Materials Literature
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Abstract A procedure was developed for benzoylating the polystyrene segments in polystyrene‐ b ‐poly(ethylene‐ co ‐butene)‐ b ‐polystyrene (SEBS) triblock copolymers. The products were characterized by NMR spectroscopy, gel permeation chromatography, dynamic mechanical thermal analysis, and membrane osmometry. The mec…
Abstract Blends of poly(hydroxy ester ether) (PHEE), a recently developed bisphenol A ether‐based synthetic biodegradable thermoplastic polymer, with a soybean protein isolate and two hydrolyzed wheat glutens were studied. Blends of the proteins with PHEE were produced from 20 to 70% by weight of protein content. Youn…
Short-chain poly-(R)-3-hydroxybutyrate (cPHB), a highly flexible, amphiphilic molecule with salt-solvating properties, is a ubiquitous constituent of prokaryotic and eukaryotic cells, wherein it is mainly conjugated to proteins. The solvating properties and cellular distribution of cPHB suggest it may be associated wi…
Organogelators are small organic molecules that self-assemble at low temperature in long entangled and connected fibers to give birth to a random gel. In this paper, we describe a systematic procedure to prepare easily orientated samples by using a weak flow. We demonstrate that applying a mechanical shear stress duri…
Convenient routes to a range of water-soluble polyferrocenylsilane polyelectrolytes are reported. Direct reaction of the protected aminopropynyl reagent LiC⋮CCH 2 N(SiMe 2 CH 2 ) 2 ( 8 ) with the substitutionally labile ring-opened polymer [fcSiMeCl] n ( 3 ) (fc = Fe(η−C 5 H 4 ) 2 ), which is generated via Pt-catalyze…
Abstract The thermal stabilizing efficiency of a range of phenolic antioxidants (Lowinox CA22, Lowinox WSP, Lowinox TBP6, Irganox 3114, Irganox 1330, and Cyanox 1790) was determined in polyethylene films with chemiluminescence and hydroperoxide analysis and compared with standard systems based on Irganox 1010 and 1076…
Abstract The role of hydrogen bonding in promoting intermolecular cohesion and higher glass‐transition temperatures of polymer is a subject of longstanding interest. A series of poly(vinylphenol‐ co ‐vinylpyrrolidone) copolymers were prepared by the free‐radical copolymerization of acetoxystyrene and vinylpyrrolidone;…
The structural distortion of high-generation poly(amidoamine) (PAMAM) dendrimers at the liquid/solid interface was investigated in situ using tapping mode atomic force microscopy (AFM). With a substantial compression along the surface normal but minor lateral expansion, isolated PAMAM dendrimers at the water/mica inte…
Abstract A series of phosphorus‐containing, wholly aromatic thermotropic copolyesters from acetylated 2‐(6‐oxide‐6H‐dibenz〈c,e〉〈1,2〉oxa phosphorin‐6‐yl)‐1,4‐dihydroxy phenylene, p ‐acetoxybenzoic acid, terephthalic acid, and isophthalic acid were prepared by melting polycondensation. The structure and basic properties…
Periodic mesoporous organosilica (PMO) with two-dimensional hexagonal symmetry was synthesised using a bridged silsesquioxane (CH3O)3Si-CH2-CH2-Si(CH3O)3 as precursor and polyoxyethylene non-ionic surfactant (Brij-56) as template. The hybrid material was characterised by X-ray diffraction, N2 adsorption, TEM, and soli…
Abstract Poly(vinyl alcohol) (PVA) films with different thicknesses (0.08, 0.2, 0.23, 0.42 mm) were prepared by a casting technique. The transmission and the absorption of the PVA films were measured as functions of the wavelengths. PVA film with a thickness of 0.42 mm showed zero transmission in the wavelength range…
Abstract Radiation effects of low‐density polyethylene/ethylene‐vinyl acetate copolymer (LDPE/EVA) blends were discussed. EVA content in the LDPE/EVA blends was an enhancement effect on radiation crosslinking of LDPE/EVA blends, and the highest radiation crosslinking was obtained when the EVA content was reached at 30…
Abstract Poly(lactic acid) (PLA) is a biodegradable synthetic polyester with unique properties that make it an excellent candidate for biomaterial blends. It provides improved moisture resistance to blends with biopolymers and biodegradability/biocompatibility to blends with synthetic polymers, without impairing the u…
In support of programs to identify polyhydroxyalkanoates with improved materials properties, we report on our efforts to characterize the mechanical and thermal properties of copolyesters of 3-hydroxybutyrate (3HB) and 3-hydroxyhexanoate (3HHx). The copolyesters, having molar fraction of 3HHx ranging from 2.5 to 35 mo…
A simple quasistatic treatment for the plasmon resonance spectra of nanoparticle rod−rod and rod−sphere pairs is presented. Spectra are calculated for gold particle pairs at different distances and mutual orientations. For rod−rod and rod−sphere pairs, the spectral changes that occur as a result of interparticle inter…
We have investigated the static and dynamic response of magnetic clusters in Co_{0.2}Zn_{0.8}Fe_{1.6}Ti_{0.4}O_4 spinel oxide, where a sequence of magnetic phase transitions, i.e., paramagnetic (PM) to ferromagnetic at T_{C} $\leq$ 270K and ferromagnetic to canted spin glass state at T_f$ $\leq$ 125K is observed.
Experiments in quasi 2-dimensional geometry (Hele Shaw cells) in which a fluid is injected into a visco-elastic medium (foam, clay or associating-polymers) show patterns akin to fracture in brittle materials, very different from standard Laplacian growth patterns of viscous fingering. An analytic theory is lacking sin…
Recent years have shown steady progress in research towards molecular electronics [1,2], where molecules have been investigated as switches [3-5], diodes [6], and electronic mixers [7]. In much of the previous work a Scanning Tunnelling Microscope was employed to address an individual molecule. As this arrangement doe…
We consider spatially discrete bistable reaction-diffusion equations that admit wave front solutions. Depending on the parameters involved, such wave fronts appear to be pinned or to glide at a certain speed. We study the transition of traveling waves to steady solutions near threshold and give conditions for front pi…
Abstract We evaluated the effects of the solvent composition with respect to the solution concentration, applied electric field, and tip‐to‐collector distance on the morphology of electrospun poly(vinyl chloride) (PVC) fibers. The solvent volume ratio was strongly correlated with the diameter of the electrospun fibers…