Materials Literature
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The objective of this study was to investigate the effect of alkali treatment on properties of shellac. The native shellac was treated with sodium hydroxide for 15, 30, and 60 min to obtain hydrolyzed shellac. All types of shellac, namely native and hydrolyzed shellac at various times of treatment, were then prepared…
A simple wide-view circular polarizer comprising of a linear polarizer and two biaxial films is proposed. Over the +/-85o viewing cone, the produced polarization is almost circular and the light leakage from the crossed circular polarizers is calculated to be less than 8.23x10(-5), provided that the air-interface surf…
A novel two-dimensional cyanide-bridged polymer [CuII(tren)]{CuI[W(V)(CN)8]} . 1.5H2O (tren = tris(2-aminoethyl)amine) formed via the simultaneous in situ metal-ligand redox reaction of [Cu(tren)(OH2)]2+ and self-assembly with [W(V)(CN)8]3- consists of a {CuI[W(V)(CN)8]} square grid built of CuI centres of tetrahedral…
Driven by shrinking feature sizes, microprocessor “hot-spots” — with their associated high heat flux and sharp temperature gradients — have emerged as the primary “driver” for on-chip thermal management of today’s IC technology. Solid state thermoelectric micro-coolers offer great promise for reducing the severity of…
We have incorporated the photochromic dyes spiropyran and spirooxazine in surfactant templated mesostructured silica particles. Spherical inorganic–organic hybrid pigments with varying dye content were produced by a one-pot synthesis in an aerosol reactor where the internal mesostructure could be controlled. The mesos…
Mesoporous titania nanocrystals containing iron tetrasulfophthalocyanine (FePcS) have been synthesised by a one-pot hydrolytic process from a modified Ti alkoxide; the novel hybrid catalyst was efficient in heterogeneous oxidation of 2,3,6-trimethylphenol and β-isophorone suggesting a cooperative effect between TiO2 a…
The basic optical properties and optical constants of the ionomer thin film have been investigated by means of transmittance and reflectance spectra. The real (n) and imaginary (k) parts of the complex refractive index and dielectric constant of the thin film were determined. The oscillator energy Eo, dispersion energ…
Reaction of Mn(ClO4)2.6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.
In contrast to the photosensitization with a non-methylated analogue, supramolecular photochirogenesis with a novel permethylated mono(6-O-benzoyl)-beta-cyclodextrin exhibited a critical dependence of the product's enantiomeric excess upon temperature, and possessed a large differential entropy of activation (-11 J K(…
Article Stabilisation of Paper Containing Iron-Gall Ink with Current Aqueous Processes was published on September 1, 2005 in the journal Restaurator. International Journal for the Preservation of Library and Archival Material (volume 26, issue 3).
We investigated poly(L-lactic acid) (PLLA) fibers and coils, simulating stents and the influence of impregnation with curcumin, a non-steroidal anti-inflammatory drug, intended to reduce the pro-inflammatory property of these implants. Fibers obtained by melt extrusion of 137 kDa PLLA resin containing 10% curcumin (C-…
Titanium dioxide open-cell macro-cellular foams have been generated with emphasis toward controlling macro-, meso- and microstructures thus reaching hierarchically organized inorganic architectures. At the macroscopic length scale a non-static air–liquid foam strategy allows strong control over the open-cell morpholog…
A high spin molecular square of square pyramidal Co(II) and tetrahedral Mn(II) corners exhibiting an overall S= 4 ground state has been crystallized and its magnetic properties investigated.
Enhancement of fluorescence of CdS nanoparticles by tyrosine at pH 10 in contrast to Stern-Volmer quenching at pH 7 was observed and both the effects were found to depend on the size of the nanoparticles.
We describe application of a novel refinement method for an accurate determination of the chemical diffusion coefficient, D , and the generalized kinetic parameter, Λ, from experimental potentiostatic intermittent titration technique (PITT) data suited for a variety of electrochemically doped electroactive polymers an…
In this paper, we apply the Double Negative Material in some basic applications, including waveguide, rectangular patch antenna and disc patch antenna. By analyzing theoretically we find that the sizes of these equipments can be greatly reduced by using multi-block (which may include both double positive and double ne…
Abstract First and second‐generation rigid dendrimers based on polyphenylated tetrahedral adamantane cores with four or sixteen peripheral phosphonate moieties, PD1 and PD2, respectively, were synthesized and characterized. Further reaction of the dendritic phosphonates with tungstic acid in the presence of hydrogen p…
Four tetracatenar (L1–L4) and one hexacatenar (L5) ligands, derived from the diaza-18-crown-6 framework, are synthesized and characterized. In these ligands, the amine functions are fitted with benzoyloxybenzyl linker groups, attached either with a carbonyl function (L1) or a methylene bridge (L2–L5) and bearing alkox…
Fleshing wastes from tanneries create major environmental problems. Despite their considerable fat content, these wastes do not find important usage. Their disposal is also troublesome and costly. We have investigated the possible use of this fat in the production of biodiesel (fatty acid methyl esters) by transesteri…
ABSTRACT Starch acetate nanocomposite foams with four organoclays (Cloisite 30B, 10A, 25A, and 20A) were prepared by melt‐intercalation methods. The structural properties, thermal behaviors, and mechanical properties were characterized by X‐ray diffraction (XRD), scanning electron microscopy (SEM), differential scanni…