Materials Literature
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We investigate the influence of disorders in terminal ethylene groups of BEDT-TTF molecules (ethylene-disorders) on the vortex pinning of the organic superconductor $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br. Magnetization measurements are performed under different cooling-processes. The second peak in the magnetization h…
Abstract In this article, poly(vinyl chloride) (PVC)–organoclay nanocomposites were prepared via in situ polymerization intercalation and melt blending intercalation, respectively. Their nanostructures were characterized by X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Differences in the morpholo…
Abstract The miscibility behaviour and hydrogen‐bonding interaction in blends of poly(2‐hydroxypropyl methacrylate) (PHPMA) with polyvinylpyrrolidone (PVP) were characterized using differential scanning calorimetry and Fourier‐transform infrared spectra. This polymer blend was miscible over the whole composition range…
Abstract The grafting of glycidyl methacrylate (GMA) onto linear low‐density polyethylene (LLDPE) was investigated. The grafting was performed by free‐radical grafting in the melt state in a twin‐screw extruder using an organic peroxide as initiator. The effect of initial GMA and peroxide concentration, styrene comono…
Uniform micro-sized alpha- and beta-Si(3)N(4) thin ribbons have been achieved by a high-temperature thermal-decomposition/nitridation route. As-grown ribbons were characterized by using powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, elect…
The Dorokhov-Mello-Pereyra-Kumar (DMPK) equation for transmission eigenvalues is derived for metallic carbon nanotubes with several conducting channels when the potential range of scatterers is larger than the lattice constant. With increasing system length L, the system approaches a fixed point, where only one channe…
Abstract The nonisothermal crystallization kinetics of high‐density polyethylene (HDPE) and polyethylene (PE)/PE‐grafted maleic anhydride (PE‐ g ‐MAH)/organic‐montmorillonite (Org‐MMT) nanocomposite were investigated by differential scanning calorimetry (DSC) at various cooling rates. Avrami analysis modified by Jezio…
Star-shaped mesogens with long semiflexible oligoester arms up to the fifth generation and a shell of aliphatic dodecyloxy chains self-assemble in columnar mesophases. Different conformers may be envisaged, which can provide a dense packing and migrosegregation of different molecular parts.
Sugar-appended porphyrins (1 a-e) with monosaccharide groups at their periphery have been rationally designed for a new class of gelating reagents. A few of these compounds have the tendancy to form one-dimensional aggregates stable enough to show successful gelation ability for DMF-alcohol mixed solvents. The aggrega…
θ-(BEDT-TTF) 2 RbZn(SCN) 4 is a two-dimensional organic conductor exhibiting a metal–insulator transition at T MI =200 K. This insulating charge ordered state below T MI was investigated by a single crystal structural analysis taking account of the superlattice formation below T MI . A large displacement (about 0.2 Å)…
The metal–insulator (M–I) transitions in VO 2 and Ti 2 O 3 were investigated using the three-band Hubbard model in connection with the on-site exchange interaction and lattice distortions. Although these two compounds have different crystal structures, the mechanism of the phase transitions can be understood from a un…
It is shown that whatever the technique used, conventional solid-state reaction or precipitation from solutions, the formation of lithium lanthanum titanate, Li 0.5 La 0.5 TiO 3, is a multistage process, which occurs in a wide temperature range. Thermal analyses, X-ray powder diffraction (XRPD), and infrared (IR) spec…
Program FOX for ab initio crystal structure determination from powder diffraction uses global optimization algorithms to find the correct structure by making trials in the direct space. It is a modular program, capable of using several criteria for evaluating each trial configuration, e.g. combining neutron and X-ray…
Software for the simulation of X-ray powder diffraction (XRPD) patterns for ultrafine-grained materials with some kinds of imperfections has been developed. These calculations are performed on the base of the model of one-dimensionally disordered (1D-disordered) crystal [1]. Such a model can describe stacking faults (…
Zinc porphyrin-naphthalenediimide (ZnP-NIm) dyads and zinc porphyrin-pyromellitdiimide-naphthalenediimide (ZnP-Im-NIm) triad have been employed to examine the effects of metal ions on photoinduced charge-separation (CS) and charge-recombination (CR) processes in the presence of metal ions (scandium triflate (Sc(OTf)(3…
Abstract The alkaline hydrolysis of polyacrylonitrile staple fibers was investigated for evaluation as superabsorbent materials. Studies were performed to analyze the hydrolysis of fibers and the quantification of the developed functional groups, such as carboxyl and amide groups as well as changes in the nitrile cont…
Four linear benzofuran trimers have been prepared by a two-stage synthetic procedure. They were tested as materials for organic electroluminescence (OEL). Precursor phenylene ethynylene oligomers were formed in the first stage, then after removal of the phenolic hydroxyl protecting groups, a base was used to promote t…
We studied the interrelationship of elastic and piezoelectric properties with the lattice structure and crystal physics of paratellurite $(\ensuremath{\alpha}\ensuremath{-}{\mathrm{TeO}}_{2}).$ Tetragonal paratellurite ${(D}_{4}^{4},P422)$ shows six independent elastic constants ${C}_{\mathrm{ijkl}},$ the associated i…
By means of neutron diffraction the low-temperature crystal structure of NaBD 4 has been determined. At 10 K the lattice parameters are a = 4.332(1) Å and c = 5.869(1) Å. Deuterium is found in a tetrahedral arrangement [sites (8g)] around B. The symmetry corresponds to space group P4 2 /nmc. For room temperature the s…
The catalytic dehydrocoupling reactions of Me2NH.BH3 and Ph2PH.BH3 using the rhodium precatalyst [Rh(1,5-cod)(mu-Cl)]2 were found to proceed by different mechanisms: heterogeneous involving Rh(0) metal for the former case and homogeneous for the latter.