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Protein nucleation and crystallization by homologous protein thin film template

Eugenia Pechkova、Claudio Nicolini2002-01-01Journal of Cellular Biochemistry

A new method of protein nucleation and crystallization based on Langmuir-Blodgett technology is here utilized for the template stimulation of crystal growth of so far non-crystallized proteins. Microcrystals (60-120 microm) of bovine cytochrome P450scc and human protein kinase CKII alpha subunit were obtained with use…

Protein Structure and DynamicsMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

The Influence of Salt Deposits on the Atmospheric Corrosion of Zinc. The Important Role of the Sodium Ion

Rakel Wreland Lindström、Jan‐Erik Svensson、L.‐G. Johansson2002-01-01Journal of The Electrochemical Society

The influence of salt deposits on the atmospheric corrosion of zinc was studied in the laboratory. Four chloride-containing salts, NaCl, NH 4 Cl , ZnCl 2 , and MgCl 2 , and four sulfate-containing salts, Na 2 SO 4 , ( NH 4 ) 2 SO 4 , ZnSO 4 , and MgSO 4 , were investigated. The salts were applied by spraying a saturat…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilitySmart Materials for Construction

Electrochemistry of Nitrogen-Incorporated Hydrogenated Amorphous Carbon Films

H. Cachet、C. Deslouis、Mustapha Chouiki 等 6 位作者2002-01-01Journal of The Electrochemical Society

Nitrogen-doped hydrogenated amorphous carbon, a ­ C : H : N x films, were synthesized by microwave electron cyclotron resonance plasma-enhanced chemical vapor deposition, using N 2 / C 2 H 2 as precursors. Such films, with thickness in the range of a few tens of nanometers, very smooth, and pinhole free, appear as ele…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Organometallic precursor route to carbon nanotubes

A. Govindaraj、C. N. R. Rao2002-01-01Pure and Applied Chemistry

Abstract Multi-walled as well as single-walled carbon nanotubes are conveniently prepared by the pyrolysis of organometallic precursors, such as metallocenes and phthalocyanines, in a reducing atmosphere. Pyrolysis of organometallics alone or in mixture with hydrocarbons also yields aligned nanotube bundles with usefu…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresFiber-reinforced polymer composites

Thermoelectric micro devices: current state, recent developments and future aspects for technological progress and applications

H. Böttner2002-01-01OpenAlex

Due to their unique expected properties thermoelectric microdevices, thermogenerators as well as Peltier coolers, are of high demand for different applications namely for telecommunication purposes. Thus worldwide efforts are undertaken to expand the technology for thermoelectric devices into the field of typical micr…

2D Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin Films

Kinetic studies of the aqueous oxidative polymerization of 3-hydroxyaniline and characterization of the polymer obtained

S. M. Sayyah、A. A. Bahgat、H. M. Abd El‐Salam2002-01-01International Journal of Polymeric Materials

The aqueous polymerization of 3-hydroxyaniline (3HA) was studied using sodium dichromate as oxidant in presence of hydrochloric acid. The effect of hydrochloric acid, sodium dichromate and monomer concentration on the polymerization rate, specific viscosity of the obtained polymer and a.c.conductivity was investigated…

Conducting polymers and applicationsAnalytical Chemistry and Sensors

Development of the web-based NIST X-ray Photoelectron Spectroscopy (XPS) Database

Angela Lee、D M. Blakeslee、C. J. Powell 等 4 位作者2002-01-01Data Science Journal

The CODATA Data Science Journal is a peer-reviewed, open access, electronic journal, publishing papers on the management, dissemination, use and reuse of research data and databases across all research domains, including science, technology, the humanities and the arts. The scope of the journal includes desc…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Spectroscopic Characterization of Model Urea, Urethane Compound, and Diamine Extender for Polyurethane−Urea

Shi-Kwun Wang、Chong Sook Paik Sung2002-01-01Macromolecules

During the reaction injecting molding process of polyurethane−urea (PUU) based on 4,4‘-methylenebisphenyl diisocyanate (MDI), urethane as well as urea linkages are produced when a highly fluorescent aromatic diamine is used as a chain extender. To explore intrinsic fluorescence as a cure characterization technique, mo…

Polymer composites and self-healingLignin and Wood ChemistryEnvironmental Chemistry and Analysis

Photothermal deflection spectroscopy of chalcogenide glasses

Keiji Tanaka、Tamihiro Gotoh、Norimitsu Yoshida 等 4 位作者2002-01-01Journal of Applied Physics

Photothermal deflection spectroscopy has been applied to optical absorption measurements in As2S3, Se, and As–S glasses. The spectroscopic method is demonstrated to be suitable for evaluation of small absorption in thin samples, while its accuracy is affected by light scattering. For As2S3, as-evaporated films give hi…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesThermography and Photoacoustic Techniques

Effect of Electrolytes on Performance of Electrochemical Capacitors Based on Poly[3-(3,4-difluorophenyl)thiophene]

Lin Li、David C. Loveday、Dhurjati S. K. Mudigonda 等 4 位作者2002-01-01Journal of The Electrochemical Society

Poly[3-(3,4-difluorophenyl)thiophene], MPFPT, electrochemically deposited onto carbon paper, was studied in electrochemical capacitors utilizing several tetraalkylammonium/acetonitrile electrolyte systems. Although the surface morphology of the polymer varied with the anion used for polymerization, an open and porous…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Progress on Composites with Embedded Shape Memory Alloy Wires

Jan Schrooten、Véronique Michaud、John Parthenios 等 8 位作者2002-01-01MATERIALS TRANSACTIONS

Composite materials containing thin Shape Memory Alloy (SMA) wires show great promise as materials able to adapt their shape, thermal behaviour or vibrational properties during service. Tools for designing such materials are however far from being available. The work presented here reports the main achievements of a c…

Polymer composites and self-healingShape Memory Alloy TransformationsInnovations in Concrete and Construction Materials

Effects of Hydrogen Pickup and Second-Phase Particle Dissolution on the In-Reactor Corrosion Performance of BWR Claddings

Per Tägtström、Magnus Limbäck、Mats Dahlbäck 等 5 位作者2002-01-01OpenAlex

It is well established that the second-phase particle (SPP) size distribution and the cladding chemical composition affects the in-reactor corrosion rate of boiling water reactor (BWR) cladding, although the mechanisms are not yet fully understood. To further study these effects, the corrosion and hydriding performanc…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Electrocatalysis of Oxygen Reduction on Polypyrrole/Mixed Valence Spinel Oxide Nanoparticles

Hongbo Cong、K. El Abbassi、P. Chartier2002-01-01Journal of The Electrochemical Society

Composite electrodes based on mixed valence oxide nanoparticles (Ox) embedded in an electrically conductive polymer (ECP) were investigated toward the oxygen reduction reaction (ORR). ECP was polypyrrole (PPy), and Ox was the spinel mixed valence oxide Cu 1.4 Mn 1.6 O 4 , which is known to be an electrocatalyst of the…

Fuel Cells and Related MaterialsConducting polymers and applicationsElectrochemical Analysis and Applications

Room Temperature Deformation Behavior of Zn-22 mass%Al Alloy with Nanocrystalline Structure

Tsutomu Tanaka、Koichi Makii、Atsumichi Kushibe 等 4 位作者2002-01-01MATERIALS TRANSACTIONS

The deformation behavior near room temperature in Zn-22 mass%Al alloy including nanocrystalline structure produced with Thermo Mechanical Controlling Process (TMCP) technology has been characterized over a wide range of strain rates from 10−6 to 10−1 s−1 at temperatures from 273 to 473 K . The microstructure of TMCP p…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesMetallurgy and Material Forming

Folding Pathway Mediated by an Intramolecular Chaperone: Dissecting Conformational Changes Coincident with Autoprocessing and the Role of Ca2+ in Subtilisin Maturation

Yukinori Yabuta、Ezhilkani Subbian、Hiroshi Takagi 等 5 位作者2002-01-01The Journal of Biochemistry

Subtilisin is produced as a precursor that requires its N-terminal propeptide to chaperone the folding of its protease domain. Once folded, subtilisin adopts a remarkably stable conformation, which has been attributed to a high affinity Ca(2+) binding site. We investigated the role of the metal ligand in the maturatio…

Heat shock proteins researchProtein purification and stabilityEnzyme Structure and Function

The First Assembly of a Nest-Shaped Heterothiometallic Cluster and a Polyoxometalate Anion − Synthesis, Characterization, and Strong Third-Order Nonlinear Optical Response

Chi Zhang、Yinglin Song、Fritz E. Kühn 等 7 位作者2002-01-01European Journal of Inorganic Chemistry

Two heterothiometallic cluster compounds [MOS3Cu3(4-pic)6]·0.5[M2O7] (M = Mo 1, W 2) having a cationic cluster skeleton and a polyoxometalate cluster anion, as well as two other clusters [MOS3Cu3(4-pic)6]·[BF4] (M = Mo 3, W 4) have been synthesized for nonlinear optics studies. Single-crystal X-ray diffraction data sh…

Magnetism in coordination complexesNanocluster Synthesis and ApplicationsOrganometallic Compounds Synthesis and Characterization

Cyclam complexes containing silica gels for dioxygen adsorption

Géraud Dubois、Raphaël Tripier、Stéphane Brandès 等 5 位作者2002-01-01Journal of Materials Chemistry

Several cyclam incorporating silica gels have been synthesised using three different methods, including a sol–gel approach. These various materials show different textures and the macrocycle contents can reach values up to 1.5 mmol g−1. Cu(II) and Co(II) complexes of these modified silica gels have been studied. Final…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisOxidative Organic Chemistry Reactions

Photoisomerization of azobenzene in the interlayer space of magadiite

Makoto Ogawa2002-01-01Journal of Materials Chemistry

The intercalation of a cationic azobenzene derivative into the interlayer space of magadiite was conducted by the ion exchange reactions between magadiite and p-[2-(2-hydroxyethyldimethylammonio)ethoxy]azobenzene bromide. X-Ray diffraction and elemental analysis confirmed the formation of the p-[2-(2-hydroxyethyldimet…

Photochemistry and Electron Transfer StudiesLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Epitaxial Growth of CrO2 Thin Films on TiO2(110) Surfaces

Heather A. Bullen、Simon J. Garrett2002-01-01Chemistry of Materials

Chromium dioxide films on TiO 2 (110) single crystals have been grown by using chemical vapor deposition. The average growth rate was ∼1.8 nm·min - 1 . Powder X-ray diffraction indicated that the films were highly (110) textured. X-ray photoelectron spectroscopy showed that the CrO 2 films were continuous and no other…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides