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X-ray photoelectron spectroscopy (XPS) spectra of palladium oxide (PdO) are presented. Clean, ground PdO powder was pressed into In foil and analyzed with a Surface Science Instruments SSX-101 M-Probe ESCA instrument using monochromatized Al Kα x rays. Spectra include a survey scan, the Pd 3d, 3p, 3s, 4s, 4p regions,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCopper(II) 12-Metallacrown-4: Synthesis, Structure, Ligand Variability, and Solution Dynamics in the 12-MC-4 Structural MotifBrian R. Gibney, Dimitris P. Kessissoglou, Jeff W. Kampf, and Vincent L. PecoraroCite this: Inorg. Chem. 1994, 33, 22, 4840–4849Publication Date (Prin…
Two-dimensional symmetric and asymmetric subwavelength binary gratings are investigated. A method for determining the three effective indices of a two-dimensional (2-D) subwavelength grating is presented, as well as a theoretical formalization for the effective index parallel with the normal to the surface. It is show…
X-ray photoelectron spectroscopy (XPS) spectra of elemental palladium (Pd) are presented. The specimen is a polycrystalline foil and was analyzed after chemical cleaning and ion-sputtering to remove surface contamination. The spectra were collected with a Surface Science Instruments SSX-101 M-Probe ESCA instrument usi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation and Reactivity of Oxoiron(IV) PorphyrinsJohn T. Groves, Zeev Gross, and Michael K. SternCite this: Inorg. Chem. 1994, 33, 22, 5065–5072Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published inissue 1 October 1994https://pu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolarization Effects of Fluorine on the Relative Permittivity in PolyimidesG. Hougham, G. Tesoro, A. Viehbeck, and J. D. Chapple-SokolCite this: Macromolecules 1994, 27, 21, 5964–5971Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Publis…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTemplate-Synthesized Polyaniline MicrotubulesRanjani V. Parthasarathy and Charles R. MartinCite this: Chem. Mater. 1994, 6, 10, 1627–1632Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published inissue 1 October 1994https://pubs.acs.org…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure, Chemistry, and Activity of Cu-ZSM-5 Catalysts for the Selective Reduction of NOx in the Presence of OxygenWolfgang Gruenert, Neil W. Hayes, Richard W. Joyner, Efim S. Shpiro, M. R. H. Siddiqui, and Galina N. BaevaCite this: J. Phys. Chem. 1994, 98, 42, 10832–10846…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Free Energy Model for Confined Diblock CopolymersD. G. Walton, G. J. Kellogg, A. M. Mayes, P. Lambooy, and T. P. RussellCite this: Macromolecules 1994, 27, 21, 6225–6228Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published inissue…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA More General Approach to Distinguishing "Homogeneous" from "Heterogeneous" Catalysis: Discovery of Polyoxoanion- and Bu4N+-Stabilized, Isolable and Redissolvable, High-Reactivity Ir.apprx.190-450 Nanocluster CatalystsYin Lin and Richard G. FinkeCite this: Inorg. Chem. 1994…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHighly Enantioselective, Low-Temperature Epoxidation of StyreneMichael Palucki, Paul J. Pospisil, Wei Zhang, and Eric N. JacobsenCite this: J. Am. Chem. Soc. 1994, 116, 20, 9333–9334Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Publish…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of Solvent on the Silanization of Glass with OctadecyltrichlorosilaneMark E. McGovern, Krishna M. R. Kallury, and Michael ThompsonCite this: Langmuir 1994, 10, 10, 3607–3614Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published i…
Both Vickers and Knoop hardness ( H ), measured at two or more loads in the range of 100–2000 g (most commonly 100 and 500 g) for a variety of dense oxide and non‐oxide materials, covering a range of grain sizes ( G ), including single crystals where possible, were shown to generally be consistent with (often more lim…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular or Supramolecular Templating: Defining the Role of Surfactant Chemistry in the Formation of Microporous and Mesoporous Molecular SievesJ. S. Beck, J. C. Vartuli, G. J. Kennedy, C. T. Kresge, W. J. Roth, and S. E. SchrammCite this: Chem. Mater. 1994, 6, 10, 1816–182…
An ab initio variable-cell-shape molecular-dynamics algorithm is used to investigate the stability of three carbon nitrides with composition ${\mathrm{C}}_{3}$${\mathrm{N}}_{4}$. The hexagonal \ensuremath{\beta}-${\mathrm{C}}_{3}$${\mathrm{N}}_{4}$ structure, which has been the subject of earlier investigations, is re…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSonochemical Degradation of Phenol in Dilute Aqueous Solutions: Comparison of the Reaction Rates at 20 and 487 kHzChristian Petrier, Marie-Francoise Lamy, Anne Francony, Abdallah Benahcene, Bernard David, Viviane Renaudin, and Nicolas GondrexonCite this: J. Phys. Chem. 1994,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Concept for the Synthesis of 3-Dimensional Homo- and Bimetallic Oxalate-Bridged Networks [M2(ox)3]n. Structural, Moessbauer, and Magnetic Studies in the Field of Molecular-Based MagnetsSilvio Decurtins, Helmut W. Schmalle, Philippe Schneuwly, Juergen Ensling, and Philipp G…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyelectrolyte-Surfactant Complexes: A New Type of Solid, Mesomorphous MaterialMarkus Antonietti, Juergen Conrad, and Andreas ThuenemannCite this: Macromolecules 1994, 27, 21, 6007–6011Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Pub…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTImproved Resolution and Very High Sensitivity in MALDI TOF of Matrix Surfaces Made by Fast EvaporationOle. Vorm, Peter. Roepstorff, and Matthias. MannCite this: Anal. Chem. 1994, 66, 19, 3281–3287Publication Date (Print):October 1, 1994Publication History Published online1 M…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEnzymes and Other Proteins Entrapped in Sol-Gel MaterialsDavid Avnir, Sergei Braun, Ovadia Lev, and Michael OttolenghiCite this: Chem. Mater. 1994, 6, 10, 1605–1614Publication Date (Print):October 1, 1994Publication History Published online1 May 2002Published inissue 1 Octob…