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Combinatorial pulsed laser deposition and thermoelectricity of (La1−xCax)VO3 composition-spread films

Quinjiao Wang, Kenji Itaka, Hideki Minami, Hitoshi Kawaji and Hideomi Koinuma2004-01-01Science and Technology of Advanced Materials

La1−xCaxVO3 composition-spread film library was fabricated by combinatorial pulsed laser deposition and their thermoelectric properties were evaluated paralelly by the multi-channel probes of Seebeck coefficient and electric conductivity. Concurrent X-ray analysis verified the formation of solid soluted films in the f…

Formation of nanocrystalline surface layers in various metallic materials by near surface severe plastic deformation

Masahide Sato, Nobuhiro Tsuji, Yoritoshi Minamino and Yuichiro Koizumi2004-01-01Science and Technology of Advanced Materials

The surface of the various kinds of metallic materials sheets were severely deformed by wire-brushing at ambient temperature to achieve nanocrystalline surface layer. The surface layers of the metallic materials developed by the near surface severe plastic deformation (NS-SPD) were characterized by means of TEM. Nearl…

Microstructures and mechanical properties of bulk nanocrystalline Fe–Al–C alloys made by mechanically alloying with subsequent spark plasma sintering

Yoritoshi Minamino, Yuichiro Koizumi, Nobuhiro Tsuji, Naoko Hirohata, Kiyoshi Mizuuchi and Yoshihira Ohkanda2004-01-01Science and Technology of Advanced Materials

The microstructure and superior mechanical properties of bulk nanocrystalline Fe–Al–C alloys made by mechanically alloying (MA) with subsequent spark plasma sintering (SPS) were investigated. Three kinds of nanocrystalline Fe–24 at% Al–X at%C (X=1,2,4) alloy powder were produced by MA from iron and aluminum powder wit…

High temperature degradation in power plants and refineries

Furtado Heloisa Cunha、May Iain Le2004-01-01Materials Research

Thermal power plants and refineries around the world share many of the same problems, namely aging equipment, high costs of replacement, and the need to produce more efficiently while being increasingly concerned with issues of safety and reliability. For equipment operating at high temperature, there are many differe…

Comparison of two different synthesis methods of perovskites, SrCo0.5FeO3 type, aiming at evaluating their use as membranes for partial oxidation of methane

Noronha F.B.、Mattos L.V.、Souza H.P. de 等 6 位作者2004-01-01Materials Research

In this work two different synthesis methods of perovskites, SrCo0.5FeO3, were compared: combustion synthesis and oxides mixture aiming at evaluating their use as membranes for partial oxidation of methane. The combustion synthesis method explores an exothermic, generally very fast and self-sustaining chemical reactio…

Plasma sintering of unalloyed iron: a study of surface porosity

Lourenço Jorge Magner、Maliska Ana Maria、Klein Aloísio Nelmo 等 4 位作者2004-01-01Materials Research

Samples of unalloyed iron powder were compacted and sintered in an abnormal glow discharge, generated in a gas mixture of 80% Ar + 20% H2 by using a pulsed power source. The samples were placed on a holder, acting as the discharge cathode, and were heated by the bombardment of ions, strongly accelerated in the cathode…

Void Content, Density and Weight Reduction Studies on Short Bamboo Fiber–Epoxy Composites

A. Varada Rajulu、K. Narasimha Chary、G. Ramachandra Reddy 等 4 位作者2004-01-01Journal of Reinforced Plastics and Composites

Short bamboo fiber reinforced epoxy composites were developed with varying fiber content. The void content, density, and weight reduction of these composites were determined. The void content of these composites was found to be decreasing with increasing fiber content. The density of these composites was found to be d…

Bamboo properties and applicationsNatural Fiber Reinforced CompositesMechanical Engineering and Vibrations Research

Self-similar chain of metal nanospheres as efficient nanolens

Mark I. Stockman、Kuiru Li、David J. Bergman2004-01-01OpenAlex

As an efficient nanolens, we propose a self-similar linear chain of several metal nanospheres with progressively decreasing sizes and separations. To describe such systems, we develop the multipole spectral expansion method. Optically excited, such a nanolens develops the nanofocus (“hottest spot”) in the gap between…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchQuantum Dots Synthesis And Properties

Novel Room Temperature Inorganic Ionic Liquids

Liyi Dai、Shuyuan Yu、Yongkui Shan 等 4 位作者2004-01-01European Journal of Inorganic Chemistry

Abstract New inorganic ionic liquids (IIL) consisting of an inorganic polyoxometalate anion with the Keggin structure and a sodium cation, that is Na 13 [Ln(TiW 11 O 39 ) 2 ]· x H 2 O [where Ln = lanthanide (type 1)], Na 5 [MTiW 11 O 39 ]· x H 2 O and Na 6 [MTiW 11 O 39 ]· x H 2 O [where M = transition metal (type 2)]…

Polyoxometalates: Synthesis and ApplicationsIonic liquids properties and applicationsVanadium and Halogenation Chemistry

Sol–gel synthesis of Al 2 O 3 –P 2 O 5 glasses: mechanistic studies by solution and solid state NMR

Long Zhang、Hellmut Eckert2004-01-01Journal of Materials Chemistry

Colorless and transparent aluminium phosphate gels and glasses with P/Al ratios ranging from 0.5 to 3.0 are prepared via the sol–gel process using aluminium lactate and phosphoric acid as precursors. This glass-forming range is significantly wider than accessible via the melt cooling route. Optimum pH ranges and therm…

Zeolite Catalysis and SynthesisGlass properties and applicationsAdvanced NMR Techniques and Applications

Modeling and Simulation of Microstructure Evolution in Solidifying Alloys

Laurentiu Nastac2004-01-01Kluwer Academic Publishers eBooks

The aim of Modeling and Simulation of Microstructure Evolution in Solidifying Alloys is to describe in a clear mathematical language the physics of the solidification structure evolution of cast alloys. The concepts and methodologies presented here for the net-shaped casting and the ingot remelt processes can be appli…

Aluminum Alloy Microstructure PropertiesMetallurgy and Material FormingSolidification and crystal growth phenomena

Highly efficient dehalogenation using hydroxyapatite-supported palladium nanocluster catalyst with molecular hydrogen

Takayoshi Hara、Kohsuke Mori、Michitaka Oshiba 等 6 位作者2004-01-01Green Chemistry

A hydroxyapatite-supported Pd nanocluster (PdHAP) efficiently catalysed the dehalogenation of various organic halides in the presence of atmospheric molecular hydrogen; chlorobenzene gave benzene in an excellent TON of 10 000 for 10 h. Moreover, the dehalogenation of halophenols in aqueous conditions was also achieved.

Environmental remediation with nanomaterialsNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Transverse dynamics of nematicons

Marco Peccianti、Andrea Fratalocchi、Gaetano Assanto2004-01-01Optics Express

Optical anisotropy plays a fundamental role on light propagation in nematic liquid crystals. With specific reference to nematicons, we investigate the transverse dynamics due to the interplay of nonlinear self-confinement, birefringent walk-off and a bias-dependent transverse index profile.

Quantum optics and atomic interactionsLiquid Crystal Research AdvancementsAdvanced Fiber Laser Technologies

Chitin Mineralization

Giuseppe Falini、Simona Fermani2004-01-01Tissue Engineering

The polysaccharide chitin is found in nature as a major component of the organic fraction of several biocomposites in which an organic matrix is associated with an inorganic fraction. The relationship between the mineral phase and the organic phase implies a high level of molecular recognition. Chitin in mineralized b…

Calcium Carbonate Crystallization and InhibitionPaleontology and Stratigraphy of FossilsBone Tissue Engineering Materials

Electrochemical Capacitor Behavior of Layered Ruthenic Acid Hydrate

Wataru Sugimoto、Hideki Iwata、Yasushi Murakami 等 4 位作者2004-01-01Journal of The Electrochemical Society

A hydrous ruthenic acid possessing a layered structure with a crystalline framework was prepared by proton exchange of a layered potassium ruthenate. Its electrochemical capacitor behavior was studied by cyclic voltammetry in various electrolytes. Specific capacitance up to 390 F at a scan rate of 50 mV s −1 , which i…

Advancements in Battery MaterialsPolyoxometalates: Synthesis and ApplicationsSupercapacitor Materials and Fabrication

A pentanuclear yttrium hydroxo cluster as an oxidation catalyst. Catalytic oxidation of aldehydes in the presence of air

Peter W. Roesky、Graciela Canseco‐Melchor、Agustino Zulys2004-01-01Chemical Communications

The air- and moisture-stable pentanuclear yttrium cluster H(5)[Y(5)(mu(4)-O)(mu(3)-O)(4)(mu-eta](2)-Ph(2)acac)(4)(eta](2)-Ph(2)acac)(6)](Ph(2)acac = dibenzoylmethanide) has been used as a homogeneous catalyst for the oxidation of aldehydes to the corresponding carboxylic acids in the presence of air.

Lanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and ApplicationsMagnetism in coordination complexes

Moisture Effects in Heat Transfer Through Clothing Systems for Wildland Firefighters

Lelia Lawson、Elizabeth M. Crown、M. Y. Ackerman 等 4 位作者2004-01-01International Journal of Occupational Safety and Ergonomics

Wildland firefighters work in unfavourable environments involving both heat and moisture. Moisture in clothing systems worn by wildland firefighters may increase or decrease heat transfer, depending on its source and location in the clothing system, location on the body, timing of application and degree of sorption. I…

Thermoregulation and physiological responsesOccupational Health and PerformanceTextile materials and evaluations

Conceptual Design of HP-STMCs Space Reactor Power System for 110 kWe

Mohamed S. El‐Genk2004-01-01AIP conference proceedings

A conceptual design of a Heat Pipe‐Segmented Thermoelectric Module Converters (HP‐STMCs) space reactor power system (SRPS) for a net power of 110 kWe is developed. The parametric analysis changed the number of radiator’s potassium heat pipes from 224 to 336 and calculated the effects on the operation parameters and to…

Graphite, nuclear technology, radiation studiesFusion materials and technologiesNuclear and radioactivity studies

Design of solid wood panels with cross layers

Hans Joachim Blaß、Peter Fellmoser2004-01-01Repository KITopen (Karlsruhe Institute of Technology)

The objective of this paper is to present a method for the design of solid wood panels with cross layers. The stress distribution in and the deformation behaviour of solid wood panels were analysed using the composite theory. The shear influence in solid wood panels was determined using the shear analogy method. A str…

Wood Treatment and PropertiesMaterial Properties and ProcessingTextile materials and evaluations

Monitoring the formation of biosilica catalysed by histidine-tagged silicatein

Muhammad Nawaz Tahir、Patrick Théato、Wernér E.G. Müller 等 8 位作者2004-01-01Chemical Communications

Surface bound silicatein retains its biocatalytic activity, which was demonstrated by monitoring the immobilisation of silicatein using a histidine-tag chelating anchor and the subsequent biosilicification of SiO(2) on surfaces by surface plasmon resonance spectroscopy, atomic force microscopy and scanning electron mi…

Mesoporous Materials and CatalysisProtist diversity and phylogenyDiatoms and Algae Research