Materials Literature
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欠陥型ホタル石構造を基本としたC型希土類酸化物のYb2O3とEr2O3の単結晶をアークイメージフローティングゾーン法により作製し, 四軸型単結晶X線回折計を用い, 室温から1260Kまで6点の温度での高温構造の解析を行った. 最終のR因子はYb2O3で0.034から0.050, Er2O3で0.036から0.051であった. 単位胞の平均線熱膨張係数はYb2O3で8.27×10-6K-1 (室温から850K) 及び10.31×10-6K-1 (850Kから1250K), Er2O3で7.47×10-6K-1 (室温から770K) 及び10.74×10-6K-1 (770Kから1250K) である. 欠陥型ホタル石構造における酸素の…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHomogeneous catalysis of the photoreduction of water by visible light. 4. Cobalt(I) polypyridine complexes. Redox and substitutional kinetics and thermodynamics in the aqueous 2,2'-bipyridine and 4,4'-dimethyl-2,2'-bipyridine series studied by the pulse-radiolysis techniqueH…
Chemical, X-ray, electron optical, and infrared analyses have been made on twenty antigorites form the Nishisonogi and Sasaguri areas, northern Kyushu, Japan, along with two antigorites from other localities. The indexed X-ray powder patterns give various supercell A parameters (A = 35.4–47.2Å) as well as varying subc…
Abstract The photo and thermal oxidation of various epoxide–amine tridimensional polycondensates is studied by IR spectrophotometry and DSC. The network degradation results in a decrease of the glass transition temperature ( T g ), which is correlated with the quantity of amide groups formed. For each system, the rela…
Abstract Plasma polymerization of tetra fluoroethylene (TFE), perfluoro‐2‐butyl‐tetrahydrofuran (PFBTHF), ethylene, and styrene were investigated in various combinations of monomer flow rates and discharge wattages for the substrate temperature range of −50 to 80°C. The polymer deposition rates can be generally expres…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymerized-depolymerized vesicles. Reversible thiol-disulfide-based phosphatidylcholine membranesN. K. P. Samuel, Maninder Singh, Kazuo Yamaguchi, and Steven L. RegenCite this: J. Am. Chem. Soc. 1985, 107, 1, 42–47Publication Date (Print):January 1, 1985Publication History…
It is shown that the multi-peaked cyclic voltammograms for silicon phthalocyanine monomer-oligomer sets may be predicted from initial state molecular orbital energy levels if field shifts are used to allow for the charges of the anions and cations. The theory should have broad application for the understanding of the…
The paper first reviews briefly the various kinds of information that can be obtained from x-ray diffraction studies. Next, specific examples are given from the literature of determinations of each of the different kinds of data.
When related to a phase-change problem, an implicit finite-difference discretization of the enthalpy formulation results in a system of non-linear equations at each time step. In this paper, various numerical enthalpy methods based on such discretizations are outlined and examined. An alternative discretization for an…
The Metropolis algorithm has been generalized to allow for the variation of shape and size of the MC cell. A calculation using different potentials illustrates how the generalized method can be used for the study of crystal structure transformations. A restricted MC integration in the nine dimensional space of the cel…
Although benzotriazole and tolyltriazole are well known as extremely effective inhibitors of copper corrosion, very little has been reported in the literature regarding their chemistry, particularly in near neutral, low conductivity aqueous media. The behavior of these inhibitors was studied under typical cooling wate…
Progress of Theoretical Physics Vol. 76 No. 4 (1986) pp. 865-878 ΛN Exchange-Force Effects on the Binding Energies of 5ΛHe, 9ΛBe, 6ΛΛHe and 10ΛΛBe Hypernuclei Wang Xi-cang, Hideo Takaki and Hiroharu Bandō Progress of Theoretical Physics Vol. 78 No. 6 (1987) pp. 1317-1329 Structure of 20ΛNe Hypernucleus Toshimi Sakuda…
A series of polytungstate anions [XW12O40]n–(X = P, Si, Fe, Co, or H2; n= 3,4,5,6, and 6 respectively), spanning a range of reduction potentials, have been studied as sensitizers for the photoreduction of water and O2. [SiW12O40]4– was the most efficient sensitizer for H2 evolution in the presence of colloidal platinu…
Water sorption values for direct filling resins and an unfilled resin were much more similar at 30 days when expressed as mg/g organic matrix than as mg/cm2 or weight percent. This interpretation is indicative of the water sorption characteristics of resin matrices. The values are even more indicative when solubility…
DTA-TG study on several aragonites was carried out to clarify the transformation of aragonite to calcite through heating process. Aragonite formed in biological system started and completed the transformation at temperatures lower than did aragonite formed in inorganic systems. The DTA-TG study showed that weight loss…
Ti–Ni specimens of the equiatomic composition have been processed by conventional powder metallurgy techniques. The effects of compaction pressure, sintering temperature, and powder particle size on dimensional changes of sintered compacts are reported. During sintering, anisotropy of dimensional change occurs, with e…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotocatalytic generation of hydrogen by 1:12 heteropolytungstates with concomitant oxidation of organic compoundsA. Ioannidis and E. PapaconstantinouCite this: Inorg. Chem. 1985, 24, 3, 439–441Publication Date (Print):January 1, 1985Publication History Published online1 May…
Abstract
The crystal structures of cellulose polymorphs IV I and IV II have been determined by X-ray fiber diffraction analysis combined with stereochemical model refinement. Both structures crystallize in a two-chain unit cell of essentially identical parameters. The most probable space group in both cases is P1. The chain co…
The low resistivity of copper salts of TCNQ and the associated broad e.s.r. signals suggest that the characteristic narrow-band structure of the TCNQ columns may be modified by electronic coupling to metal d bands. Crystalline AgTCNQ and CuTCNQ have been synthesised electrochemically. The crystal structure of AgTCNQ r…