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Effect of Purity on Diffusivity and Solubility of Hydrogen in Aluminum

Minoru Ichimura、Yasushi Sasajima、Mamoru Imabayashi1992-01-01Materials Transactions JIM

Diffusion coefficient and solubility of hydrogen in commercial pure solid aluminum of 2N(99.7 mass%) were measured by means of the ordinary desorption method, and they were compared with those of high-purity 4N aluminum. A variety of distribution of intermetallic compound particles did not essentially influence the hy…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesHigh Temperature Alloys and Creep

The structure and magnetism of a trimetallic µ-oxo ruthenium( IV ) porphyrin–iron( III ) salicylideneamine complex containing the Fe–O–Ru–O–Fe system

Lewis D. Schulz、Gary D. Fallon、Boujemaa Moubaraki 等 5 位作者1992-01-01Journal of the Chemical Society Chemical Communications

The redox reaction between trans-dioxotetraphenylporphyrinruthenium(VI) and two equivalents of the five-coordinate iron(II) salicylideneamine complex Fe(salmah) in toluene results in the transfer of two electrons and formation of the novel bis-µ-oxo trimetallic complex [RuIV(tpp){OFeIII(salmah)}2] containing first and…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Friction welding of shape memory alloy

Takeshi Shinoda、T. Tsuchiya、Hiroki Takahashi1992-01-01Welding International

(1992). Friction welding of shape memory alloy. Welding International: Vol. 6, No. 1, pp. 20-25.

Welding Techniques and Residual StressesShape Memory Alloy TransformationsLaser and Thermal Forming Techniques

Lariat ether bola-amphiphiles: formation of crown ether based bola-amphisomes

Servando Muñoz、Jesus Mallen、Akio Nakano 等 7 位作者1992-01-01Journal of the Chemical Society Chemical Communications

The first crown ether-based bola-amphiphiles are prepared and are shown to aggregate into a previously unknown type of niosome.

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesSupramolecular Self-Assembly in Materials

Radiation-Induced Segregation in 20Cr/25Ni/Nb Stainless Steel

D.I.R. Norris、Charley Baker、Christopher D. Taylor 等 4 位作者1992-01-01OpenAlex

Intergranular corrosion of irradiated austenitic steels has been attributed to compositional changes produced by radiation-induced segregation at grain boundaries, and the effect has been investigated for the 20Cr/25Ni/Nb stainless steel employed as fuel cladding in advanced gas-cooled reactors. Analytical electron mi…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Formation process of kaolinite from the amorphous mixture of silica and alumina

Ritsuro Miyawaki、Shinji Tomura、Keiichi Inukai 等 7 位作者1992-01-01Clay science/Clay Science

The formation process of kaolinite from the amorphous mixture of silica and alumina by hydrothermal reaction was studied by XRD, IR, DTA-TG, TEM, and high-resolution solid state 29 Si- and 27 Al-MAS/NMR. The amorphous mixture of the starting material prepared with commercially available silica-sol and alumina-sol was…

Glass properties and applicationsArsenic contamination and mitigationClay minerals and soil interactions

Reduction of Platinum Corrosion in Molten Glass

Bernd Fischer1992-01-01Platinum Metals Review

In order to ensure the high quality necessary for use in scientific instruments, most high-technology optical glasses are melted in platinum containers. In general, this noble metal has excellent corrosion and erosion resistance, as well as low solubility, when in contact with molten glass. Therefore the dangers of di…

Material Properties and Applications

Wear Testing of Advanced Materials

R Divakar、P.J. Blau1992-01-01OpenAlex

Description STP 1167 addresses special problems engineers encounter when developing and using wear tests for ceramics and other advanced materials.

Metal and Thin Film MechanicsTribology and Wear AnalysisMetal Alloys Wear and Properties

Performance of Protective Clothing: Fourth Volume

JP McBriarty、NW Henry1992-01-01OpenAlex

Description 80 peer-reviewed papers address these issues: • Hazards and Methods (including aerosols, physical resistance, biological, chemical, pesticides, and thermal and heat) • Field tests, New tests, Evaluations, Design, Physiological, Performance (including field tests, new and improved tests, evaluations, physio…

Textile materials and evaluationsFashion and Cultural Textiles

Development of 800 kV gas-insulated switchgear

H. Toda、Y. Ozaki、Isao Miwa 等 6 位作者1992-01-01IEEE Transactions on Power Delivery

An 800 kV gas-insulated switchgear, with a capacity level recognized as the largest in the world, was developed as the first development of UHV gas-insulated switchgear, and good results were obtained in the type tests for this switchgear. With the gas circuit breaker and the disconnector used in this gas-insulated sw…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaThermal Analysis in Power Transmission

A Mathematical Model for the Influence of Deep‐Level Electronic States on Photoelectrochemical Impedance Spectroscopy: II . Assessment of Characterization Methods Based on Mott‐Schottky Theory

D. Bivings Bonham、Mark E. Orazem1992-01-01Journal of The Electrochemical Society

The impact of the assumptions inherent in using the Mott‐Schottky theory to identify deep‐level electronic states in semiconductors was assessed by comparison to the results of a less restrictive mathematical model. The model, developed in another paper, treated the transport and recombination reactions involving elec…

Transition Metal Oxide NanomaterialsElectrochemical Analysis and ApplicationsElectron and X-Ray Spectroscopy Techniques

Reactivation of poly(3-methylthiophene) following overoxidation in the presence of chloride

Zhigang Qi、Peter G. Pickup1992-01-01Journal of the Chemical Society Chemical Communications

Poly(3-methylthiophene) films made electrochemically inactive by overoxidation in the presence of Cl– can be reactivated both electrochemically and chemically to produce a partially chlorinated conducting polymer.

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

Poly(rA) ioinos poly(rG) poly(rC) to form a tripie helix

Michael Chastain、Ignacio Tinoco1992-01-01Nucleic Acids Research

Poly(rA) binds poly(rG).poly(rC) to form a triple helix. Evidence for this structure includes ultraviolet absorbance mixing curves and melting curves, and circular dichroism spectroscopy. The formation of the triple helix depends on the length of the poly(rC) strand. Triple helix forms when the average length is aroun…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryCovalent Organic Framework Applications

Microstructured fluids: Structure, diffusion and rheology of colloidal dispersions

Thanh Huy Phung、John F. Brady1992-01-01AIP conference proceedings

The behavior of concentrated Brownian suspensions in a linear shear flow is studied numerically. Particle trajectories are calculated by Stokesian dynamics, a molecular‐dynamics‐like method that accurately represents the suspension hydrodynamics, including both many‐body interactions and lubrication. The simulations a…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies

A Mathematical Model for Chemical Vapor Infiltration with Volume Heating

José I. Morell、Demetre J. Economou、Neal R. Amundson1992-01-01Journal of The Electrochemical Society

A detailed mathematical model is presented to investigate the chemical vapor infiltration (CVI) of fiber‐reinforced ceramic composites with a volume‐heating source. Volume heating may be achieved by using microwave power or radio frequency (RF) induction in the case of conductive substrates. The analysis includes a se…

Advanced ceramic materials synthesisEpoxy Resin Curing ProcessesAdvanced Surface Polishing Techniques

X-Ray investigations in low-molecular-weight glassy mesophases

W. Wedler、Petra Hartmann、Udo Bakowsky 等 5 位作者1992-01-01Journal of Materials Chemistry

Pure low-molecular-weight mesogenic compounds as well as mesogenic mixtures, able to form glass phases above room temperature, have been investigated by microscopy, calorimetry and X-ray scattering. Indications for two types of short-range order (SRO) in the glassy state have been found. Diffuse low-angle scattering m…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesMolecular spectroscopy and chirality

Formulation of a universal electron probe microanalysis correction method

V. D. Scott、G. Love1992-01-01X-Ray Spectrometry

Abstract A new correction method for obtaining quantitative electron probe microanalysis results is described. It utilizes data provided by Monte Carlo simulations and tracer measurements to obtain a detailed picture of the way in which the x‐ray emission process is influenced by the relevant experimental parameters.…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Optic properties and EPR spectra of PbTiO3:Mn crystals

A. Molak、K. Wójcik1992-01-01Ferroelectrics

The crystals PbTiO3:Mn have been obtained. The influence of Mn dopant on light absorption, electric conductivity, dielectric permittivity was observed. The defect centers of Mn24, Mn4+, Vo, Fe3+-Vo were determined with EPR test.

Luminescence Properties of Advanced MaterialsGlass properties and applicationsPhotorefractive and Nonlinear Optics

Analysis of partial discharge pulse distribution along transformer windings using digital filtering techniques

Qi Su、R.E. James1992-01-01IEE Proceedings C Generation Transmission and Distribution

The capacitive network often used for the calculation of initial voltage distribution along a transformer winding can be in error for steep impulses. As such pulses are produced by partial discharges (PDs) the application of the concept could contribute to inaccuracies in methods developed for the location of PDs in w…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAdvanced Electrical Measurement Techniques

Molecular Mechanics Studies of Molybdenum Disulphide Catalysts Parameterisation of Molybdenum and Sulphur

Thierry M. Brunier、Michael G. B. Drew、Philip C. H. Mitchell1992-01-01Molecular Simulation

A method for the parameterisation of molybdenum disulphide is presented which reproduces the crystal structure accurately. The method involves calculating parameters such that there is no net force contribution from any individual term of the potential on any atom. Ideal bond lengths and bond angles are taken from the…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsMachine Learning in Materials Science