Materials Literature
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TbIII chelates containing aromatic moieties show sonoluminescence in aqueous solutions during the sonolysis of water. The observed 5D4→7FJ transitions of TbIII are due to the excitation of ligand, followed by an intramolecular energy transfer from the ligand to the central ion, which finally emits. No sonoluminescence…
Abstract Results concerning the catalytic activity of catalysts prepared by Equilibrium Deposition Filtration (EDF) and corresponding catalysts prepared by conventional impregnation techniques are reported. These results show that the EDF and co‐EDF methodologies may be used for preparing very active catalysts even wi…
The photodegradation of alkannin/shikonin (A/S) was studied as a function of solvent polarity, pH and ionic strength. This process follows an apparent first-order kinetic reaction. The photodegradation rate is inversely proportional to the solvent polarity in the order of chloroform > dichloromethane > 2-propanol > et…
A series of tests was run to characterize the through-the-thickness tensile strength of a variety of composites that included two-dimensional (2D) braids, 2D and three-dimensional (3D) weaves, and prepreg tapes. A new test method based on a curved beam was evaluated. The through-the-thickness deformations were charact…
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A number of new poly(organophosphazenes) have been synthesized which bear 2-butenoxy or (4-(allyloxy)phenyl)phenoxy side groups. Cosubstituent groups included trifluoroethoxy, phenoxy, or (benzyloxy)phenoxy groups. Species with (4-(allyloxy)phenyl)phenoxy units underwent Si−H coupling with linear silanes or siloxanes…
We studied the mechanism behind the double-zincate process, used for pretreating aluminum alloy, through SEM observation, electrode potential tracing, and weight changes determined during each zincate process. Zinc particles grew during the first zincate process, with a thin, uniform Zn layer forming during the second…
Very sharp deformation textures, with single maxima of more than 50x random centred on the rotated cube component ({001}<110>), were produced by submitting a non‐oriented electrical steel sheet to various sequences of cross‐rolling. The cold rolled sheets were subsequently annealed at 730 º C for 3 min. The resu…
In the ZrO 2 ‐Cr 2 O 3 system, metastable t ‐ZrO 2 solid solutions containing up to 11 mol% Cr 2 O 3 crystallize at low temperatures from amorphous materials prepared by the hydrazine method. The lattice parameter c decreases linearly from 0.5149 to 0.5077 nm with increased Cr 2 O 3 content, whereas the lattice parame…
The potential for using subsize specimens to determine the actual properties of reactor pressure vessel steels is receiving increasing attention for improved vessel condition monitoring that could be beneficial for light-water reactor plant-life extension. This potential is made conditional upon, on the one hand, by t…
Studies on Ln[Co(CN)(6)].nH(2)O (Ln = lanthanoid ions; n = 5, 4) by means of thermal analysis, Raman spectroscopy, and X-ray crystallography were carried out, in order to establish the boundary structures in the series. From the thermal analyses, it was confirmed that the complexes include Ln'[Co(CN)(6)].5H(2)O (Ln' =…
The donor-acceptor compounds N,N'-dicyanobenzo[b]naphtho[2,3-e][1,4]dithiin-6,11-quinonediimine (9a) and N,N'-dicyanobenzo[b]naphtho[2,3-e][1,4]oxathiin-6,11-quinonediimine (10a) and their methyl-substituted derivatives (9b and 10b-d, respectively) have been prepared, and their structural and electronic properties hav…
Solids mixing refers to the blending of particulate components differing in one of their properties. To compare mix and mixer theoretical standard deviation σ is defined as the mixing quality. To simulate the stochastic mixing process the Fokker-Planck-Equation is used. Similar simulations described in the literature…
The anticoagulant activity of albumin-heparin conjugates covalently immobilized on carboxylated polystyrene beads was determined before and after exposure to different plasma/PBS dilutions using a thrombin inhibition assay, a FXa inhibition assay, and a modified aPTT assay. Exposure of albumin-heparin modified surface…
A stepwise synthesis of the opp-dibenzoporphyrin (dibenzo[g,q]porphyrin) system involving isoindole precursors is described. 3-Halogeno-1-formylisoindoles are condensed with various α-unsubstituted pyrroles to give the corresponding benzopyrromethene hydrobromides. Thermal self-condensation of such compounds bearing a…
CdS nanocrystallites prepared by capping with pentafluorothiophenol, 2,3,5,6-tetrafluorothiophenol or 4-fluorothiophenol are characterized as quantum dots by TEM, FTIR, NMR, UV–VIS and fluorescence spectroscopy. The crystalline size tends to increase with an increase in the number of fluorine atoms in the capping mole…
Unsteady conjugate mass transfer between a spherical bubble, droplet, or particle and a surrounding fluid flow with chemical reaction in the continuous phase has been analyzed. An algorithm based on spectral methods has been developed and implemented for the simulation of the interphase mass transfer. The influence of…
This investigation established the effects of bulk immiscibility on the bulk and surface structure of FePd catalyst particles supported on graphite. By use of Mössbauer effect spectroscopy, X-ray diffraction and gas-adsorption microcalorimetry, it was shown that iron-rich FePd/Grafoil catalyst particles consist of the…
Numerous methods have been used to illustrate and simulate complex spin-echo phenomena for noninteracting spins. Our approach is to reconstruct the time domain signal by what amounts to a finite Fourier series, the terms of which correspond to spin isochromats. The coefficients of the series evolve in response to puls…
Lithium hydride (LiH) has been shown to react with water at a rate defined by a nonequilibrium thermodynamic-based model. The rate at any time is proportional to the surface area of the LiH multiplied by the difference in chemical activity of the reaction product, lithium hydroxide (LiOH), between the solid phase and…