Materials Literature
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Einfach, aber gut: Das leicht zu handhabende und umweltverträgliche Oxone erzeugt Singulettsauerstoff, der unter milden Bedingungen selektiv und mit guten bis ausgezeichneten Ausbeuten para-Alkylphenole 1 oxidativ zu para-Peroxychinolen 2 desaromatisiert. Auch para-Chinole 3 können in einem Eintopfverfahren aus 1 durc…
Anode tubes coated with thin and dense electrolyte layers were fabricated by thermoplastic coextrusion, using a nickel oxide (NiO)–yttria‐stabilized zirconia (YSZ) composite and YSZ as the anode and electrolyte materials, respectively. The initial feedrod with a diameter of 22 mm, comprised of three thermoplastic comp…
The bacterial phosphoenolpyruvate (PEP):glycose phosphotransferase system (PTS) mediates uptake/phosphorylation of sugars. The transport of all PTS sugars requires Enzyme I (EI) and a phosphocarrier histidine protein of the PTS (HPr). The PTS is stringently regulated, and a potential mechanism is the monomer/dimer tra…
The reflection resonance spectrum of a subwavelength diffraction-grating-coupled waveguide is used to analyze biomolecular interactions in real time. By detecting this resonance wavelength shift, the optical waveguide biosensor provides the ability to identify the kinetics of the biomolecular interaction on an on-line…
Gadolinium(III)-modified polycrystalline lead titanate (PbTiO3) of 1.0mol% dopant level was investigated by means of multifrequency electron paramagnetic resonance spectroscopy in order to determine sign and size of the local-environment sensitive finestructure parameter B20. The Gd3+ ions were assigned to substitute…
We report on the effects of a low-frequency electric field on the optical nonlinear response of thin dye-doped liquid crystal cells. Experimental data show that the external field allows reaching extremely high values of the optical nonlinearity without any critical control of the cell interfaces. A qualitative interp…
Thin films of single c-domain/single-crystal (1−x)Pb(Mg1∕3Nb2∕3)O3−xPbTiO3 (PMN-PT) with x≅0.33 near a morphotropic boundary composition were heteroepitaxially grown on (110)SRO∕(001)Pt∕(001)MgO substrates. The heteroepitaxial growth was achieved by rf-magnetron sputtering at the substrate temperature of 600°C. After…
Wechselhafte Taktizität: Die Ringöffnungspolymerisation von rac-β-Butyrolacton (rac-BBL) in Gegenwart eines sechsfach koordinierten Yttriumkomplexes mit dianionischem Amin-Bis(phenolat)-Liganden als Initiator ergibt bei Raumtemperatur Poly(3-hydroxybutyrat) (PHB) mit bis 94 % Syndiotaktizität und enger Molekulargewich…
The polarization fatigue behaviors of ferroelectric Pb1−xSrx(Zr0.52Ti0.48)O3 (PSZT) thin films deposited on Pt-coated silicon wafers are investigated. Significantly enhanced fatigue endurance with increasing Sr doping and decreasing temperature is observed, and the almost fatigue-free performance up to 1010 switching…
By means of thorough atomistic simulations an energy-based theory, named quantized fracture mechanics, is commented and validated. This approach modifies continuum linear elastic fracture mechanics by introducing the hypothesis of discrete crack propagation, taking into account the discreteness of the crystal lattice.…
Abstract A reactive extrusion process was developed improving the rheological properties of PET via the coaddition of a dianhydride and polyol. Specifically, the coaddition of pyromellitic dianhydride (PMDA) with pentaerythritol resulted in a gel‐free polyester with superior melt strengths and viscosities compared to…
Silica layers implanted with Si and Er ions to various doses and annealed at 950°C have been investigated by means of energy-filtered transmission electron microscopy (EFTEM) and high annular angle dark field (HAADF). EFTEM analysis reveals Si nanoclusters (Si-nc) with an average size around 3nm for high Si content (1…
Epitaxial double-perovskite Sr2FeMoO6 films have been grown by pulsed laser deposition (PLD) on SrTiO3 substrates. High-quality metallic Sr2FeMoO6 thin films with low resistivity were obtained by deposited in a mixture gas of hydrogen and argon. Resistivity versus temperature measurements, magnetic measurement, and x-…
Ge ∕ Si structures grown on oxidized Si surfaces are studied by means of photoluminescence (PL). High-temperature annealing of the structures leads to the increase of their PL intensity by at least one order of magnitude at energies around 0.82eV. It is suggested that relaxation of strain, existing in our structures d…
Abstract Durability of lingo‐cellulosic fiber composites under environmental conditions such as moisture, freezing and thawing, and UV exposure needs to be determined prior to the use of these composite materials in outdoor applications. Dimensional stability and changes in the flexural strength and stiffness of extru…
Abstract A new modified carbon black (GCB) was prepared by adding special RFL latex into N220. Dynamic properties were obtained over a wide range of temperatures and strains on vulcanizates filled with GCB and unmodified carbon black, respectively. The results show that the GCB can effectively decrease the tan δ value…
The goal of this work is to develop a technique to measure the x-ray diffraction signals of breast biopsy specimens. A biomedical x-ray diffraction technology capable of measuring such signals may prove to be of diagnostic use to the medical field. Energy dispersive x-ray diffraction measurements coupled with a semian…
Abstract Polyesters were synthesized with monoglycerides prepared from rubber seed oil, a renewable resource. Monoglycerides were obtained by an alcoholysis method from the oil, which was neat or modified by treatments with different amounts of maleic anhydride at 230°C. The polyester resins were subsequently prepared…
Six of one: A hexanuclear iron p-nitrobenzoate compound (see structure; green Fe, red O, blue N, gray C), a novel type of iron cluster was prepared and characterized. The complex has an [Fe6(μ3-O)3(μ2-OH)]11+ core and shows a remarkable catalytic activity in the oxidation of cyclohexane.
Silicon carbide fiber (Hi‐Nicalon Type S, Nippon Carbon) reinforced silicon carbide matrix composites containing melt‐infiltrated silicon were subjected to creep at 1315°C at three different stress conditions. For the specimens that did not rupture after 100 h of tensile creep, fast‐fracture experiments were performed…