Materials Literature
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The synthesis, structural determinations and magnetic properties of an original dinuclear Cu-Gd and two trinuclear Cu-Ln-Cu complexes (Ln = Gd or Dy) made with a Schiff base ligand and carboxylate ligands are reported. In each complex, the copper and gadolinium or dysprosium ions are linked by a double phenoxo bridge…
The spin crossover complexes [Fe[H(2)B(pz)(2)](2)L]([H(2)B(pz)(2)](-)= dihydrobis(pyrazolyl)borate, L = 2,2[prime or minute]-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for are differ…
Mesoporous silica films were prepared on glass plates by a dip coating method, and the film/plate samples were used as a support for Au, Pt and Pd nanoparticles. By H2- or photo-reduction of metal precursors impregnated on the films, metal nanoparticles are formed with an ordered array structure in the mesopores. The…
Poly(acrylonitrile) (PAN) solutions in dimethylformamide (DMF) were electrospun into webs consisting of 300 nm ultrafine fibers. High-surface area carbon nanofiber webs were prepared by oxidatively stabilized electrospun PAN fibers, followed by activation at 800°C with steam for different times. The specific surface a…
Ferromagnetic shape memory alloys (FSMAs) such as NiMnGa are expected to be new practical actuator materials with high driving frequency by magnetic field and large strain due to the shape memory effect (SME). However, the brittleness and poor workability of FSMAs, especially at a polycrystalline state, are serious pr…
The amphiphilic octaacids rccc-4,6,10,12,16,18,22,24-octakis-O-(carboxymethyl)-2,8,14,20-tetra(n-undecyl)resorc[4]arene (1) and 5,11,17,23,29,35,41,47-octakis(1,1,3,3-tetramethylbutyl)-49,50,51,52,53,54,55,56-octa(carboxymethoxy)calix[8]arene (2) form stable monolayers at the air–water interface which induce growth of…
Microemulsion methods have been used to prepare a wide range of spinel ferrite nanoparticles with low size distribution. Synthesis conditions are summarised for both normal micelle (o/w) and reverse micelle (w/o) synthesis procedures with examples over a variety of ferrite nanoparticles (MFe2O4; M = Co, Fe, Mg, Mn, Cr…
Donor-acceptor nanoensembles, prepared via electrostatic interactions of single wall carbon nanotubes and porphyrin salts, give rise to photoinduced intra-complex charge separation that lasts tens of microseconds.
The historical investigations on the physicochemical and transport properties of lanthanum chromite‐based perovskite oxides are reviewed to evaluate the compatibility as interconnects in solid oxide fuel cells. These materials improve sinterability in air. This has led to investigations on other physicochemical proper…
The oxygen ionic conductivity of apatite-type and increases with increasing oxygen content. The ion transference numbers, determined by faradaic efficiency measurements at 973-1223 K in air, are close to unity for and and vary in the range 0.96-0.99 for other compositions. Doping of with iron results in an increasing…
The solvent-dependent aggregation properties of a water-soluble cationic poly(fluorene) were studied and used to control fluorescence resonance energy transfer to Texas Red-labeled DNA.
Fine powders of propylammonium-exchanged Na2Ti3O7 were successfully converted to transparent thin films by swelling (and exfoliating) the material in water and subsequent casting and drying the obtained titanate sol on a substrate. The dispersion of the material was promoted by sonication and hydrothermal treatment of…
The synthesis and characterization of new spin-crossover pyrazolato bridged dinuclear [(FeII(NCS)(py))2(mu-bpypz)2] and the corresponding cyanotrihydroborato-kappaN complexes are described together with the X-ray crystal analysis of the latter in both the high-spin and low-spin states as well as the variable temperatu…
The methacrylate ligands of the cluster Zr6O4(OH)4(methacrylate)12 undergo degenerate exchange with methacrylic acid in solution. Addition of propionic or isobutyric acid allows partial or complete exchange of the methacrylate ligands for propionate or isobutyrate. The mixed-carboxylate cluster Zr6O4(OH)4(OMc)8(isobut…
Various engineered domain configurations were induced into barium titanate (BaTiO3) single crystals, and their piezoelectric properties were investigated as a function of (1) the crystal structure, (2) the crystallographic orientation and (3) the domain size. As a result, the orthorhombic mm2 BaTiO3 crystals showed th…
Layered double hydroxides (LDHs) with different kinds of metal ions (Mg–Al, Co–Fe, Ni–Fe, and Mg–Fe) in the brucite layers were prepared and their anion exchange properties were studied by measurements of distribution coefficient (Kd) and ion exchange capacity. The basal spacing of LDHs varied depending on the kind of…
Colloidal Au nanoparticles have been functionalized with mercaptopropane sulfonate (MPS) and mercaptoethylamine (MEA) short alkanethiols in aqueous solutions. Adsorption kinetics of these charged thiols onto gold nanoparticles has been followed by the decrease in the surface plasmon band at 530 nm due to the red shift…
A series of M(II) complexes with the ligand 3,5-pyrazoledicarboxylic acid (H3dcp) has been synthesised mainly via hydrothermal reactions and their structures have been characterised. Simple mononuclear [Ni(Hdcp)(H2O)4] (1), Na2(mu-H2O)2(H2O)8[Ni(Hdcp)2(H2O)2] (2), [M(H2dcp)2(H2O)2] x 2H2O [M = Co (3), Zn (4) and Cu (5…
(LNF) is one of the promising cathode materials for intermediate-temperature solid oxide fuel cells (SOFCs). However, LNF is more reactive with -based electrolyte than conventional in the sintering temperature region. In this paper, we examine the relationships among LNF sintering characteristics, reactivity, and cell…
A heterometallic complex, Na(2)[Co(II)(2)Co(III)(2)(IDC(3-))(4)(bipy)(4)].12H(2)O (bipy = 2,2'-bipyridine), in which mixed-valence tetranuclear squares with imidazoledicarboxylate (IDC(3-)) linkers are tethered into a unique chain through disodium units, is hydrothermally synthesized and structurally and magnetically…