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The Effect of Vanadium Deficiency on the Stability of Pd and Pt Catalysts in Lanthanum Strontium Vanadate Solid Oxide Fuel Cell Anodes

Nguyen M. Vo、Michael D. Gross2012-01-01Journal of The Electrochemical Society

Solid oxide fuel cell anodes comprised of vanadium deficient lanthanum strontium vanadate (La 0.7 Sr 0.3 V 1−x O 3−δ for x = 0, 0.05, 0.10, 0.15, and 0.20) infiltrated into porous yttria stabilized zirconia (YSZ) were investigated. La 0.7 Sr 0.3 V 1−x O 3−δ (LSV) remained single phase up to x = 0.10, with the formatio…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Europium Structural Effect on a Borosilicate Glass of Nuclear Interest

O. Bouty、Jean‐Marc Delaye、S. Peuget2012-01-01Procedia Chemistry

Short and middle range order structure of a borosilicate glass of nuclear interest doped with europium oxide was investigated in this study. Neutron diffraction and Wide Angle X-ray Scattering were used as experimental techniques. Furthermore, Reverse Monte Carlo simulation technique was also applied to build reliable…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsNuclear materials and radiation effects

Influence of the Magnetic Field on the Graphene Conductivity

S. V. Kryuchkov、E. I. Kukhar2012-01-01Journal of Modern Physics

The transversal conductivity of the gap-modification of the graphene was studied in the cases of weak nonquatizing and quantizing magnetic field. In the case of nonquantizing magnetic field the expression of the current density was derived from the Boltzmann equation. The dependence of conductivity and Hall conductivi…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvanced Physical and Chemical Molecular Interactions

Electrocaloric Materials for Cooling Applications

Sohini Kar‐Narayan、N. D. Mathur2012-01-01Ferroelectrics

We summarise the electrically driven temperature changes that have been convincingly reported for known electrocaloric materials. Materials improvements would facilitate solid-state cooling applications.

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric materials and actuators

Effect of functional groups on the radial collapse and elasticity of carbon nanotubes under hydrostatic pressure

Cuicui Ling、Qingzhong Xue、Nuannuan Jing 等 4 位作者2012-01-01Nanoscale

The effect of functional groups on the radial collapse and elasticity of a single-walled carbon nanotube (SWNT) under hydrostatic pressure was investigated using molecular dynamics and molecular mechanics simulations. It is found that the radial collapse and elasticity of the chemically modified SWNTs strongly depend…

Carbon Nanotubes in CompositesEnergetic Materials and CombustionNanotechnology research and applications

Relationship between cation exchange capacity and the saline phase of Cheliff sol

Djamel Saidi2012-01-01Agricultural Sciences

T Measurements of the cation exchange capacity (CEC) show significant soil properties, in particular its ability to retain the cations because of their mobility in the soil. Thirteen soil samples rich in electrolytes of the Cheliff plain (Algeria) were analyzed in order to measure their CEC and to draw up the existing…

Soil Carbon and Nitrogen DynamicsSoil and Unsaturated FlowClay minerals and soil interactions

DC Conductivity and Dielectric Behaviour of Glassy Se<sub>100–x</sub>Zn<sub>x</sub> Alloy

Mohammad Nasir、M. Zulfequar2012-01-01Open Journal of Inorganic Non-metallic Materials

The DC conductivity and dielectric properties of glassy Se100–xZnx 2 ≤ x ≤ 20 alloys have been investigated in the temperature range 303 - 487 K with frequency range 100 Hz – 1 MHz. It is observed that DC conductivity decreases and the activation energy increases with Zn content in Se-Zn system. Dielectric dispersion…

Glass properties and applicationsPhase-change materials and chalcogenidesSolid-state spectroscopy and crystallography

Mixed azide and carboxylate bridged trinuclear Mn(ii) and Co(ii) motifs in coordination ladders: structures and magnetism

Yanqin Wang、Ai-Ling Cheng、Xuan Wang 等 4 位作者2012-01-01RSC Advances

Two isomorphous Mn(II) and Co(II) coordination polymers with an azide and zwitterionic dicarboxylate ligand as coligands were synthesized and structurally characterized, and their magnetic properties were studied. They are formulated as [M3(L)2(N3)6(H2O)2]·2H2O (M = Mn (1), Co (2), L = 1,2-bis(4-carboxylatopyridinium-…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Waste-free scale up synthesis of nanocrystalline hexaaluminate: properties in oxygen transfer and oxidation reactions

Said Laassiri、Nicolas Bion、Fabien Can 等 7 位作者2012-01-01CrystEngComm

Synthesis of nanocrystalline hexaaluminate is reported using an original activated reactive synthesis process. Starting from a classical ceramic solid, exhibiting low surface area and a micrometric crystal size, a two-step grinding process allows reduction of the crystal size down to a few nanometers and development o…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Molecular dynamics simulations studies of laser ablation in metals

Johannes Roth、S. Sonntag、Johannes Karlin 等 7 位作者2012-01-01AIP conference proceedings

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Johannes Roth, Steffen Sonntag, Johannes Karlin, Carolina Trichet Paredes, Marc Sartison, Armin K…

Diamond and Carbon-based Materials ResearchLaser-induced spectroscopy and plasmaAdvanced Materials Characterization Techniques

Mechanoluminescence by Impulsive Deformation and Photoluminescence of SrAl2O4:Eu Phosphor Prepared by Combustion Synthesis

A. Choubey、Nameeta Brahme、D. P. Bisen2012-01-01Physics Procedia

SrAl2O4: Eu was synthesized by combustion method. Mechanoluminescence (ML) and Photoluminescence (PL) were studied. Time vs ML intensity plot shows two peaks. ML intensity increases with load applied and it is regained by UV irradiation. Photoluminescence shows intense emission in green region. PACS: 78.60.Mq; 78.55.Hx

Luminescence Properties of Advanced MaterialsQuantum Dots Synthesis And PropertiesLuminescence and Fluorescent Materials

Analysis of Carbon Nanotubes Produced by Pyrolysis of Composite Film of Poly (Vinyl Alcohol) and Modified Fly Ash

Dilip Chandra Deb Nath、Veena Sahajwalla2012-01-01Materials Sciences and Applications

We determined the catalytic function of chemically modified fly ash (MFA) for the growth of carbon nanotube (CNT) ropes with ~54% yield by the pyrolysis of the composite film of poly (vinyl alcohol) (PVA) at 500°C for 10 min under 2 L/min flow of nitrogen. Fly ash was treated with 2M sodium hydroxide to have MFA and u…

Carbon Nanotubes in CompositesGraphene research and applicationsFiber-reinforced polymer composites

Influence of the Shape of the Particles in the Solidification of Composite Materials

Eliana Agaliotis、Mario Roberto Rosenberger、Alicia Esther Ares 等 4 位作者2012-01-01Procedia Materials Science

Abstract The shape of a solidifying interface is generally affected when it encounters foreign inert particles. The degree of deformation depends on the morphology and physical properties of the particles, the melt, the solid and the external fields, affecting the pushing and capture process of the particles. The part…

Material Dynamics and PropertiesCoagulation and Flocculation StudiesParticle Dynamics in Fluid Flows

The first μ-Ge2Se8 ligand to lanthanide(iii) centers: solvothermal syntheses and characterizations of lanthanide selenidogermanate complexes with a pentadentate polyamine as a co-ligand

Ruihong Chen、Weiwei Tang、Jingjing Liang 等 6 位作者2012-01-01Dalton Transactions

Solvothermal reactions of elements Ge and Se with Ln(2)O(3) in a pentadentate polyamine, tetraethylenepentamine (tepa), produced novel neutral lanthanide-selenidogermanate polymers [{Ln(tepa)(μ-OH)}(2)(μ-Ge(2)Se(8))](n) (Ln = Eu 1, Gd 2, Dy 3). The reaction with Dy(2)O(3) in ethylenediamine (en) afforded an ionic sele…

Synthesis and characterization of novel inorganic/organometallic compoundsCrystal Structures and PropertiesInorganic Chemistry and Materials

One-pot Synthesis of Novel Energy Materials: Sub-micron Fe2O3 Encapsuled Carbon Spheres Core-shell Composite

Meng Xiaomin、Wan Ruijun2012-01-01Energy Procedia

Sub-micron Fe2O3 encapsuled carbon spheres core-shell composite (Fe2O3/C) has been successfully prepared through one-pot solvothermal reaction of acetylacetone and FeCl3 at 500°C. The phase and morphology of the sample were examined by XRD, TEM, SEM, HRTEM, XPS and TGA. Meanwhile, magnetic property of the sample was m…

Advancements in Battery MaterialsGraphene research and applicationsSupercapacitor Materials and Fabrication

Superthin combined PVA-graphene film

Hai-Yan Kong、Ji‐Huan He2012-01-01Thermal Science

Superthin polyvinil alcohol graphene sheet of several nanometers in thickness is obtained by the electrospinning. Polyvinil alcohol (10 wt.%) solution with the additive of ash (0.5 wt.%) is used for this purpose

Graphene research and applicationsPolymer Nanocomposite Synthesis and IrradiationGraphene and Nanomaterials Applications

Self-assembly of metallopolymer guided by graphene nanoribbons

Darkeyah G. Reuven、Huayang Li、Issifu I. Harruna 等 4 位作者2012-01-01Journal of Materials Chemistry

Self-assembly owing to noncovalent interactions provides a powerful tool for the creation of structures at a molecular level. Metal-connected diblock polymers offer a versatile building block for a large variety of nanostructures. Here, we report the supramolecular self-assembly of bis(2,2′:6′,2′′-terpyridine) metal-c…

Graphene research and applicationsSupramolecular Self-Assembly in MaterialsCovalent Organic Framework Applications

Dual Cells with Mixed Protonic-Anionic Conductivity for Reversible SOFC/SOEC Operation

Massimo Viviani、Giovanna Canu、Maria Paola Carpanese 等 13 位作者2012-01-01Energy Procedia

The dual cell concept is a novel design for solid oxide fuel cells operating at intermediate temperature. The cell comprises a series of five layers with different compositions, alternating two dense electrolytes and three porous layers, i.e. the outer electrodes and a central membrane. The dual cell concept makes it…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsChemical Looping and Thermochemical Processes

Crystal structure and ionic conductivity of AgCr<sub>2</sub>(PO<sub>4</sub>)(P<sub>2</sub>O<sub>7</sub>)

Brahim Ayed2012-01-01Comptes Rendus Chimie

Single crystals of a new phosphate AgCr2(PO4)(P2O7) have been prepared by the flux method and its structural and the infrared spectrum have been investigated. This compound crystallizes in the monoclinic system with the space group C2/c and the parameters are, a = 11.493 (3) Å, b = 8.486 (3) Å, c = 8.791 (2) Å, β = 11…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyChemical Synthesis and Characterization

Microwave Complex Permittivity and Absorption of MnO2Nanorods and Nanoparticles

Wen-Fan Liang、Ruey‐Bin Yang、Siu-Tong Choi2012-01-01Ferroelectrics

The electromagnetic and microwave-absorbing properties of irregular-shaped MnO2 nanoparticles (NP) and MnO2 nanorods (NR) as dielectric absorbent fillers in an insulating epoxy resin were investigated by the transmission/reflection method at 2−18 GHz. The real part of complex permittivity ϵ′ for 60 wt% of MnO2 NP-epox…

Advanced Sensor and Energy Harvesting MaterialsElectromagnetic wave absorption materialsDielectric materials and actuators