Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSiloxane Coupling AgentsLeanne G. Britcher, David C. Kehoe, Janis G. Matisons, and A. Geoffrey SwincerCite this: Macromolecules 1995, 28, 9, 3110–3118Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https://pub…
Abstract This work investigates unit cell dimensions, crystal size and specific surface area of aluminous goethite that was progressively dehydroxylated to form hematite. Goethite synthesized from the ferrous system altered to hematite with DTGA maximum increasing from 236° to 273°C for 0 to 30.1 mole % Al-substitutio…
Salt layers play an important role in many electrochemical dissolution processes. The composition of salt films formed on austenitic stainless steel have, for the first time, been determined using in situ energy dispersive x‐ray fluorescence microanalysis during dissolution in a chloride solution. The electrode was th…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReversible Thermal Gelation in Polymer/Surfactant Systems. Control of the Gelation TemperatureK. Loyen, I. Iliopoulos, R. Audebert, and U. OlssonCite this: Langmuir 1995, 11, 4, 1053–1056Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Publ…
Magnetoliposomes for hyperthermia treatment of cancer were prepared by coating phospholipid on to magnetite particles. The optimum phospholipid composition for dispersibility was a phosphatidylcholine/phosphatidylethanolamine ratio of 2:1. The average size of the magnetoliposomes, which were aggregates of 10 nm core m…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIsomerization of n-Pentane and Other Light Hydrocarbons on Hybrid Catalyst. Effect of Hydrogen SpilloverAihua Zhang, Ikusei Nakamura, Kohjiroh Aimoto, and Kaoru FujimotoCite this: Ind. Eng. Chem. Res. 1995, 34, 4, 1074–1080Publication Date (Print):April 1, 1995Publication Hi…
In certain cases, lyotropic lamellar phases under shear form structures corresponding to a close-packed assembly of multilayered vehicles. We present light and neutron scattering data showing that these micrometer-sized objects may exhibit a long-range order under shear similar to that which has been observed for rigi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Density Functional Study of Ethylene Insertion into the M-CH3 Bond of the Constrained Geometry Catalysts [(SiH2-C5H4-NH)MCH3]+ (M = Ti, Zr, Hf) and (SiH2-C5H4-NH)TiCH3Liangyou Fan, Daryll Harrison, Tom K. Woo, and Tom ZieglerCite this: Organometallics 1995, 14, 4, 2018–202…
The attachment of bacteria to solid surfaces is influenced by substratum chemistry, but to determine the mechanistic basis of this relationship, homogeneous, well-defined substrata are required. Self-assembled monolayers (SAMs) were constructed from alkanethiols to produce a range of substrata with different exposed f…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Model for Antiplasticization in PolystyreneS. L. Anderson, E. A. Grulke, P. T. DeLassus, P. B. Smith, C. W. Kocher, and B. G. LandesCite this: Macromolecules 1995, 28, 8, 2944–2954Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRadical Carbonylation of Alkanes via Polyoxotungstate PhotocatalysisB. Scott Jaynes and Craig L. HillCite this: J. Am. Chem. Soc. 1995, 117, 16, 4704–4705Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https:/…
The design and fabrication of large-area, high-efficiency metallic gratings for use in high-power laser systems is described. The gratings exhibit a diffraction efficiency in excess of 95% in the m = -1 order (Littrow mount) and have a high threshold for laser damage. Computations and experimental measurements are pre…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolysilane DendrimersAkira Sekiguchi, Masato Nanjo, Chizuko Kabuto, and Hideki SakuraiCite this: J. Am. Chem. Soc. 1995, 117, 14, 4195–4196Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https://doi.org/10.102…
Li is intercalated into (XRG) films up to a stoichiometry of . The spin‐coated films are highly reversible hosts for Li and do not support cointercalation of solvent molecules. The specific energy , and specific capacity are higher than any reported previously for xerogel materials or for other vanadium oxides. It is…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTWater-Soluble Poly(aniline-co-o-anthranilic acid) CopolymersMy T. Nguyen and Arthur F. DiazCite this: Macromolecules 1995, 28, 9, 3411–3415Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https://pubs.acs.org/d…
We investigate by Monte Carlo simulations the diffusion of ions in ordered and structurally disordered lattices, where the Coulomb interaction between the mobile ions is explicitly taken into account. Results for tracer diffusion, conductivity, the diffusion-induced spin-lattice relaxation rate, and the incoherent int…
Pure coupons of chemically vapor deposited (CVD) SiC were oxidized for 100 h in dry flowing oxygen at 1300°C. The oxidation kinetics were monitored using thermogra‐vimetry (TGA). The experiments were first performed using high‐purity alumina reaction tubes. The experiments were then repeated using fused quartz reactio…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel Blends of Hyperbranched Polyesters and Linear PolymersD. J. Massa, K. A. Shriner, S. R. Turner, and B. I. VoitCite this: Macromolecules 1995, 28, 9, 3214–3220Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1…
The phenomenological derivation of a phase field model of capillarity that accounts for the structure of an interfacial layer formed by two immiscible incompressible liquids is addressed. A rheological expression for the reversible component of capillary stresses is obtained in terms of the free energy of a binary flu…
The temperature behavior of the zone-center soft modes of ${\mathrm{KTaO}}_{3}$ and ${\mathrm{SrTiO}}_{3}$ is remeasured betwen 5 and 300 K by the technique of hyper-Raman spectroscopy, the experimental errors of soft-mode frequency and damping constant being reduced to below \ifmmode\pm\else\textpm\fi{}1 ${\mathrm{cm…