Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFirst example of a discrete copper(III, II) mixed-valence complex: the triangular CuIIICuII2O core circumscribed by oxime ligandsDipankar Datta and Animesh ChakravortyCite this: Inorg. Chem. 1983, 22, 11, 1611–1613Publication Date (Print):May 1, 1983Publication History Publi…
The thermal decomposition and the glass transition temperature Tg of poly(phenyl methacrylate) (PPhMA) and poly(cyclohexyl methacrylate) (PcHU) were studied with a differential scanning calorimeter (DSC). The undecomposed and decomposed polymers were analyzed by gel permeation chromatography (GPC) for molecular weight…
The condensation of organoantimony(V) dihalides with diamines forming antimony(V) polyamines employing the interfacial technique is described. Structural characterization was accomplished by employing elemental analysis, light-scattering photometry, infrared spectroscopy, control reactions, and mass spectroscopy. The…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEsterification reaction of poly[(chloromethyl)styrene] with salts of carboxylic acid using phase-transfer catalystsTadatomi Nishikubo, T. Iizawa, K. Kobayashi, Y. Masuda, and M. OkawaraCite this: Macromolecules 1983, 16, 5, 722–727Publication Date (Print):May 1, 1983Publicat…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnion ordering in mixed valence dicesium hexachloroantimonate (Cs2SbCl6) and related saltsKosmos Prassides, Peter Day, and Anthony K. CheethamCite this: J. Am. Chem. Soc. 1983, 105, 10, 3366–3368Publication Date (Print):May 1, 1983Publication History Published online1 May 20…
ABSTRACT Bovine skin corium obtained from freshly slaughtered cattle of increasing biological age showed greater resistance to the action of acids, as measured by extractable collagen. Citrate‐soluble content of corium from fetal skin was 30.9%, while that of 3 to 6‐wk old calf was 6.4% and of 18‐month steer was 3.2%.…
New anthraquinone dyes have been developed with high-order parameters and solubilities in both positive and negative dielectric anisotropy liquid-crystal hosts. The dyes show high stability and allow the formulation of black mixtures which show good contrast in a range of display devices.
Fission product yields for 24 masses were determined for the fission of $^{239}\mathrm{Pu}$ with essentially monoenergetic neutrons of 0.17, 1.0, 2.0, 3.4, 4.5, 6.1, and 7.9 MeV. Fission product activities were measured by Ge(Li) $\ensuremath{\gamma}$-ray spectrometry of irradiated $^{239}\mathrm{Pu}$ targets and by c…
Multiple regression analysis was used to determine whether certain deformation properties (stiffness, shear, extensibility) and structural characteristics (fabric weight, thickness, and density) serve as reliable predictors of the drape of knitted fabrics. Stiffness, measured in terms of bending length, thickness, and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReduction of carbon monoxide by binuclear tantalum hydride complexesPatricia A. Belmonte, F. Geoffrey N. Cloke, and Richard R. SchrockCite this: J. Am. Chem. Soc. 1983, 105, 9, 2643–2650Publication Date (Print):May 1, 1983Publication History Published online1 May 2002Publish…
The sequence of the structural phase transitions of the layer compound (C 2 H 5 NH 3 ) 3 FeCl 4 has been determined with the ultrasonic, dielectric and polarized microscope measurements as following; Phase I ( D 4 h 17 )–(378.8 K)–Phase II ( D 2 h 18 )–(203.5 K)–Phase III–(133.7 K)–Phase IV. The set of the critical ex…
Abstract Cake staling, which is associated with changes in crumb firmness and moistness, has been shown to be related to two basic processes occurring in the crumb. These are an intrinsic firming process of the cell‐wall material of the crumb and the macroscopic migration of moisture from the central areas of the crum…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotochromism of monolayers of poly(methylmethacrylate) having spirobenzopyran side groupsR. Vilanove, H. Hervet, H. Gruler, and F. RondelezCite this: Macromolecules 1983, 16, 5, 825–831Publication Date (Print):May 1, 1983Publication History Published online1 May 2002Publish…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReversible exchange of (.eta.5-cyclopentadienyl)(dinitrosoalkane)cobalt complexes with alkenes. Kinetic and spectroscopic evidence for cyclopentadienyldinitrosylcobalt as a reactive intermediatePaul N. Becker and Robert G. BergmanCite this: J. Am. Chem. Soc. 1983, 105, 10, 2…
Abstract “Catalyst‐free” trimethylsilyl end‐blocked polydimethylsiloxanes of M n = 68,300 and 111,000 were isothermally depolymerized above 400°C. The volatilized products were a mixture of cyclic oligomers and trace quantities of Me 3 Si(OSiMe 2 ) n OSiMe 3 ( n = 0,1). The relative degree of polymerization was follow…
Abstract An old problem is addressed being the description of the dielectric response of electrons near the surface of an infinite half space to perturbing potentials and external charges. Taking into account spatial dispersion, expressions are derived for the screened potential and the inverse dielectric function wit…
Commercial manganin stress gauges are used in planar impact experiments to determine spall strengths of variously heat-treated 2024A1 specimens. A one-dimensional Lagrangian code is used to find the best fit of calculated versus experimental stress histories by varying the spall strength in the code and using a simple…
Tin oxide thin films were exposed to an rf excited hydrogen plasma (100 mTorr) for various times. The plasma system was operated in a self-biased mode. X-ray photoelectron spectroscopy analysis of vacuum transferred samples shows that SnO2 is reduced. A thin self-limiting layer of elemental Sn forms on the reduced fil…
In view of the practical difficulties already encountered plus those anticipated in the implementation of many-body hydrodynamic interactions, we examine a number of empirically screened two particle mobility tensors. The empirical screening constant(s), which depend on the dispersion concentration, are adjusted to gi…
Concrete containing both portland cement and fly ash were evaluated to determine the effect of fly ash on air-void stability. Tests indicate that air contents of concrete containing Class C fly ash appear to be more stable than those of concrete containing Class F fly ash. The higher the organic matter content of a fl…