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The Photoreduction of Viologen Dyes with Palladium meso-Tetraphenylporphyrintrisulfonate

Ichiro Okura、Shigetoshi Aono、Makoto Takeuchi 等 4 位作者1982-11-01Bulletin of the Chemical Society of Japan

Abstract Pd–TPPS3 was found to be an effective photosensitizer for the photoreduction of viologen dyes, such as methyl, ethyl, propyl, butyl, and heptyl viologens. The order of the reduction rate was as follows: Ethyl>Butyl>Methyl>Propyl>Heptyl. The respective complex formation was observed…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesOxidative Organic Chemistry Reactions

Mineralogy and Iron Characterization of Plinthitic Soils on Alluvial Landforms in Venezuela

L. A. Daugherty、R. W. Arnold1982-11-01Soil Science Society of America Journal

Abstract The iron oxides and clay mineralogy were characterized for several soils of Venezuela which contain plinthite and pseudo‐plinthite. Molar ratios of SiO 2 /Al 2 O 3 (Ki ratios) of the plinthite and pseudo‐plinthite zones range from below 2 to above 4 suggesting a wide range in mineral composition. Cation excha…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Magnetic properties of Gd(FeyAl1-y)3and (GdxY1-x)Fe3compounds

E. Burzo、D. Seitabla1982-11-01Journal of Physics F Metal Physics

Reports the results of magnetic measurements performed on Gd(Fe y Al 1-y ) 3 and (Gd x Y 1-x )Fe 3 compounds over the temperature range 4.2-1300K. For x and y>or=0.2 the compounds are ferrimagnetically ordered. In this case, the reciprocal susceptibility chi -1 follows a Neel-type hyperbolic law. The YFe 3 compound is…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Concerning the discommensurate character of NbSe3

J. A. Wilson1982-11-01Journal of Physics F Metal Physics

Recent data have been used to develop the strongly discommensurate model for NbSe 3 that was introduced in 1978/9. The tightly defined q vectors found for both CDWS are accounted for by a plausible internal structure for the discommensurations. These, because of their relatively weak impurity pinning, seem to form a v…

2D Materials and ApplicationsOrganic and Molecular Conductors ResearchIron-based superconductors research

Temperature dependence of the configurational entropy of undercooled melts and the nature of glass transition

Andrey Milchev、Iwan Gutzow1982-11-01Journal of Macromolecular Science Part B

The configurational entropy as well as other related thermodynamic properties of a (poly)disperse glass-forming polymer melt have been calculated exactly in terms of a lattice-hole model and within the framework of the mean field approximation (MFA). One of the main results of the calculation, in which the average “st…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesRheology and Fluid Dynamics Studies

Response curves for the thermoluminescence induced by alpha particles: interpretation using track structure theory

Y.S. Horowitz、M. Moscovitch、A. Dubi1982-11-01Physics in Medicine and Biology

A three dimensional model is developed to describe the linear-sublinear behaviour of the thermoluminescence (TL) dose response curve induced by heavy charged particles specifically 'low energy' ( approximately 1 MeV u -1 ) alpha particles. Supralinearity induced by alpha particles is shown to be suppressed or non-exis…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesAdvanced Semiconductor Detectors and Materials

Ground State of a Wigner Crystal in a Magnetic Field I. Cubic Structure

Tatsuzo Nagai、Hidetoshi Fukuyama1982-11-01Journal of the Physical Society of Japan

The ground-state energies in magnetic fields are calculated for the electron crystals with the bcc and fcc structures at low electronic densities. The energies are obtained as sums of the static energy and the zero-point vibration energy in the harmonic approximation. The zero-point energy of the fcc becomes lower tha…

Chemical and Physical Properties of Materials

Universal law for the rotational viscosity of nematic liquid crystals

Hp. Schad、H. R. Zeller1982-11-01Physical Review A

The rotational viscosity ${\ensuremath{\gamma}}_{1}(T)$ of a nematic is of dominant importance for wide operating temperature display applications. In this paper we show that ${\ensuremath{\gamma}}_{1}(T)$ is, except for a small prefactor variation, a universal function of $T\ensuremath{-}{T}_{g}$ where ${T}_{g}$ is t…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesNonlinear Dynamics and Pattern Formation

Deuterium quadrupole coupling in methanol, salicyclic acid, catechol, resorcinol, and hydroquinone

J. W. Clymer、J. L. Ragle1982-11-01The Journal of Chemical Physics

Deuteron NQR spectra of several model systems involving alcoholic of phenolic-OD groups are discussed. The spectra of alpha hydroquinone and its two isomers resorcinol and catechol show complex structure due to the presence of inequivalent O–D⋅⋅⋅O hydrogen bonds. In the case of hydroquinone, this structure collapses t…

Crystallography and molecular interactionsAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Magnetic domains in rare-earth cobalt permanent magnets

G. C. Hadjipanayis、R. C. Hazelton、K. R. Lawless 等 4 位作者1982-11-01IEEE Transactions on Magnetics

The microstructure of two commercial 2:17 precipitation hardened rare-earth magnets has been examined and compared with the magnetic properties. Transmission electron microscope studies on Sm(Co,Fe,Cu,Hf)7.25, Hicorex 99C show a fine cellular microstructure with 2:17 rhombohedral cells surrounded by coherent 1:5 hexag…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsMagnetic Properties of Alloys

Effect of Jahn-Teller distortion on the lattice vibration frequencies of nickel ferrite

C. M. Srivastava、T. T. Srinivasan1982-11-01Journal of Applied Physics

The infrared spectra of Ni1−xCuxFe2O4 (x=0, 0.1, 0.2) studied at room temperature in the range of 250–800 cm−1 show two main bands. On adding copper to nickel ferrite, the center frequency of these two bands is found to shift to lower energies. The force constants obtained using the center frequency have been observed…

Magnetic Properties and ApplicationsSemiconductor materials and interfacesMagneto-Optical Properties and Applications

High-field magnetization curves of amorphous alloys

O. Kohmoto1982-11-01Journal of Applied Physics

Effects of Si addition into amorphous (Fe0.064Co0.936)76.5 -B23.5 alloy having zero magnetostriction were investigated by the measurement of high-field magnetization at room temperature in the field range 150≤H≤13 000 Oe. The FeCo-B alloy shows anomalies in both the law of approach to saturation and the para process.…

Microstructure and Mechanical Properties of SteelsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Slow decomposition of silicone rubber

Petr Vondráček、A. N. Gent1982-11-01Journal of Applied Polymer Science

Abstract The sol content of previously extracted samples of lightly crosslinked silicone rubber has been found to increase during prolonged storage under relatively mild conditions. Simultaneously, the tensile stress slowly decreases in samples held stretched, and the equilibrium degree of swelling increases somewhat.…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaSilicone and Siloxane Chemistry

A lattice model of liquid crystals with matrix order parameter

N Angelescu、Valentin A. Zagrebnov1982-11-01Journal of Physics A Mathematical and General

A lattice model with full rotational invariance is proposed for describing nematic liquid crystals. Orientational long-range order at low temperature is proved using the infrared bound method.

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationOptical Polarization and Ellipsometry

Method for the measurement of rotational power loss and related properties in electrical steel sheets;

W. Brix、K. A. Hempel、Werner Schroeder1982-11-01IEEE Transactions on Magnetics

An apparatus is described which is used to measure the magnetic field vectors in electrical steel sheets in rotating magnetic fields. To avoid complicated eddy current effects we produce a rotating B-vector with constant modulus and angular velocity. Considerable variations of the modulus of the magnetic field strengt…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesElectromagnetic Effects on Materials

Magnetic shielding to multi-gigawatt magnetic switches ten years of amorphous magnetic applications

C. Smith1982-11-01IEEE Transactions on Magnetics

The applications of ferromagnetic amorphous alloys provide an excellent example of the unpredictable nature of the benefits from research and from the development of a technology. This paper traces a brief history of applications of amorphous alloys as soft magnetic materials. Specific applications are then discussed…

Metallic Glasses and Amorphous AlloysMagnetic Properties and ApplicationsMagneto-Optical Properties and Applications

Vibrational spectra and analyses of the S42+, Se42+, Te42+, and trans-Te2Se22+ polyatomic cations

Robert C. Burns、R. J. Gillespie1982-11-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVibrational spectra and analyses of the S42+, Se42+, Te42+, and trans-Te2Se22+ polyatomic cationsRobert C. Burns and Ronald J. GillespieCite this: Inorg. Chem. 1982, 21, 11, 3877–3886Publication Date (Print):November 1, 1982Publication History Published online1 May 2002Publi…

Crystal Structures and PropertiesPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Residual Value of Lime and Leaching of Calcium in a Kaolinitic Ultisol in the High Rainfall Tropics

D. K. Friesen、A. S. R. Juo、M. H. Miller1982-11-01Soil Science Society of America Journal

Abstract A long‐term experiment was conducted on a highly acidic (pH 4.6), coarse‐textured Ultisol (Typic Paleudult; loamy, siliceous, isohyperthermic) in the high rainfall region of southeastern Nigeria in order to evaluate the requirement for and residual value of lime [Ca(OH) 2 ] to a continuous crop rotation, and…

Soil Carbon and Nitrogen DynamicsSoil Geostatistics and MappingClay minerals and soil interactions

A Comparative Rheological Investigation of Natural and Synthetic Cis-1,4 Polyisoprenes and Their Carbon Black Compounds

Sergio Montes、James L. White1982-11-01Rubber Chemistry and Technology

Abstract A comparative experimental study of the rheological properties of four cis -1,4 polyisoprenes, two naturally occurring and two synthetic, is reported. The two naturally occurring elastomers are from the hevea tree and guayule bush, and the synthetics are produced by alkyl lithium and Ziegler catalysts. Transi…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Thermal reactivity of poly(styrene peroxide): a thermodynamic approach

K. Kishore、K. Ravindran1982-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal reactivity of poly(styrene peroxide): a thermodynamic approachK. Kishore and K. RavindranCite this: Macromolecules 1982, 15, 6, 1638–1639Publication Date (Print):November 1, 1982Publication History Published online1 May 2002Published inissue 1 November 1982https://pu…

Polymer crystallization and propertiesThermal and Kinetic AnalysisPolymer Science and PVC