Materials Literature
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Abstract The spontaneous spreading of non‐film‐forming fluids on the surfaces of aqueous solutions of poly(2‐acrylamido‐2‐methyl‐propanesulfonic acid) and its chemically crosslinked gels was studied. The experiments were performed in the same concentration range for the solutions and gels, far above the overlap concen…
Preliminary studies suggest that protein crystallization experiments using nanoliter-volume protein crystallization droplets may produce equal or better quality protein crystals compared with those grown using microliter volumes, and sometimes produce crystals in nanoliter volumes when microliter volumes are unable to…
10.1021/ma0477605
Two recent developments, a novel screening/optimization strategy that considerably reduces the number of trials required to produce diffraction-size crystals and a simple modification that doubles the screening capacity of the Douglas Instruments ORYX 1-6 protein-crystallization robot, have been implemented into a str…
Abstract We present results of Raman‐scattering experiments on a series of nitrogen‐doped ZnO epilayers grown by chemical vapor deposition. Nitrogen, a potential acceptor in ZnO, was introduced by the thermal decomposition of ammonia (NH 3 ). We found a structure consisting of at least four lines with frequencies of 2…
Measurements of crystal growth kinetics are often performed by isothermal seeded batch experiments. On the basis of measurements for the chiral system mandelic acid/water, this work deals with (a) the experimental evaluation of different analytical techniques to determine simultaneously the solute concentration in the…
A highly efficient microwave-assisted method was successfully developed for the synthesis of a library of carbostyril analogues. The reaction time for synthesis of carbostyril analogues was drastically reduced from a reported 18-58 h to only 80 min. Compounds obtained directly from each synthesis were more than 90% pu…
Abstract Differential scanning calorimetry was used to investigate the isothermal crystallization, subsequent melting behavior, and nonisothermal crystallization of syndiotactic 1,2‐polybutadiene (st‐1,2‐PB) produced with an iron‐based catalyst system. The isothermal crystallization of two fractions was analyzed accor…
The effect of solvent polarity on the initiation and propagation of ethylene polymerization with a constrained geometry catalyst (CGC) and MAO counterion was investigated by the density functional theory (DFT) with the conductor-like screening model (COSMO). Structures and energetics of reactant, π-complex, transition…
Variations in the distribution of bond orders within coordination polyhedra in crystals have been used as a scale of departure from perfect polyhedral symmetry and a measure of polyhedral distortion. The distribution of bond orders mathematically resembles the probability distribution; the bond orders can be normalize…
Abstract An ion‐exchange method was applied to replace sodium cations inside the interlamellar space of montmorillonite with positively charged stearyl trimethyl ammonium chloride. The d 001 ‐spacing of montmorillonite is larger in toluene than in other solvents. The overexchanged stearyl methyl ammonium chloride in t…
The scope of this work is the determination of single-crystal elastic properties from X-ray diffraction stress analysis performed on multiphase polycrystals. An explicit three-scale multiphase inverse self-consistent model is developed in order to express the single-crystal elasticity constants of a cubic phase as a f…
Abstract Summary: A series of flame‐retardant‐containing unsaturated polyesters have been developed. The flame retardants include expandable graphite (EG) and phosphorous‐containing materials (ammonium polyphosphate (APP) and triphenyl phosphate (TPP)). The flame‐retardant properties of these samples were investigated…
Orientation distributions of cobaltite thermoelectric and polyphased bismuth-based cuprate superconducting textured materials are determined from neutron and X-ray diffraction analysis. Curved position-sensitive detectors coupled to a tilt-angle (χ) scan enable the treatment of the whole diffraction pattern using the…
Abstract Summary: Various crystalline textures have been identified in a crystallizable block copolymer system, polystyrene‐ block ‐[syndiotactic poly(propylene)] (PS‐sPP), having a glass‐transition temperature of PS ( T g,PS ) located in the midst of the sPP crystallization window. A confined morphology for the cryst…
In situ Raman spectroscopy was used to explore the mechanical stability and electronic properties of superhard boron suboxide (B6O) under nonhydrostatic pressure. B6O stabilizes in a rhombohedral structure (R3¯m) to the peak pressure of 90GPa. The icosahedra-chain (B–O) phonon at 274cm−1 exhibits a negative pressure d…
Synthesis of fully hydrophilic star-shaped macromolecules with different kinds of arms (A(x)B(y)C(z)) based on polyglycidol (PGL, A(x)) and poly(ethylene oxide) (PEO, C(z)) arms and diepoxy compounds (diglycidyl ethers of ethylene glycol (DGEG) or neopentyl glycol (DGNG) in the core, B(y)) forming the core is describe…
We have investigated the characteristics of Au Schottky contacts to ZnO:N layers grown on ͑0001͒ GaN/Al 2 O 3 substrates by plasma-assisted molecular-beam epitaxy.It is found that the Schottky characteristics are dependent on the growth temperature and polar direction of ZnO:N layers.The Schottky barrier height for th…
Three rotaxanes, with axles with two zinc porphyrins (ZnPs) at both ends penetrating into a necklace pending a C60 moiety, were synthesized with varying interlocked structures and axle lengths. The intra-rotaxane photoinduced electron transfer processes between the spatially positioned C60 and ZnP in rotaxanes were in…
A supported-metal catalyst can be considered as a mixture of three homogeneous phases: support, void and metal. Information about the metal phase alone can be obtained using anomalous small-angle X-ray scattering (ASAXS), which requires measuring the SAXS for two different wavelengths near the metal's absorption edge.…