Materials Literature
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Trivalent europium‐activated yttrium oxysulfide phosphor material prepared by a sulfide fusion method is the primary red material used extensively in color television (CTV) screens. Applying the heterogeneous nucleation theory, we discuss some new results obtained on the formation process of the yttrium oxysulfide sys…
Abstract EuCu 2 As 2 (a = 4,215(1) Å, c = 10,185(2) Å) und EuCu 2 Sb 2 (a = 4,504(1) Å, c = 10,824(2) Å) wurden durch Erhitzen entsprechender Gemenge aus CuCl und Arsen bzw. Antimon mit Europium auf ca. 900°C dargestellt und mit verd. Essigsäure von den Nebenprodukten befreit. Das Arsenid kristallisiert im ThCr 2 Si 2…
Electrochromic manganese oxide thin films were prepared by chemical vapor deposition. The source material was manganese (III) acetylacetonate. Transparent thin films were obtained at a substrate temperature above 250°C. Oxidation and reduction of the films in a propylene carbonate solution resulted in desirable change…
Abstract The crosslinking of ferroelectric liquid‐crystalline (LC) polysiloxanes — performed within the region of microphase separation — allows the preparation of LC‐elastomers which combine macroscopic form stability (insolubility) with nearly unchanged switching time (compared to the uncrosslinked polymers).
The operation of optical narrowband reflection filters based on resonance anomalies of waveguide gratings is well established for gratings of infinite extent. We investigate the properties of finite-aperture waveguide-grating resonance filters by means of rigorous electromagnetic theory and an approximate model. The r…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory for the Phase Behavior of Polyolefin Blends: Application to the Polyethylene/Isotactic Polypropylene BlendJohn J. Rajasekaran, John G. Curro, and J. D. HoneycuttCite this: Macromolecules 1995, 28, 20, 6843–6853Publication Date (Print):September 1, 1995Publication Hist…
Ceramic specimens of the complex perovskite oxide Ba(Fe 1/2 Nb 1/2 )O 3 were fabricated by conventional solid state sintering. Dielectric constants were measured as a function of temperature as well as of frequency. As a result, dielectric constants showed an unusual temperature dependence. Moreover, a large dielectri…
Abstract Incorporation of rick husk ash (RHA) fillers into polypropylene affected some of the thermal properties of polypropylene composites. Addition of the black rice husk ash (BRHA) filler raised the thermal degradation temperature while maintaining the oxidative stability. The thermal degradation temperature of th…
Growth of artificial pits in the Ni/sulfuric acid system was investigated using a microprobe technique for the potential monitoring and pH measurements within the pits, as well as routine electrochemical, solution analysis, and metallographic techniques. The measured data and the observed changes in shape of the pit w…
Abstract Compatibility of natural rubber (NR)/polystyrene (PS) blend is poor and can be enhanced by the addition of a graft copolymer of natural rubber and polystyrene (NR- graft -PS). The effects of homopolymer molecular weight, copolymer molecular weight, copolymer concentration, processing conditions and mode of ad…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTShear-Induced Alignment of a Hexagonal Lyotropic Liquid Crystal as Studied by Rheo-NMRMichail Lukaschek, David A. Grabowski, and Claudia SchmidtCite this: Langmuir 1995, 11, 9, 3590–3594Publication Date (Print):September 1, 1995Publication History Published online1 May 2002P…
We have tested the effect of several cations in attempts to crystallize the ligand-bound forms of the leucine/isoleucine/valine-binding protein (LIVBP) (M(r) = 36,700) and leucine-specific binding protein (LBP) (M(r) = 37,000), which act as initial periplasmic receptors for the high-affinity osmotic-shock-sensitive ac…
One of the most commonly overlooked parameters in grain boundary engineering initiatives is solute-interface interactions involving solute concentrations typically in the ppm range. In this work, experimental evidence is presented that demonstrates the significant effect of such interactions upon (1) the specific prop…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of the Restricted Geometry on the Morphology of Ultrathin Poly(di-n-hexylsilane) FilmsM. M. Despotopoulou, C. W. Frank, R. D. Miller, and J. F. RaboltCite this: Macromolecules 1995, 28, 19, 6687–6688Publication Date (Print):September 1, 1995Publication History Published…
A new method of high-resolution electron microscopy image analysis is presented which improves considerably the visibility of nanocrystals in amorphous materials. The technique is based on individual Bragg filtering of the lattice fringes in the image. The significant feature is that the amplitude and phase of the fri…
Over the past two decades the amount of effort devoted to the study of metal oxides by surface scientists has increased significantly. The general characteristics of the electronic structure of metal-oxide surfaces are now fairly well understood, although transition-metal oxides have been more thoroughly studied than…
Complex dielectric constant of an antiferroelectric liquid crystal family represented by 4-(1-methylheptyloxycarbonyl) 3-fluorophenyl 4'-dodecylbiphenyl-4-carboxylate was measured in the frequency range between 10 -2 Hz and 10 7 Hz. The experimental results were analyzed using a generalized Cole-Cole expression, and s…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAryl fluoride monomers in nucleophilic aromatic substitution polymerization: evaluation of monomer reactivity by 19F NMR spectroscopyKenneth R. CarterCite this: Macromolecules 1995, 28, 19, 6462–6470Publication Date (Print):September 1, 1995Publication History Published onli…
Equilibrium constants and enthalpy changes for reactions catalyzed by the lyase class of enzymes have been compiled. For each reaction the following information is given: the reference for the data; the reaction studied; the name of the enzyme used and its Enzyme Commission number; the method of measurement; the condi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffects of p-Methylstyrene Comonomeric Units on the Polymorphic Behavior of Syndiotactic PolystyreneCarla Manfredi, Gaetano Guerra, Claudio De Rosa, Vincenzo Busico, and Paolo CorradiniCite this: Macromolecules 1995, 28, 19, 6508–6515Publication Date (Print):September 1, 199…