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The Preparation of Organo Colloidal Precious Metal Particles

Kenjiro Meguro、Makoto Torizuka、Kunio Esumi1988-02-01Bulletin of the Chemical Society of Japan

Abstract Platinum particles were prepared by reducing the hydrogen hexachloroplatinate extracted in organic solvents from an aqueous solution by these extractants:dioctadecyldimethylammonium chloride(DDAC), trioctylmethylammonium chloride(TMAC), and trioctylphosphine oxide(TOPO). The extraction ratio of platinum(IV) i…

Gold and Silver Nanoparticles Synthesis and Applications

Experimental study and kinetic modeling of propene oxidation in a jet stirred flow reactor

Philippe Dagaut、Michel Cathonnet、JC Boettner1988-02-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTExperimental study and kinetic modeling of propene oxidation in a jet stirred flow reactorP. Dagaut, M. Cathonnet, and J. C. BoettnerCite this: J. Phys. Chem. 1988, 92, 3, 661–671Publication Date (Print):February 1, 1988Publication History Published online1 May 2002Published…

Catalytic Processes in Materials Science

Mechanical properties and morphology of polypropylene composites II. Effect of polar components in talc‐filled polypropylene

J.E. Stamhuis1988-02-01Polymer Composites

Abstract Using the concept of filler coating, a study has been made of the morphology and mechanical properties of polypropylene/talc/elastomer composites with a series of polar components as added elastomers. Both impact strength and stiffness of the blends were better than those of polypropylene homopolymer. Most of…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Stress Corrosion Cracking and Liquid Metal Embrittlement in Pure Magnesium

S.P. Lynch、P. Trevena1988-02-01CORROSION

Metallographic and fractographic observations of crack growth in pure magnesium in dry air, aqueous, and liquid alkali metal environments are described. Crack growth in dry air at ambient temperatures was macroscopically brittle and occurred parallel to {101¯ X} planes or along grain boundaries, but fracture surfaces…

Corrosion Behavior and InhibitionMagnesium Alloys: Properties and ApplicationsHydrogen embrittlement and corrosion behaviors in metals

RADIATION DOSES AND CAUSE-SPECIFIC MORTALITY AMONG WORKERS AT A NUCLEAR MATERIALS FABRICATION PLANT

Harvey Checkoway、Neil Pearce、Douglas Crawford‐Brown 等 4 位作者1988-02-01American Journal of Epidemiology

A historical cohort mortality study was conducted among 6,781 white male employees from a nuclear weapons materials fabrication plant for the years 1947-1979. Exposures of greatest concern are alpha and gamma radiation emanating primarily from insoluble uranium compounds. Among monitored workers, the mean cumulative a…

Risk and Safety AnalysisGraphite, nuclear technology, radiation studiesChemical Safety and Risk Management

Molecular disorder in columnar-phase discotic liquid-crystal strands

Ernest Fontes、Paul A. Heiney、Masashi Ohba 等 5 位作者1988-02-01Physical Review A

We present x-ray diffraction measurements of freely suspended single-orientation columnar-phase strands of 2,3,7,8,12,13-hexa(-n-tetradecanoyloxy)truxene [(${\mathrm{C}}_{13}$${\mathrm{H}}_{27}$COO${)}_{6}$-TX] which show a dramatic difference between the ordering of the rigid, planar central cores and the flexible hy…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Effect of Phosphate on the Corrosion of Carbon Steel and on the Composition of Corrosion Products in Two-Stage Continuous Cultures of Desulfovibrio desulfuricans

Paul J. Weimer、Margaret J. Van Kavelaar、Charles B. Michel 等 4 位作者1988-02-01Applied and Environmental Microbiology

A field isolate of Desulfovibrio desulfuricans was grown in defined medium in a two-stage continuous culture apparatus with different concentrations of phosphate in the feed medium. The first state (V1) was operated as a conventional chemostat (D = 0.045 h) that was limited in energy source (lactate) or phosphate. The…

Corrosion Behavior and InhibitionMetal Extraction and BioleachingCalcium Carbonate Crystallization and Inhibition

Morphology control of binary polymer mixtures by spinodal decomposition and crystallization. 2. Further studies on PP/EPR

Nobuyuki Inaba、Takeshi Yamada、Shyunichi Suzuki 等 4 位作者1988-02-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMorphology control of binary polymer mixtures by spinodal decomposition and crystallization. 2. Further studies on PP/EPRNobuyuki Inaba, Takeshi Yamada, Shyunichi Suzuki, and Takeji HashimotoCite this: Macromolecules 1988, 21, 2, 407–414Publication Date (Print):February 1, 1…

Polymer crystallization and properties

Betaine compounds–a new family with ferroelectric and incommensurate phases

J. Albers1988-02-01Ferroelectrics

Several addition compounds of the amino acid betaine and inorganic acids were found in the last years to possess structural, ferroelastic, ferroelectric or antiferroelectric phase transitions. As well commensurate as incommensurate phases are observed. The materials are betaine phosphate (antiferroelectric), betaine a…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

A Three-Dimensional Model for the Analysis of Transient Thermal and Conversion Characteristics of Monolithic Catalytic Converters

David K. S. Chen、Edward J. Bissett、Se H. Oh 等 4 位作者1988-02-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">A transient three-dimensional model has been developed to simulate the thermal and conversion characteristics of nonadiabatic monolithic converters operating under flow maldistribution conditions. The model accounts for convective heat and mass transport, gas-solid heat and mass t…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Hydrodesulfurization Studies

Shear‐Lag Analysis of Fiber Push‐Out (Indentation) Tests for Estimating Interfacial Friction Stress in Ceramic‐Matrix Composites

Dinesh K. Shetty1988-02-01Journal of the American Ceramic Society

A shear‐lag analysis is presented for estimating sliding friction stress at fiber‐matrix interfaces in ceramic‐matrix composites using the single‐fiber push‐out test. The analysis includes an approximate correction for the increased interfacial compression and, therefore, the interfacial friction stress arising from t…

Advanced ceramic materials synthesisMechanical Behavior of CompositesMechanical stress and fatigue analysis

Study on the Size and Shape of CuCl Microcrystals Embedded in Alkali‐Chloride Matrices and Their Correlation with Exciton Confinement

T. Itoh、Y. Iwabuchi、Mikio Kataoka1988-02-01physica status solidi (b)

Abstract In alkali chlorides heavily doped with Cu + ions, CuCl microcrystals of different sizes are grown under different heat treatments. Their size and shape are studied using small‐angle X‐ray scattering. A clear correlation is established between the microcrystal size and the blue shift of the exciton luminescenc…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Smectic-C‘‘chevron,’’ a planar liquid-crystal defect: Implications for the surface-stabilized ferroelectric liquid-crystal geometry

Noel A. Clark、T. P. Rieker1988-02-01Physical Review A

The recent discovery of ``chevron'' structured smectic-C (SC) layers in surface-stabilized ferroelectric liquid-crystal (SSFLC) cells [T. P. Rieker, N. A. Clark, G. S. Smith, D. S. Parmar, E. B. Sirota, and C. R. Safinya, Phys. Rev. Lett. 59, 2568 (1987)] enables the understanding of many commonly observed features of…

Liquid Crystal Research AdvancementsPolysaccharides and Plant Cell WallsPlant Reproductive Biology

Penetration of Nylon Ballistic Panels by Fragment-Simulating Projectiles

Robert Prosser1988-02-01Textile Research Journal

The main purpose of this report is to present an analysis of the ballistic behavior of the fragment-simulating projectile (FSP)-nylon cloth system. For a set of V c determinations, plots of V r versus V s can be adequately represented by hyperbolas. The energy lost by an FSP after complete passage through a nylon ball…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorIon-surface interactions and analysis

Stickstoff-Fixierung durch Borabenzol

Günther Maier、Hans Peter Reisenauer、Jochem Henkelmann 等 4 位作者1988-02-01Angewandte Chemie

Auf äußerst milde Weise stabilisiert ist Borabenzol 3 im matrixisolierten Borabenzol-Stickstoff-Addukt 4, das sich IR-spektroskopisch nachweisen ließ. Generell gilt, daß Boraarene und Boraethene nur zu fassen sind, wenn die Elektronenlücke am Bor durch einen Donor gefüllt ist. 4 bildet sich via 3 bei der Blitzpyrolyse…

Hydrogen Storage and MaterialsBoron Compounds in ChemistryInorganic Fluorides and Related Compounds

Calculation of the Raman line broadening on carbonation in synthetic hydroxyapatite

Frits F. M. de Mul、Cees Otto、Jan Greve 等 5 位作者1988-02-01Journal of Raman Spectroscopy

Abstract The position and broadening of the Raman band associated with the phosphate symmetric stretching vibration in hydroxyapatite are simulated using a simple inter‐ and intra‐ionic potential. The results are compared with experimental values. This comparison was made as a function of the incorporation of carbonat…

Glass properties and applicationsCrystal Structures and PropertiesCultural Heritage Materials Analysis

Influence of operating conditions on particulate fouling

Hans Müller‐Steinhagen、F. Reif、Norman Epstein 等 4 位作者1988-02-01The Canadian Journal of Chemical Engineering

Abstract The influence of flow velocity and particle size on the deposition of suspended alumina particles onto heat transfer surfaces was measured with two fouling probes, namely, a heated cylindrical rod in an annulus and a coiled wire in crossflow. Additionally, the response of the fouled probes to such changes as…

Calcium Carbonate Crystallization and Inhibitionnanoparticles nucleation surface interactionsMagnetic and Electromagnetic Effects

Piperazine silicate (EU 19): the structure of a very small crystal determined with synchrotron radiation

Steven J. Andrews、Miroslav Z. Papiz、Robert F. McMeeking 等 8 位作者1988-02-01Acta Crystallographica Section B Structural Science

Single-crystal diffraction data have been recorded for a very small crystal of dimensions 8 x 18 × 175 ~rn 3. From these data the structure of piperazine silicate (EU 19) has been determined and refined to R = 0.094 for 490 observed reflections. Data collection for such a crystal has been made practicable by the high…

Protein Structure and DynamicsEnzyme Structure and FunctionX-ray Diffraction in Crystallography

Translational symmetries in the linear-chain semiconductors K4[Pt2(P2O5H2)4X].cntdot.nH2O (X = Cl, Br, I)

Leslie G. Butler、M. H. ZIETLOW、Chi‐Ming Che 等 9 位作者1988-02-01Journal of the American Chemical Society

The solid-state structures of the linear-chain semiconductors K4[Pt2(P2O5H2)4X]•nH2O (X = Cl, Br, I), abbreviated Pt2Cl, Pt2Br, and Pt2I, have been studied. The X-ray crystal structures of Pt2Cl at 300 and 22 K and of Pt2Br at 19 K are reported. These structures show that Pt2Cl is a composite of alternating units of P…

Crystal structures of chemical compoundsSolid-state spectroscopy and crystallographyOrganometallic Compounds Synthesis and Characterization

Gradient-index rod lens made by a double ion-exchange process

S. Ohmi、Hiroyuki Sakai、Yoshiyuki Asahara 等 6 位作者1988-02-01Applied Optics

Gradient-index rod lenses with a parabolic-index profile have been fabricated by a double Na-Ag ion-exchange process, and their optical characteristics have been evaluated. The numerical aperture and minimum focused spot diameter of the 2-mm diam rod lens were 0.58 and 2.5 microm for lambda = 0.63 microm, respectively…

Advanced X-ray Imaging TechniquesAdvanced optical system designOptical Coatings and Gratings