Materials Literature
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Decimolar solutions of sodium orthophosphate passivate iron at p H. values above 7.25 in the presence of air. When the solutions are deaerated the phosphate reacts with the iron forming ; potential‐time and polarization curves indicate that this reaction is mainly under cathodic control. It is suggested that oxygen di…
Three forms of zinc orthophosphate:manganese have been found. The α form corresponds in x‐ray diffraction pattern to the published values. The luminescence is green, the peak wavelength being 5540 Å. It is produced when manganese concentrations are below 1 mole per cent, or when higher concentrations are not heated ab…
A chronological arrangement has been made of some developments relating to corrosion, in which references are given to papers and patents that were considered to be among the significant contributions to advancement of understanding of its nature, or control of its manifestations. Excerpts from a few of the earlier pa…
The crystal structure work on the borides of the transition elements is summarized. It is shown that the borides may be classified according to the boron arrangement. The phases are regarded as metal lattices with boron in the interstices. The boron atoms form an increasing number of boron‐boron contacts with increasi…
Conductivity was developed in the surface layer of a lead silicate glass containing 61% lead oxide by certain prescribed hydrogen treatments. The conducting layer was found to be from 50 to 100 a.u. thick. The specific resistance was 800 ohm‐cm., or more, depending on the hydrogen treatment. The ratio of hot‐to‐cold r…
B. W. Langley, B. Lythgoe and N. V. Riggs, J. Chem. Soc., 1951, 2309 DOI: 10.1039/JR9510002309
It is frequently stated that one fabric dries faster than another, usually with reference to house hold conditions of drying on a line. However, the data of this report show that by and large all fabrics dry at the same rate under these conditions (rate being expressed as weight of water evaporating per unit area per…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOn the Interaction between Hexacyanatoferrate(III) Ions and (a) Hexacyanatoferrate(II) or (b) Iron(III) Ions1a,2James A. Ibers and Norman DavidsonCite this: J. Am. Chem. Soc. 1951, 73, 1, 476–478Publication Date (Print):January 1, 1951Publication History Published online1 Ma…
G. W. Brindley, Discuss. Faraday Soc., 1951, 11, 75 DOI: 10.1039/DF9511100075
Pure lead was anodized at various constant potentials in sulfuric acid solutions. At potentials below those for formation, a layer of tetragonal is formed near the lead. is formed as an outer layer. The rate of corrosion of Pb was found to increase with increasing temperature and decreasing acid concentration and is g…
The rollers used in drafting textile fibres are disk-shaped, the lower one made of steel, the upper with a metal centre and a fairly thin elastic cover. The length over which the rollers are in contact, and the pressure distribution over this length, are factors which affect their performance as drafting agents. The p…
The kinetics of oxidation of cobalt is a complex problem since the metal forms two or more oxides and the metal itself has a phase transition from hexagonal to face‐centered cubic at a temperature between 300° and 500°C. The vacuum microbalance method is used to study the effect of time, temperature, pressure, pretrea…
C. Edeleanu and U. R. Evans, Trans. Faraday Soc., 1951, 47, 1121 DOI: 10.1039/TF9514701121
Abstract Molybdänblau liegt weder eine einzige Verbindung noch eine einheitliche Reduktionsstufe zugrunde. Es hängt vom Ausgangsmaterial, dem angewandten Reduktionsmittel und der Dauer der Einwirkung des Reduktionsmittels ab, welche Verbindung gebildet wird. Die einfachen Molybdänblauarten werden in Blauoxyde und Blau…
On montre qu'il convient de distinguer au moins deux espèces de traînages magnétiques : le traînage réversible et le traînage irréversible dont on peut décrire les propriétés de la manière la plus simple, du point de vue formel, en introduisant deux champs magnétiques fictifs de traînage, dépendant du temps et superpo…
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Potential‐pH Diagram of Silver Construction of the Diagram—Its Applications to the Study of the Properties of the Metal, its Compounds, and its Corrosion, Delahay, Paul, Pourbaix, Marcel, Rysselberghe, Pierre Van
On the basis of methods and conventions previously described (1) and using the available thermodynamic and electrochemical data, the potential‐ p H diagram of zinc has been constructed. Derived diagrams showing domains of corrosion, passivity, and passivation in the absence and in the presence of carbon dioxide, bicar…
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L. J. Edwards, Trans. Faraday Soc., 1951, 47, 1191 DOI: 10.1039/TF9514701191