydride

K. Balasubramanian、M. Z. Liao1989-01-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTElectronic states and potential energy surfaces of silver dihydride: comparison with gold dihydrideK. Balasubramanian and M. Z. LiaoCite this: J. Phys. Chem. 1989, 93, 1, 89–94Publication Date (Print):January 1, 1989Publication History Published online1 May 2002Published ini…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Thermal Expansion Studies on Cathode and Interconnect Oxides*

Sutham Srilomsak1989-01-01ECS Proceedings Volumes

The thermal expansion of both the cathode and interconnect of the high temperature solid oxide fuel cell is reviewed. The influence of dopants such as Al, Mg and Sr are discussed. Data are presented which suggest that Sr doped LaCrO 3 matches the thermal expansion of zirconia best, but this composition is more suscept…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsCatalysis and Oxidation Reactions