The influence of dislocations on crystal growth
F. C. Frank, Discuss. Faraday Soc., 1949, 5, 48 DOI: 10.1039/DF9490500048
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F. C. Frank, Discuss. Faraday Soc., 1949, 5, 48 DOI: 10.1039/DF9490500048
Abstract The problem of metallic conduction at high frequencies and low temperatures, recently discussed by Pippard, is reformulated using the general methods of the theory of metals, and exact solutions are obtained which are valid for all frequencies and temperatures. It is shown that, for large values of the free p…
In certain exponential absorption experiments, notably measurements of cross sections by transmission, it is important to achieve minimum statistical error in a limited time or to minimize the counting time required to measure the absorption coefficient with a preassigned accuracy. The conditions required to attain th…
A bstract A study has been made of the transmittance of near‐infrared energy by a number of binary glasses. Of the systems studied, the lithia‐silica and lead oxide‐silica glasses were found to have the highest transmittance of energy in the range of wave lengths from 3.0 to 5.0 microns. The transmittance of lithia‐si…
A technique is developed for the quantitative evaluation of the deformation components of visco-elastic materials when these are subjected to tensile loading, for loads ranging from zero to rupture, under dynamic loading conditions, at constant rates of load, elongation, or strain for different magnitudes of constant…
Metahalloysite is one of the kaolin group of minerals with a composition approximating to the formuia Al 2 O 3 .2SiO 2 .2H 2 O, and its structure is generally considered to be built of composite layers of atoms of the kind found in other minerals of this group. It differs from them most strikingly in that it can be pr…
A study has been made of electron bombardment conductivity in diamond using primary electrons of energies up to 14,000 ev. An alternating field method is used which reduces or eliminates the effects of internal space charge fields. Data on internal yields as a function of crystal field are given for both electron and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEquilibria in Hydrogenation of Esters and of IndolesHomer Adkins and Robert E. Burks Jr.Cite this: J. Am. Chem. Soc. 1948, 70, 12, 4174–4177Publication Date (Print):December 1, 1948Publication History Published online1 May 2002Published inissue 1 December 1948https://pubs.ac…
The experiments described below on the dehydration of halloysite were largely carried out in the laboratoire Central des Services Chimiques de l'État, Paris, where we enjoyed not only the excellent facilities of the laboratory but also the advice of Monsieur J. Méring and Mile R. Glaser who had made similar studies of…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis of AlkoxymethyltrimethylsilanesJohn L. SpeierCite this: J. Am. Chem. Soc. 1948, 70, 12, 4142–4143Publication Date (Print):December 1, 1948Publication History Published online1 May 2002Published inissue 1 December 1948https://pubs.acs.org/doi/10.1021/ja01192a049http…
The crystal structure of ZrOS has been investigated by means of X-ray powder photographs and by powder spectrometry. The substance has a simple cubic lattice with a0 = 5.696 ± 0.002 A. (λ = 1.5418 A.) with space group T4–P213. In the resulting structure Zr shows a co-ordination number of seven, being surrounded by thr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Chemistry of Spiropyrans.Ahmed. MustafaCite this: Chem. Rev. 1948, 43, 3, 509–523Publication Date (Print):December 1, 1948Publication History Published online1 May 2002Published inissue 1 December 1948https://pubs.acs.org/doi/10.1021/cr60136a004https://doi.org/10.1021/cr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolar-Type Rust InhibitorsH. R. Baker and W. A. ZismanCite this: Ind. Eng. Chem. 1948, 40, 12, 2338–2347Publication Date (Print):December 1, 1948Publication History Published online1 May 2002Published inissue 1 December 1948https://pubs.acs.org/doi/10.1021/ie50468a024https:/…
In order to explain the properties of a barium titanate single domain crystal, a previous theory of the ferroelectric effect in rochelle salt has been extended to the three-dimensional structure of barium titanate. This involves six equilibrium positions and results in significant differences from the single bond type…
The crystal structure of hexagonal barium titanate has been determined by X-ray methods. The unit cell, which contains six units of BaTiO3, has a0 = 5.735 A. and c0 = 14.05 A. In the space group C63/mmc all the ions occur at special positions: 2 Ba at (b), 4 Ba at (f), 2 Ti at (a), 4 Ti at (f), 6 O at (h), and 12 O at…
Abstract Polyvinyl alcohol prepared by hydrolyzing polymerized vinyl acetate is partially degraded within a few minutes by reagents known to attack 1,2‐glycol structures. The degree of degradation is limited, however, the final molecular weights of the degraded products being in the range of 3700 to 6500 (viscosity av…
In spherical photo-tubes with interchangeable emitters, energy distributions of external photoelectrons from the semiconductors, Te, Ge, and B, were compared with those of several metals. Contact potentials were determined from the saturation points of current-voltage characteristics. For the semiconductors, as contra…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDetermination of Tensile Strength of Natural Rubber and GR-STakeru. Higuchi, H. M. Leeper, and D. S. DavisCite this: Anal. Chem. 1948, 20, 11, 1029–1033Publication Date (Print):November 13, 1948Publication History Published online1 May 2002Published inissue 13 November 1948h…
A technique is described for the preparation of `single' crystals of BaTiO3. At room temperature the crystals are complexes of habit appropriate to cubic symmetry, but consisting of multiply-twinned tetragonal components with orientation very sensitive to externally applied pressure or electric fields. Optical and X-r…
Abstract An einem Rechenbeispiel wird gezeigt, wie sich Elektronenlinsen durch eine für Elektronen durchlässige ebene Metallfolie chromatisch korrigieren lassen. Die benachbarten Elektroden influenzieren auf der Folie negative Ladungen, die die langsameren Strahl-elektronen verhältnismäßig stark nach außen drängen und…