Materials Literature
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ABSTRACT During heterogeneous photothermal catalysis, catalysts are prone to undergo random and disordered structural evolution, which poses a severe challenge to the construction of advanced photothermal catalytic systems integrating photoexcited charge carrier separation, molecular activation, and active‐site engine…
ZUSAMMENFASSUNG Die Natur vereint Stabilität und Responsivität in einzelnen molekularen Gerüsten und schafft so Systeme, die strukturell persistent bleiben und zugleich gezielt in aktivierte Funktionszustände überführt werden können. Tetrazole verkörpern dieses Prinzip in der synthetischen Chemie, indem sie aromatisch…
Abstract Atomically dispersed catalysts (ADCs) have drawn considerable attention in recent years for their promising activity in heterogeneous catalysis. Conventional catalyst sintering theory largely ignores the entropy effect and suggests that ADCs are normally thermodynamically unstable due to their high surface fr…
The rapid proliferation of the Internet of Things (IoT) and wearable electronics necessitates sustainable and autonomous energy solutions beyond conventional batteries. Triboelectric nanogenerators (TENGs) have emerged as a promising technology for harvesting ambient mechanical energy, yet their practical deployment i…
Despite the exponential growth in genome sequencing, the functional annotation of genes, particularly the discovery of novel enzymatic activities, remains a formidable challenge. This gap is exacerbated by annotation biases that propagate assumptions about enzyme function across homologous sequences. Here, we report t…
Traditional descriptions of interparticle forces rely heavily on scalar interaction potentials that depend solely on the separation distance between particles. This scalar framework, while effective for many isotropic systems, fails to capture subtle directional dependencies that arise in complex materials, such as li…
FINDING: Golden Ratio φ governs self-similarity across geometric, temporal, and spatial scales, with explicit mathematical definitions from rectangle invariance and pentagon diagonals. | MATH: φ = (1+√5)/2 ≈ 1.6180339; φ⁻¹ = φ-1 ≈ 0.618; φ² = φ+1 ≈ 2.618; φ² - φ - 1 = 0. Fibonacci spiral construction via quarter-circl…
High-voltage spinel LiNi0.5Mn1.5O4 (LNMO) is a promising cathode for next-generation lithium-ion batteries, yet its application is limited by structural instability and poor high-temperature/high-rate performance. Here, spherical secondary polycrystalline aggregate (LNMO-PC), micron-sized primary particle (single-crys…
ABSTRACT Ultrathin metal films approaching the transdimensional (TD) thickness limit, an intermediate regime between 2D and 3D, provide a promising route for light–matter interaction control and manipulation, yet their nonlinear optical response near the epsilon‐near‐zero (ENZ) condition remains poorly understood. Her…
Abstract Environmental and resource crises demand clean energy. Magnesium batteries offer high capacity, safety, and low cost, but severe passivation and self-corrosion in aqueous environments hinder their development. This study introduces an innovative method for electrochemically synthesizing a ZIF-67/Ppy composite…
Terrestrial microplastics are increasing in abundance and are an emerging contaminant of concern, particularly in agroecosystems where plastic mulch use and subsequent soil contamination are prevalent. Microplastics can impact soil physical, chemical, and biological properties; however, the mechanistic drivers of thes…
Polydimethylsiloxane (PDMS)-based fouling-release coatings perform poorly in static conditions due to their lack of antifouling mechanisms like biocidal activity or surface repellence. The high melt viscosity, limited chain-end functional groups, and lack of intermolecular interactions of linear PDMS chains lead to ch…
Abstract Flexible phase change materials (PCMs) are pivotal for mitigating overheating in compact electronics, yet are often constrained by solid-state rigidity, leakage, and low thermal conductivity. Herein, we present an anion-modulated ionic cross-linking strategy to fabricate flexible and leakage-proof alginate-ba…
As a rising member of carbon allotropes, graphdiyne holds significant research value in terms of both its properties and applications. For properties, there is currently a lack of methods to assess the polymerization degree of graphdiyne, which is crucial to establish a standardized evaluation system for graphdiyne pr…
This paper presents a methodology to evaluate the entire process of thermal evolution and fracture failure within stay cables subjected to sheath fires. Computer software FDS 2021 and ABAQUS 2021 are applied to build a sequentially thermos–mechanics coupled method integrating thermal, structural, and fracture dynamic…
Abstract A new hybrid salt [4-apyH][Cr(dipic) 2 ]·3H 2 O ( 1 ) ([4-apyH] + = [C 5 H 7 N 2 ] + = 4-aminopyridinium cation, dipic 2− = dipicolinato(2−) ligand) has been synthesized and characterized by elemental and thermal analyses, FT-IR and UV/Vis spectroscopies, EPR, single-crystal and powder X-ray diffraction. Salt…
ABSTRACT Increasing the compaction density of dry‐processed thick iodine cathodes is essential for enhancing energy density, yet remains hindered by sluggish reaction kinetics and aggravated polyiodide shuttling. Herein, we report an implanted Zn 2+ ‐conducting (PAMPS‐Zn, poly(zinc 2‐acrylamido‐2‐methylpropane sulfona…
Abstract Natural antifoulant borneol was combined with a hydrolyzable cationic ester to develop amphiphilic copolymer poly(lauryl methacrylate)-b-poly(carboxybetaine methacrylate ester-co-isobornyl methacrylate) (PLMA-b-P(CBMAE-co-IBOMA)). Taking advantage of the zwitterionic groups resulting from the hydrolysis of CB…
Benzoxazoles are key heteroaromatic motifs found in pharmaceuticals, bioactive natural products, and synthetic lead structures. However, complex benzoxazole derivatives, such as bis(benzoxazoles), are challenging to produce using conventional chemical synthesis. Alternatively, biosynthetic pathways represent a promisi…
Zeolites have been proposed as carrier materials for the storage and controlled release of the anticancer drug 5-fluorouracil (5-FU). Containing both hydrogen-bond donor and acceptor groups, 5-FU molecules can form relatively strong intermolecular hydrogen bonds. Prior work on zeolite beta has shown that guest-guest i…