Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSteric Effects on the Base Strengths of Cyclic Amines1H. K. Hall Jr.Cite this: J. Am. Chem. Soc. 1957, 79, 20, 5444–5447Publication Date (Print):October 1, 1957Publication History Published online1 May 2002Published inissue 1 October 1957https://pubs.acs.org/doi/10.1021/ja01…
Previous studies of the kinetics of dehydroxylation of kaolinite and halloysite point to first‐order reactions, in approximate conformity with the Arrhenius relation. Isothermal weight‐loss measurements have shown that the rate constants are markedly dependent on factors such as specimen size, shape, and compaction. A…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCRYSTALLOGRAPHY OF OCTACALCIUM PHOSPHATEWalter E. Brown, James R. Lehr, James P. Smith, and A. William FrazierCite this: J. Am. Chem. Soc. 1957, 79, 19, 5318–5319Publication Date (Print):October 1, 1957Publication History Published online1 May 2002Published inissue 1 October…
Upon depoling ceramic barium titanate, up to 9% of the domains reorient by 90°, indicating that during poling at least this percentage of the domains was permanently reoriented by 90°. Ceramic barium titanate shows a strong anelastic effect in the ferroelectric state, presumably due to domain reorientations under stre…
Magnetic properties of the synthesized solid solution x FeTiO 3 ·(1- x ) Fe 2 O 3 of ilmenite (FeTiO 3 ) and hematite (Fe 2 O 3 ) were investigated in detail for the whole range of 0≦ x ≦1. On the experimental side of the study, the most suitable method for preparing the specimen with the largest intensity of magnetiz…
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Abstract Durch Auswaschen des frisch bereiteten Graphitoxyds mit salzsäurehaltigem Chlordioxydwasser wurde unter Ausschluß von Lieht ein auch nach dem Trocknen noch helles Produkt erhalten. Das helle und das übliche dunkle Graphitoxyd aus der gleichen Herstellung haben die gleiche chemische Zusammensetzung. Durch Umse…
An expression for the steady-state creep rate of crystals is derived for the case where dislocation climb is not rate controlling. Two rate-controlling processes are considered. In the first the dislocations are considered to move in a viscous manner, their velocity of motion being proportional to the force exerted on…
(1957). A theory of the fracture of metals. Advances in Physics: Vol. 6, No. 24, pp. 418-465.
The piezoelectric effect of bone has been observed similarly to the case of wood or ramie. The specimens were cut out from the femur of man and ox, and dried completely by heating. The piezoelectric constants were measured by three different experiments, that is, measurements of the static direct effect, the dynamic d…
A detailed model for the crystal structure of the fibrous polysaccharide chitin is proposed. The structure determination has been carried out by using an optical analogue instrument which proved to be an adequate and rapid tool for the derivation of Fourier transforms, signs of amplitudes and the production of optical…
Glycine silver nitrate, N${\mathrm{H}}_{2}$C${\mathrm{H}}_{2}$COOH\ifmmode\cdot\else\textperiodcentered\fi{}AgN${\mathrm{O}}_{3}$, is ferroelectric below -55\ifmmode^\circ\else\textdegree\fi{}C. At -195\ifmmode^\circ\else\textdegree\fi{}C the spontaneous polarization is 0.55\ifmmode\times\else\texttimes\fi{}${10}^{\en…
An electron spin resonance (ESR) spectrum induced in magnesium oxide crystals by pile irradiation has been interpreted as arising from $F$ centers. After an oxide ion is displaced from its normal position by neutrons, an electron donated by ever-present divalent impurities may become trapped at the vacancy. Those cent…
Copper chromite, CuCr~O 4, is a tetragonally distorted normal spinel with a c/a ratio, as referred to a face-centered unit cell, of about 0.91. A structure which is physically reasonable, belonging to the space group D~-I42d, is based on an environment for the copper ions which is distorted from a tetr~hedron toward a…
Abstract A theoretical calculation of the energy levels, and hence absorption spectrum, of an isolated vacancy in an otherwise perfect diamond lattice has been made. The concept of a defect molecule is introduced. This enables familiar molecular orbital theory to be applied in calculating the electronic structure of t…