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Synthesis, characterization, and ceramic conversion reactions of borazine-modified hydridopolysilazanes: new polymeric precursors to silicon nitride carbide boride (SiNCB) ceramic composites

Kai Su、Edward E. Remsen、Gregg A. Zank 等 4 位作者1993-04-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, characterization, and ceramic conversion reactions of borazine-modified hydridopolysilazanes: new polymeric precursors to silicon nitride carbide boride (SiNCB) ceramic compositesKai Su, Edward E. Remsen, Gregg A. Zank, and Larry G. SneddonCite this: Chem. Mater.…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsOrganoboron and organosilicon chemistry

Lateral instabilities in a grafted layer in a poor solvent

Chuck Yeung、Anna C. Balazs、David Jasnow1993-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLateral instabilities in a grafted layer in a poor solventChuck Yeung, Anna C. Balazs, and David JasnowCite this: Macromolecules 1993, 26, 8, 1914–1921Publication Date (Print):April 1, 1993Publication History Published online1 May 2002Published inissue 1 April 1993https://pu…

Advanced Fiber Optic SensorsLiquid Crystal Research AdvancementsFluid Dynamics and Thin Films

Theory of the isotropic-nematic-nematic phase separation for a solution of bidisperse rodlike particles

G. J. Vroege、H. N. W. Lekkerkerker1993-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheory of the isotropic-nematic-nematic phase separation for a solution of bidisperse rodlike particlesG. J. Vroege and H. N. W. LekkerkerkerCite this: J. Phys. Chem. 1993, 97, 14, 3601–3605Publication Date (Print):April 1, 1993Publication History Published online1 May 2002P…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Bimetallic lanthanide complexes with lanthanide-transition metal bonds. Molecular structure of (C4H8O)(C5H5)2LuRu(CO)2(C5H5). The use of 139La NMR spectroscopy

I. P. Beletskaya、Alexander Z. Voskoboynikov、E. B. Chuklanova 等 8 位作者1993-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBimetallic lanthanide complexes with lanthanide-transition metal bonds. Molecular structure of (C4H8O)(C5H5)2LuRu(CO)2(C5H5). The use of 139La NMR spectroscopyI. P. Beletskaya, A. Z. Voskoboynikov, E. B. Chuklanova, N. I. Kirillova, A. K. Shestakova, I. N. Parshina, A. I. Gu…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Highly Monodisperse Quantum Sized CdS Particles by Size Selective Precipitation

A. Chemseddine、Horst Weller1993-04-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract Nanometer sized cadmium sulfide particles were prepared in N,N‐dimethylformamide, using thiourea as the sulfurizing agent and thioglycerine as stabilizer. For particles with diameters of less than 40 Å the size dependent solubility was utilized to separate the particles according to their size. The absorption…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

A Modal Analysis of Lamellar Diffraction Gratings in Conical Mountings

Lifeng Li1993-04-01Journal of Modern Optics

A rigorous modal analysis of lamellar gratings, i.e. gratings having rectangular grooves, in conical mountings is presented. It is an extension of the analysis of Botten et al. which considered non-conical mountings. A key step in the extension is a decomposition of the electromagnetic field in the grating region into…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Thermodynamic Stabilities of SrCeO3 and BaCeO3 Using a Molten Salt Method and Galvanic Cells

Srikanth Gopalan、Anil V. Virkar1993-04-01Journal of The Electrochemical Society

and , which are known to be excellent proton conductors, are potential candidates as electrolytes in hydrogen concentrators and fuel cells. The anticipated application temperature is in the range of ∼500 to ∼1000°C. Typical synthesis/densification temperature of these cerates using conventional processing methods is ∼…

Advancements in Solid Oxide Fuel CellsMolten salt chemistry and electrochemical processesThermal Expansion and Ionic Conductivity

Degradation of poly(3-hydroxyoctanoic acid) [P(3HO)] by bacteria: purification and properties of a P(3HO) depolymerase from Pseudomonas fluorescens GK13

Andreas Schirmer、Dieter Jendrossek、Hans G. Schlegel1993-04-01Applied and Environmental Microbiology

Twenty-five gram-negative bacteria and one gram-positive bacterium capable of growing on poly(3-hydroxyoctanoic acid) [P(3HO)] as the sole source of carbon and energy were isolated from various soils, lake water, and activated sludge. Most of the isolates degraded only P(3HO) and copolymers of medium-chain-length (MCL…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Dynamic arc modeling of pollution flashover of insulators under DC voltage

R. Sundararajan、R.S. Gorur1993-04-01IEEE Transactions on Electrical Insulation

A dynamic model that computes the flashover voltages of polluted insulators energized with DC voltage is presented. The salient feature of this model is that it takes into account the configuration of the insulator profile at every instant, which plays an important role in the flashover process of the DC polluted insu…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaPower Transformer Diagnostics and Insulation

Crystal structure and magnetic properties of two nitronyl nitroxide biradicals and of their copper(II) complexes

Andréa Caneschi、P. Chiesi、L. David 等 6 位作者1993-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal structure and magnetic properties of two nitronyl nitroxide biradicals and of their copper(II) complexesA. Caneschi, P. Chiesi, L. David, F. Ferraro, D. Gatteschi, and R. SessoliCite this: Inorg. Chem. 1993, 32, 8, 1445–1453Publication Date (Print):April 1, 1993Publi…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchElectron Spin Resonance Studies

Cascade polymers. 35. pH dependence of hydrodynamic radii of acid-terminated dendrimers

George R. Newkome、James K. Young、Gregory R. Baker 等 9 位作者1993-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleCascade polymers. 35. pH dependence of hydrodynamic radii of acid-terminated dendrimersGeorge R. Newkome, James K. Young, Gregory R. Baker, Robert L. Potter, Laurent Audoly, David Cooper, Claus D. Weis, Kevin Morris, and Charles S. Johnson Jr.Cite this: Macromolecules 1993, 26,…

Polymer crystallization and propertiesMicroplastics and Plastic PollutionDendrimers and Hyperbranched Polymers

High-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: heterolytic cleavage of hydroperoxides

Teddy G. Traylor、Shinji Tsuchiya、Young Seok Byun 等 4 位作者1993-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: heterolytic cleavage of hydroperoxidesTeddy G. Traylor, Shinji Tsuchiya, Young Seok Byun, and Cheal KimCite this: J. Am. Chem. Soc. 1993, 115, 7, 2775–2781Publicati…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesMetal-Catalyzed Oxygenation Mechanisms

Determination of Critical Concentrations of Silica and/or Calcia for Abnormal Grain Growth in Alumina

So Ik Bae、Sunggi Baik1993-04-01Journal of the American Ceramic Society

Minimum amounts of SiO 2 and CaO required for inducing abnormal grain growth in alumina were determined using ultrapure alumina (>99.999%) and sintering at 1900°C for 1 h in a contamination‐free condition. The critical concentrations of silicon in cationic mole fractions in alumina were 300 ppm without calcium, 200…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesNuclear materials and radiation effects

Stronger acceptors can diminish nonlinear optical response in simple donor-acceptor polyenes

Seth R. Marder、Christopher B. Gorman、Bruce G. Tiemann 等 4 位作者1993-04-01Journal of the American Chemical Society

There has been much recent effort in the design of optimal chromophores for second-order nonlinear optical (NLO) applications. Most studies of organic molecules have focused on donor-acceptor π-conjugated molecules containing aromatic groups. We will show that the NLO response of aromatic donor-acceptor chromophores i…

Porphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical Studies

New ordered morphologies in ABC triblock copolymers

Clemens Auschra、Reimund Stadler1993-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNew ordered morphologies in ABC triblock copolymersClemens Auschra and Reimund StadlerCite this: Macromolecules 1993, 26, 9, 2171–2174Publication Date (Print):April 1, 1993Publication History Published online1 May 2002Published inissue 1 April 1993https://pubs.acs.org/doi/10…

Advanced Polymer Synthesis and CharacterizationTheoretical and Computational PhysicsBlock Copolymer Self-Assembly

CH-.pi. interaction as an important driving force of host-guest complexation in apolar organic media. Binding of monools and acetylated compounds to resorcinol cyclic tetramer as studied by proton NMR and circular dichroism spectroscopy

Kenji Kobayashi、Yuji Asakawa、Yasuaki Kikuchi 等 5 位作者1993-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCH-.pi. interaction as an important driving force of host-guest complexation in apolar organic media. Binding of monools and acetylated compounds to resorcinol cyclic tetramer as studied by proton NMR and circular dichroism spectroscopyKenji Kobayashi, Yuji Asakawa, Yasuaki…

Conducting polymers and applicationsAdvanced NMR Techniques and ApplicationsMolecular spectroscopy and chirality

Flame retardancy of polymeric materials

作者信息未提供1993-04-01Additives for Polymers

Some of the unsolved problems and unanswered questions in the flame retardance of polymers are reviewed. They include, durable flame-retardant systems for cotton; FR treatment of cotton–PET blends; durable, weatherable, non-water-leachable, FR treatment of lignocellulosic products, especially wood; better understandin…

Flame retardant materials and properties

Sequencing of a Clostridium thermocellum gene (cipA) encoding the cellulosomal SL‐protein reveals an unusual degree of internal homology

U. T. Gerngross、Marek P.M. Romaniec、Teruyuki Kobayashi 等 5 位作者1993-04-01Molecular Microbiology

It is known that two proteins of the cellulosomal complex of Clostridium thermocellum (SL and SS) together degrade crystalline cellulose. SL is a glycoprotein of 210,000 Da which enhances the binding to cellulose and the activity of SS, an endoglucanase of 83,000 Da. We have previously reported the cloning of a DNA fr…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Mechanism of quasi-one-dimensional electronic conductivity in discotic liquid crystals

N. Boden、Richard J. Bushby、J. Clements1993-04-01The Journal of Chemical Physics

Recently, it has been shown that a new class of quasi-one-dimensional conductors can be created by doping discotic liquid crystals with appropriate oxidants. This paper reports the elucidation of the mechanism of conduction in these new materials. In particular, the ac conductivity of 2,3,6,7,10,11-hexahexyloxytriphen…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Rigid nonlabile polyoxometalate cryptates [ZP5W30O110](15-n)- that exhibit unprecedented selectivity for certain lanthanide and other multivalent cations

I. I. CREASER、M Heckel、R. Jeffrey Neitz 等 4 位作者1993-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRigid nonlabile polyoxometalate cryptates [ZP5W30O110](15-n)- that exhibit unprecedented selectivity for certain lanthanide and other multivalent cationsInge Creaser, Mark C. Heckel, R. Jeffrey Neitz, and Michael T. PopeCite this: Inorg. Chem. 1993, 32, 9, 1573–1578Publicati…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications