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The thermal degradation of polyvinyl compounds. I. A new type of molecular still

N. Grassië、H. W. Melville1949-10-07Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract A survey of depolymerization reactions has been made and the importance of the degradation emphasized in addition polymerization especially at high temperatures. In order to follow the course of the thermal degradation it is necessary to remove rapidly and measure the amount of monomer produced. In addition i…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Science and PVC

The Ultraviolet Absorption and Luminescence of Decaborane

George C. Pimentel、Kenneth S. Pitzer1949-10-01The Journal of Chemical Physics

The ultraviolet absorption spectrum of decaborane in cyclohexane shows a broad absorption with a maximum molecular extinction coefficient of 3200±100A at wave-length 2720±50A. The luminescence of decaborane dissolved in a glass at 77°K shows a continuous fluorescence extending from 3630±50A to about 6000A with a broad…

Luminescence and Fluorescent MaterialsMachine Learning in Materials ScienceBoron Compounds in Chemistry

A Low Temperature Single Crystal X-Ray Diffraction Technique

H. S. Kaufman、I. Fankuchen1949-10-01Review of Scientific Instruments

A low temperature x-ray diffraction technique, especially suitable to single crystal work, is described. Crystals are grown in glass capillaries on the x-ray camera. Position and orientation are determined with the aid of a polarizing microscope on the apparatus. A special specimen holder is used which prevents moistu…

Superconducting Materials and ApplicationsX-ray Diffraction in Crystallography

Quantitative Measurements of the Elastic Properties of the Skin and Subcutaneous Tissue in Young and Old Individuals

Esben Kirk、Sven Ancher Kvorning1949-10-01Journal of Gerontology

This is a condensation of a paper presented at the Institute on Problems of aging at Washington University, St. Louis, April 11-12, 1949, as part of the session on the biology of aging. Using an apparatus designed by schade in 1912 Drs. Kirk and Kvorning conducted a series of investigations to determine the elastic pr…

Textile materials and evaluations

The structure of Bolivian crocidolite

E. J. W. Whittaker1949-10-01Acta Crystallographica

Bolivian crocidolite, a fibrous amphibole, is shown to contain fibres approximating to single crystals. The structure, which is determined by standard methods leading to a Fourier projection on (001), is shown to be generally similar to that of tremolite. The more precise determination reveals certain departures from…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsClay minerals and soil interactions

Characterization of Heavy Metal Soaps by X-Ray Diffraction

Robert D. Vold、G. S. Hattiangdi1949-10-01Industrial & Engineering Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCharacterization of Heavy Metal Soaps by X-Ray DiffractionR. D. Vold and G. S. HattiangdiCite this: Ind. Eng. Chem. 1949, 41, 10, 2311–2320Publication Date (Print):October 1, 1949Publication History Published online1 May 2002Published inissue 1 October 1949https://pubs.acs.o…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Structural Investigations by Means of Nuclear Magnetism. I. Rigid Crystal Lattices

H. S. Gutowsky、G. B. Kistiakowsky、G. E. Pake 等 4 位作者1949-10-01The Journal of Chemical Physics

Experimental absorption line shapes at nuclear magnetic resonance are given for several simple assemblies of nuclei, with spin ½, in the solid state at temperatures between 90° and 95°K. Analysis of these data is facilitated by the theory of Van Vleck which relates the second moment of the absorption line in a rigid l…

Crystal Structures and PropertiesAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

A Note on the Anisotrophy of Cellulose Acetate Fibres

J. Preston、J.H.E.J ACKSON、M. V. Nimkar1949-10-01Journal of the Society of Dyers and Colourists

An examination has been made of the anistropies of aome cellulose scetate fibers and of cellulose fibers regenerated from them. On comparison the celloulose fibers show comparable but somewhat larger anisotropies than the corresponding cellouls acetate fibers.

Textile materials and evaluations

Some Properties of Thin Evaporated Films on Glass*

Joseph L. Rood1949-10-01Journal of the Optical Society of America

Properties of thin evaporated films of MgF2 and of CaSiO3 on glass were studied. Thicknesses of the films were determined from measurements of reflected intensity as a function of wave-length, and indices of refraction computed. Density measurements were carried out for MgF2 films. All these properties were found to b…

High voltage insulation and dielectric phenomenaOptical Coatings and Gratings

Electrochemical Behavior of Zinc and Steel In Aqueous Media

R. B. Hoxeng、Carl F. Prutton1949-10-01CORROSION

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Facebook Twitter LinkedIn Email Tools Icon Tools Get Permissions Cite Icon Cite Search Site Citation R. B. HOXENG, C. F. PRUTTON; Electrochemical Behavior of Zinc and Steel In Aqueous Media. CORROSION 1 Octob…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsElectrochemical Analysis and Applications

A High Temperature Precision X-Ray Camera: Some Measurements of the Thermal Coefficients of Expansion of Beryllium

Paul Gordon1949-10-01Journal of Applied Physics

A high temperature precision x-ray camera has been designed and constructed by modification of the familiar back-reflection symmetrical focusing type of camera. The camera, specimen, and furnace are used within a vacuum chamber to avoid oxidation. The apparatus in its present form has been employed at temperatures up…

Fusion materials and technologiesNuclear Materials and PropertiesX-ray Diffraction in Crystallography

Thermodynamics of high‐polymer solutions. III. Swelling of cross‐linked rubber

Robert L. Scott、Michael Magat1949-10-01Journal of Polymer Science

Abstract The equilibrium swelling of the gum stocks of twelve different rubber vulcanizates has been measured in thirteen organic solvents. The results are in good agreement with the theory of Flory and Rehner. Values of the internal pressure (cohesive energy density) and the average molal volume between cross‐linkage…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Viscose Processing of Cellulose

R. L. Mitchell1949-10-01Industrial & Engineering Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTViscose Processing of CelluloseR. L. MitchellCite this: Ind. Eng. Chem. 1949, 41, 10, 2197–2201Publication Date (Print):October 1, 1949Publication History Published online1 May 2002Published inissue 1 October 1949https://pubs.acs.org/doi/10.1021/ie50478a033https://doi.org/10…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Crystal chemical studies of the 5f-series of elements. X. Sulfides and oxysulfides

W. H. Zachariasen1949-10-01Acta Crystallographica

A number of sulfides and oxy-sulfides of 5f-elements and of cerium have crystal structures of known types as follows: NaCl-type: CeS, ThS, US, PuS; Sb2S3-type: Th2S3, U2S3, Np2S3; PbCl2-type: ThS2; PbFCl-type: ThOS, UOS, NpOS.

Solid-state spectroscopy and crystallographyThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Precipitation from Solid Solutions of C and N in α-Iron

C. A. Wert1949-10-01Journal of Applied Physics

The formation of precipitates from the solid solutions of C and N in α-iron has been studied by means of the internal friction peak associated with the stress-induced interstitial diffusion of the solute atoms. A transformation law has been found to fit the experimental data. The data are interpreted as showing the fo…

Microstructure and Mechanical Properties of SteelsFusion materials and technologiesMetallurgical Processes and Thermodynamics

The probability distribution of X-ray intensities

A. J. C. Wilson1949-10-01Acta Crystallographica

In a crystal without symmetry elements and containing a sufficiently large number of atoms the probability of the hkl reflexion having an intensity between I and I + dI is P(I) dI, where P(I) = Σ−1 exp{−I/Σ}, and Σ is the sum of the squares of the scattering factors of the atoms. In a centrosymmetric crystal the proba…

X-ray Spectroscopy and Fluorescence AnalysisX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena