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Tubular mesophases: liquid crystals consisting of macrocyclic molecules

Jean‐Marie Lehn、Jacques Malthête、Anne‐Marie Levelut1985-01-01Journal of the Chemical Society Chemical Communications

The hexa-(p-n-dodecyloxybenzoyl) derivatives (1b), (2b), and (3b) of the macrocyclic polyamines [18]-N6, [24]-N6O2, and [27]-N6O3 display a liquid crystal phase in which the macrocyclic units are stacked, forming a tubular mesophase.

Liquid Crystal Research AdvancementsSupramolecular Chemistry and ComplexesSynthesis and Properties of Aromatic Compounds

Bonding-state characterization of the constitutent elements of silicate minerals by X-ray photoelectron spectroscopy

Haruhiko Seyama、Mitsuyuki Soma1985-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

X-ray photoelectron and X-ray-induced Auger electron spectra of silicate minerals have been measured. The systematic shifts of the photoelectron binding energies of Si, O and tetrahedrally coordinated Al ions in the silicate framework suggest that the negative charge on the framework is delocalized over these ions. On…

Crystal Structures and PropertiesClay minerals and soil interactionsX-ray Diffraction in Crystallography

The genus allium— Part 3

G. R. Fenwick、A. Bryan Hanley、John R. Whitaker1985-01-01C R C Critical Reviews in Food Science and Nutrition

Allium is a genus of some 500 species belonging to the family Liliaceae. However, only a few of these are important as food plants, notably onion, garlic, chive, leek, and rakkyo. Such plants have been used for many centuries for their pungency and flavoring value, for their medicinal properties, and in some parts of…

Diatoms and Algae Research

Soil pH Buffering Revisited

F. R. Magdoff、Richmond J. Bartlett1985-01-01Soil Science Society of America Journal

Abstract The buffering relationships of a wide variety of Vermont soils were investigated by adding either acid (H 2 SO 4 ) or base (CaCO 3 ). Soils were found to be very well buffered above pH 7 and below pH 4. When amendment added is expressed on an organic matter (OM) basis [mmol (H + or 1/2 CaCO 3 ) g −1 OM] and t…

Soil and Water Nutrient DynamicsClay minerals and soil interactionsMine drainage and remediation techniques

Polymorphic Transformation of Some Drugs Under Compression

Hak‐Kim Chan、Éric Doelker1985-01-01Drug Development and Industrial Pharmacy

The existence of various crystalline forms in drugs is a phenomenon frequently encountered (about 40% of the USP XX tablet monographs with dissolution tests are concerned with such compounds). Some studies concerning trituration or grinding of polymorphs have been published; surprisingly little information is availabl…

Crystallization and Solubility Studiesnanoparticles nucleation surface interactionsChemical Thermodynamics and Molecular Structure

Materials for nonlinear optics

Peter Günter1985-01-01Conference on Lasers and Electro-Optics

In this paper we review both photorefractive and nonlinear optical materials for optoelectronic applications. The material requirements for nonlinear optical laser-frequency conversion using the electronic hyperpolarizabilities and optical signal processing using the photorefractive effect will be discussed. Some repr…

Photonic and Optical DevicesNonlinear Optical Materials ResearchPhotorefractive and Nonlinear Optics

Structural studies of calcium aluminosilicate glasses by high resolution solid state 29Si and 27Al magic angle spinning nuclear magnetic resonance

G. Engelhardt、Marianne Nofz、K. Forkel 等 7 位作者1985-01-01Physics and chemistry of glasses

Etude, par spectroscopie RMN de 29 Si et 27 Al dans le systeme CaO-Al 2 O 3 -SiO 2 , d'une serie de 50 verres environ dont les compositions chimiques variaient systematiquement le long de sept lignes selectionnees du diagramme de composition ternaire. Les donnees sont discutees d'apres un modele de structure base sur…

Glass properties and applicationsCultural Heritage Materials AnalysisMineralogy and Gemology Studies

Strength and Fracture Toughness of Isostatically Hot‐Pressed Composites of Al 2 O 3 and Y 2 O 3 ‐Partially‐Stabilized ZrO 2

Koji Tsukuma、Kuniyoshi Ueda、Masahiko Shimada1985-01-01Journal of the American Ceramic Society

Composites of Al 2 O 3 and Y 2 O 3 partially‐stabilized ZrO 2 were isostatically hot‐pressed using submicrometer powders as the starting material. The addition of Al 2 O 3 resulted in a large increase in bending strength. The average bending strength for a composite containing 20 wt% Al 2 O 3 was 2400 MPa, and its fra…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Phasmids : a new class of liquid crystals

Jacques Malthête、A. M. Levelut、Nguyễn Hữu Tình1985-01-01Journal de Physique Lettres

Two hexa-alkoxy derivatives (7a and 7b) of terephthal-bis-[4-benzoyloxyaniline] are described. They exhibit two new types of mesophase for which the term phasmidic is proposed : one has an hexagonal 2D lattice and the second an oblique 2D lattice.

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsSynthesis and properties of polymers

Controls on the Precipitation of Early Diagenetic Calcite, Dolomite and Siderite Concretions in Complex Depositional Sequences

C. D. Curtis、Max Coleman1985-01-01SEPM (Society for Sedimentary Geology) eBooks

abstract Carbonate concretions occur commonly in organic-rich clastic sediments of ancient coastal floodplains and deltas. They consist of calcite, dolomite, or siderite or combinations of these. The influence of marine, mixed or non-marine depositional waters is seen in early cements; solute sources from decompositio…

Innovations in Concrete and Construction MaterialsMining and Gasification TechnologiesStructural mechanics and materials

Some recent advances in the mineralogy and geochemistry of Nb and Ta in rare-element granitic pegmatites

Petr Černý、T. S. Ercit1985-01-01Bulletin de Minéralogie

On a procédé à l'examen des données existantes sur la composition chimique et les propriétés structurales de columbite-tantalite, ferrotapiolite-manganotapiolite, ixiolite, wodginite, rutile tantalifère et niobifère, cassitérite niobo-tantalifère, et du groupe de pyrochlore. La compréhension de la cristallochimie de c…

Geological and Geochemical AnalysisRadioactive element chemistry and processingNuclear materials and radiation effects

Infrared Optical Materials and their Antireflection Coatings

J. A. Savage1985-01-01OpenAlex

Materials transparent to infrared radiation are becoming more and more important with the increasing sophistication and exacting requirements of their diverse applications. Although books have appeared on different aspects of this subject, Dr Savage is the first to collect all the relevant topics in one volume. His wo…

Advanced Fiber Optic SensorsSemiconductor Lasers and Optical DevicesOptical Coatings and Gratings

Scavenging of OH Radicals Produced in the Sonolysis of Water

A. Henglein、Claudius Kormann1985-01-01International Journal of Radiation Biology and Related Studies in Physics Chemistry and Medicine

The yield of hydrogen peroxide in the sonication of argon-saturated water was studied in the presence of various solutes. The efficiency of OH radical scavenging is expressed by the reciprocal value of C 1/2, the solute concentration at which the H2O2 yield is decreased by 50 per cent. C 1/2 ranges over several orders…

Advanced Chemical Sensor TechnologiesUltrasound and Cavitation PhenomenaHydrogen's biological and therapeutic effects

Preparation and in vitro degradation properties of polylactide microcapsules.

Kimiko Makino、Masayuki Arakawa、Tamotsu Kondo1985-01-01Chemical and Pharmaceutical Bulletin

Polylactide (PLA) microcapsules with an average diameter of 1.5μm were prepared by an interfacial deposition technique. The degree of degradation of PLA microcapsules was estimated by determination of the amount of lactic acid as a final product in bulk solution and from the molecular weight distribution of PLA of the…

Hydrogels: synthesis, properties, applicationsbiodegradable polymer synthesis and propertiesAdvanced Drug Delivery Systems

Cloning, sequencing and expression of subtilisin Carlsberg fromBacillus licheniformis

Myra Jacobs、Margareta Eliasson、Mathias Uhlén 等 4 位作者1985-01-01Nucleic Acids Research

The gene encoding subtilisin Carlsberg from Bacillus licheniformis has been isolated by molecular cloning using a mixture of synthetic oligonucleotides. The entire nucleotide sequence of the coding sequence as well as 5' and 3' flanking sequences have been determined. The deduced amino acid sequence reveals an N-termi…

Bacterial Genetics and BiotechnologyAdvanced Proteomics Techniques and ApplicationsEnzyme Structure and Function

Magnetic excitations in crystal-field split 4f systems

Peter Fulde、M. Loewenhaupt1985-01-01Advances In Physics

A survey is given of magnetic excitations in metallic 4f systems when the crystal-field splitting is comparable to or larger than the magnetic interaction between different sites. Particular emphasis is put on the interaction of crystal-field split rare-earth ions with conduction electrons. A number of physical effect…

Magnetism in coordination complexesAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

The Frank constants of some nematic liquid crystals

M. J. Bradshaw、E. P. Raynes、John D. Bunning 等 4 位作者1985-01-01Journal de physique

We present results for the splay and bend constants, K11 and K33, in two homologous series of nematic compounds, the alkyl- and alkoxy-cyanobiphenyls, and in PAA. They have been obtained in two laboratories using different methods, and the extent to which they agree gives confidence that neither set is significantly a…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

Sintering and Mechanical Properties of Stoichiometric Mullite

Shuzo Kanzaki、H. Tabata、Takeshi Kumazawa 等 4 位作者1985-01-01Journal of the American Ceramic Society

Stoichiometric mullite powder (3Al 2 O 3 ·2SiO 2 ) prepared by spray pyrolysis and sintered at 1650°C attained 95% of theoretical density. The flexural strength was 360 MPa at room temperature and decreased slightly at 1400°C. A fairly high K Ic value (2.8 MN/m 3/2 ) was obtained. These mechanical properties can be at…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsMicrowave Dielectric Ceramics Synthesis

The equilibrium low-temperature structure of ice

A. J. Leadbetter、Richard C. Ward、James Clark 等 6 位作者1985-01-01The Journal of Chemical Physics

Following the discovery of a first-order phase transition in annealed KOH-doped ice at 72 K, which was identified as the order–disorder transition associated with the proton positions, a structural study has now been made. Powder neutron diffraction measurements on KOD-doped D2O above and below the phase transition, t…

High-pressure geophysics and materialsSolid-state spectroscopy and crystallographyInorganic Fluorides and Related Compounds